Crystal Growth Simulations To Establish Physically Relevant Kinetic Parameters from the Empirical Kolmogorov-Johnson-Mehl-Avrami Model
Abstract
A series of simulations was performed to enable interpretation of the material and physical significance of the parameters defined in the Kolmogorov, Johnson and Mehl, and Avrami (KJMA) rate expression commonly used to describe phase boundary controlled reactions of condensed matter. The parameters k, n, and t0 are shown to be highly correlated, which if unaccounted for seriously challenge mechanistic interpretation. It is demonstrated that rate measurements exhibit an intrinsic uncertainty without precise knowledge of the location and orientation of nucleation with respect to the free volume into which it grows. More significantly, it is demonstrated that the KJMA rate constant k is highly dependent on sample size. However, under the simulated conditions of slow nucleation relative to crystal growth, sample volume and sample anisotropy correction affords a means to eliminate the experimental condition dependence of the KJMA rate constant, k, producing the material-specific parameter, the velocity of the phase boundary, vpb.
- Authors:
-
- NCSU
- Publication Date:
- Research Org.:
- Argonne National Lab. (ANL), Argonne, IL (United States). Advanced Photon Source (APS)
- Sponsoring Org.:
- National Science Foundation (NSF)
- OSTI Identifier:
- 1104556
- Resource Type:
- Journal Article
- Journal Name:
- Chemistry of Materials
- Additional Journal Information:
- Journal Volume: 25; Journal Issue: (20) ; 10, 2013; Journal ID: ISSN 0897-4756
- Publisher:
- American Chemical Society (ACS)
- Country of Publication:
- United States
- Language:
- ENGLISH
Citation Formats
Dill, Eric D., Folmer, Jacob C.W., and Martin, James D. Crystal Growth Simulations To Establish Physically Relevant Kinetic Parameters from the Empirical Kolmogorov-Johnson-Mehl-Avrami Model. United States: N. p., 2013.
Web. doi:10.1021/cm402751x.
Dill, Eric D., Folmer, Jacob C.W., & Martin, James D. Crystal Growth Simulations To Establish Physically Relevant Kinetic Parameters from the Empirical Kolmogorov-Johnson-Mehl-Avrami Model. United States. https://doi.org/10.1021/cm402751x
Dill, Eric D., Folmer, Jacob C.W., and Martin, James D. 2013.
"Crystal Growth Simulations To Establish Physically Relevant Kinetic Parameters from the Empirical Kolmogorov-Johnson-Mehl-Avrami Model". United States. https://doi.org/10.1021/cm402751x.
@article{osti_1104556,
title = {Crystal Growth Simulations To Establish Physically Relevant Kinetic Parameters from the Empirical Kolmogorov-Johnson-Mehl-Avrami Model},
author = {Dill, Eric D. and Folmer, Jacob C.W. and Martin, James D.},
abstractNote = {A series of simulations was performed to enable interpretation of the material and physical significance of the parameters defined in the Kolmogorov, Johnson and Mehl, and Avrami (KJMA) rate expression commonly used to describe phase boundary controlled reactions of condensed matter. The parameters k, n, and t0 are shown to be highly correlated, which if unaccounted for seriously challenge mechanistic interpretation. It is demonstrated that rate measurements exhibit an intrinsic uncertainty without precise knowledge of the location and orientation of nucleation with respect to the free volume into which it grows. More significantly, it is demonstrated that the KJMA rate constant k is highly dependent on sample size. However, under the simulated conditions of slow nucleation relative to crystal growth, sample volume and sample anisotropy correction affords a means to eliminate the experimental condition dependence of the KJMA rate constant, k, producing the material-specific parameter, the velocity of the phase boundary, vpb.},
doi = {10.1021/cm402751x},
url = {https://www.osti.gov/biblio/1104556},
journal = {Chemistry of Materials},
issn = {0897-4756},
number = (20) ; 10, 2013,
volume = 25,
place = {United States},
year = {Thu Dec 05 00:00:00 EST 2013},
month = {Thu Dec 05 00:00:00 EST 2013}
}