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Title: Thermal Properties in the MgAl2O4-Al2O3 System

Compositional effects on the thermal diffusivity in the MgAl2O4-Al2O3 system were studied. The lowest thermal diffusivity, 0.0258 +/-5% cm/s, was measured between 79.8 and 83.9 wt% Al2O3 quenched from various temperatures between 1500 and 1700C. All of the chemistries in this range extend past the solvus, but still form a singe super-saturated spinel solid solution, regardless of quenching tempeature. A super-saturated metastable solid solution region was observed at 1500, 1600, and 1700C extending to 83.9, 85.2, and 87.1 wt% Al2O3, respectively. Beyond 83.9% Al2O3 a significant increase in thermal diffusivity, 11.7%, was observed and its attributed to precipiation of Al2O3 through spinodal decomposition.
Authors:
 [1] ;  [2] ;  [2]
  1. Missouri University of Science and Technology
  2. ORNL
Publication Date:
OSTI Identifier:
1093153
DOE Contract Number:
DE-AC05-00OR22725
Resource Type:
Conference
Resource Relation:
Conference: 13th Biennial Worldwide Congress on Refractories: UNITECR 2013, Victoria, BC, Canada, 20130910, 20130913
Research Org:
Oak Ridge National Laboratory (ORNL)
Sponsoring Org:
EE USDOE - Office of Energy Efficiency and Renewable Energy (EE)
Country of Publication:
United States
Language:
English