Pressure-driven orbital reorientations and coordination-sphere reconstructions in [CuF2(H2O)2(pyz)]
Journal Article
·
· Angewandte Chemie. International Edition in English
- Materials Science Division
Successive reorientations of the Jahn-Teller axes associated with the Cu{sup II} ions accompany a series of pronounced structural transitions in the title compound, as is shown by X-ray crystallography and high-frequency EPR measurements. The second transition forces a dimerization involving two thirds of the Cu{sup II} sites due to ejection of one of the water molecules from the coordination sphere
- Research Organization:
- Argonne National Lab. (ANL), Argonne, IL (United States)
- Sponsoring Organization:
- USDOE Office of Science (SC)
- DOE Contract Number:
- DE-AC02-06CH11357
- OSTI ID:
- 1047450
- Report Number(s):
- ANL/MSD/JA-72655; ACIEAY; TRN: US201216%%295
- Journal Information:
- Angewandte Chemie. International Edition in English, Vol. 51, Issue 30; ISSN 0570-0833
- Country of Publication:
- United States
- Language:
- ENGLISH
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