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Title: Efficient Fluorinating Agent through Topochemical Fluorination of Co-Fe Layered Double Hydroxides

Mixed-metal inorganic fluoride, Co0.60Fe0.40F3, solid solutions are obtained through topochemical reactions of Co2FeCl(OH)6·2H2O LDH with molecular fluorine, F2, at temperatures as low as 100 °C. This solid solution possesses interesting F-releasing ability, and its efficiency as a solid-state fluorinating agent is demonstrated on a commercial polyethylene film. 19F solid state NMR and contact angle measurements underline the efficient fluorination of this polymer.
Authors:
; ; ; ;  [1]
  1. Blaise Pascal
Publication Date:
OSTI Identifier:
1117031
Resource Type:
Journal Article
Resource Relation:
Journal Name: Inorganic Chemistry; Journal Volume: 53; Journal Issue: (2) ; 01, 2014
Publisher:
American Chemical Society (ACS)
Research Org:
Advanced Photon Source (APS), Argonne National Laboratory (ANL), Argonne, IL (US)
Sponsoring Org:
DOE - BASIC ENERGY SCIENCES
Country of Publication:
United States
Language:
ENGLISH