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Title: NDTB-1: A Supertetrahedral Cationic Framework That Removes TcO4- from Solution

A cubic thorium borate possesses a porous supertetrahedral cationic framework with extraframework borate anions. These anions are readily exchanged with a variety of environmental contaminants, especially those from the nuclear industry, including chromate and pertechnetate.
Authors:
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Publication Date:
OSTI Identifier:
1064654
DOE Contract Number:
SC0001089
Resource Type:
Journal Article
Resource Relation:
Journal Name: Angewandte Chemie (International Edition); Journal Volume: 49; Journal Issue: 1; Related Information: MSA partners with University of Notre Dame (lead); University of California, Davis; Florida State University; George Washington University; University of Michigan; University of Minnesota; Oak Ridge National Laboratory; Oregon state University; Rensselaer Polytechnic Institute; Savannah River National Laboratory
Publisher:
Wiley
Research Org:
Energy Frontier Research Centers (EFRC); Materials Science of Actinides (MSA)
Sponsoring Org:
USDOE SC Office of Basic Energy Sciences (SC-22)
Country of Publication:
United States
Language:
English
Subject:
38 RADIATION CHEMISTRY, RADIOCHEMISTRY, AND NUCLEAR CHEMISTRY; 12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE WASTES FROM NUCLEAR FACILITIES nuclear (including radiation effects), materials and chemistry by design, synthesis (novel materials), synthesis (self-assembly)