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Title: Ion-pair triple helicates and mesocates self-assembled from ditopic 2,2'-bipyridine-bis(urea) ligands and Ni(ii) or Fe(ii) sulfate salts

Journal Article · · ChemComm
DOI:https://doi.org/10.1039/c2cc33062h· OSTI ID:1049090

Here, NiSO4and FeSO4 self-assemble with heteroditopic ligands (L) comprising 2,2'-bipyridine and o-phenylene-(bis)urea cation- and anion-binding sites, respectively, into [ML3SO4] (M = Ni2+, Fe2+) triple-stranded ion-pair helicates and mesocates.

Research Organization:
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
Sponsoring Organization:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
DOE Contract Number:
AC05-00OR22725
OSTI ID:
1049090
Journal Information:
ChemComm, Vol. 48, Issue 60; ISSN 1359-7345
Publisher:
Royal Society of Chemistry
Country of Publication:
United States
Language:
English