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Title: Initial Assessment of Alternate Metals in Chalcogels

Abstract

This report provides an up-to-date account of the non-Pt based chemistries available in the literature for making non-oxide, chalcogen-based aerogels, called chalcogels. In each case, a combination of multiple precursors is required to make the chalcogels and, in most cases, the precursors are not commercially available and must be prepared in the laboratory. References for the preparation details of these precursors have been provided for each. An account of the chalcogels made at PNNL is also given in this report along with iodine sorption efficiencies for three very diverse chalcogel chemistries. A brief account of consolidation options is provided.

Authors:
; ; ;
Publication Date:
Research Org.:
Pacific Northwest National Lab. (PNNL), Richland, WA (United States)
Sponsoring Org.:
USDOE
OSTI Identifier:
1045128
Report Number(s):
PNNL-21488
AF5805000; TRN: US201214%%1083
DOE Contract Number:  
AC05-76RL01830
Resource Type:
Technical Report
Country of Publication:
United States
Language:
English
Subject:
36 MATERIALS SCIENCE; 37 INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY; IODINE; SORPTION; CHEMISTRY; chalcogen; chalcogenide; aerogel; chalcogel

Citation Formats

Riley, Brian J, Lepry, William C, Chun, Jaehun, and Strachan, Denis M. Initial Assessment of Alternate Metals in Chalcogels. United States: N. p., 2012. Web. doi:10.2172/1045128.
Riley, Brian J, Lepry, William C, Chun, Jaehun, & Strachan, Denis M. Initial Assessment of Alternate Metals in Chalcogels. United States. https://doi.org/10.2172/1045128
Riley, Brian J, Lepry, William C, Chun, Jaehun, and Strachan, Denis M. 2012. "Initial Assessment of Alternate Metals in Chalcogels". United States. https://doi.org/10.2172/1045128. https://www.osti.gov/servlets/purl/1045128.
@article{osti_1045128,
title = {Initial Assessment of Alternate Metals in Chalcogels},
author = {Riley, Brian J and Lepry, William C and Chun, Jaehun and Strachan, Denis M},
abstractNote = {This report provides an up-to-date account of the non-Pt based chemistries available in the literature for making non-oxide, chalcogen-based aerogels, called chalcogels. In each case, a combination of multiple precursors is required to make the chalcogels and, in most cases, the precursors are not commercially available and must be prepared in the laboratory. References for the preparation details of these precursors have been provided for each. An account of the chalcogels made at PNNL is also given in this report along with iodine sorption efficiencies for three very diverse chalcogel chemistries. A brief account of consolidation options is provided.},
doi = {10.2172/1045128},
url = {https://www.osti.gov/biblio/1045128}, journal = {},
number = ,
volume = ,
place = {United States},
year = {Fri Jun 29 00:00:00 EDT 2012},
month = {Fri Jun 29 00:00:00 EDT 2012}
}