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Title: Cold Crucible Induction Melter Studies for Making Glass Ceramic Waste Forms. A Feasibility Assessment

Journal Article · · Journal of Nuclear Materials

Glass ceramics are being developed to immobilize fission products, separated from used nuclear fuel by aqueous reprocessing, into a stable waste form suitable for disposal in a geological repository. This work documents the glass ceramic formulation at bench scale and for a scaled melter test performed in a pilot-scale (~1/4 scale) cold crucible induction meter (CCIM). Melt viscosity, electrical conductivity, and crystallization behavior upon cooling were measured on a small set of compositions to select a formulation for melter testing. Property measurements also identified a temperature range for melter operation and cooling profiles necessary to crystallize the targeted phases in the waste form. Bench scale and melter run results successfully demonstrate the processability of the glass ceramic using the CCIM melter technology.

Research Organization:
Pacific Northwest National Lab. (PNNL), Richland, WA (United States). Environmental Molecular Sciences Lab. (EMSL)
Sponsoring Organization:
USDOE
DOE Contract Number:
AC05-76RL01830
OSTI ID:
1114089
Report Number(s):
PNNL-SA-95078; 47580
Journal Information:
Journal of Nuclear Materials, Vol. 444, Issue 1-3; ISSN 0022-3115
Publisher:
Elsevier
Country of Publication:
United States
Language:
English