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Title: Factors Controlling Redox Speciation of Plutonium and Neptunium in Extraction Separation Processes

The objective of the project was to examine the factors controlling redox speciation of plutonium and neptunium in UREX+ extraction in terms of redox potentials, redox mechanism, kinetics and thermodynamics. Researchers employed redox-speciation extractions schemes in parallel to the spectroscopic experiments. The resulting distribution of redox species w studied uring spectroscopic, electrochemical, and spectro-electrochemical methods. This work reulted in collection of data on redox stability and distribution of redox couples in the nitric acid/nitrate electrolyte and the development of redox buffers to stabilize the desired oxidation state of separated radionuclides. The effects of temperature and concentrations on the redox behavior of neptunium were evaluated.
Authors:
 [1] ;  [2]
  1. Principal Investigator
  2. Collaborator
Publication Date:
OSTI Identifier:
1095231
Report Number(s):
DOE/ID/14829
DOE Contract Number:
FC07-07ID14829
Resource Type:
Technical Report
Research Org:
Oregon State University
Sponsoring Org:
USDOE
Country of Publication:
United States
Language:
English