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Title: Tetragonal-to-Orthorhombic Structural Phase Transition at 90Kin the Superconductor Fe1:01Se

Journal Article · · Physical Review Letters

In this Letter we show that superconducting Fe{sub 1.01}Se undergoes a structural transition at 90 K from a tetragonal to an orthorhombic phase but that nonsuperconducting Fe{sub 1.03}Se does not. High resolution electron microscopy at low temperatures further reveals an unexpected additional modulation of the crystal structure of the superconducting phase that involves displacements of the Fe atoms, and that the nonsuperconducting composition shows a different, complex nanometer-scale structural modulation. Finally, we show that magnetism is not the driving force for the phase transition in the superconducting phase.

Research Organization:
Brookhaven National Lab. (BNL), Upton, NY (United States)
Sponsoring Organization:
USDOE SC OFFICE OF SCIENCE (SC)
DOE Contract Number:
DE-AC02-98CH10886
OSTI ID:
1040186
Report Number(s):
BNL-90533-2009-JA; PRLTAO; R&D Project: MA-015-MACA; KC0201010; TRN: US201210%%369
Journal Information:
Physical Review Letters, Vol. 103, Issue 5; ISSN 0031-9007
Country of Publication:
United States
Language:
English

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