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Title: Ice Nucleation and Droplet Formation by Bare and Coated Black Carbon Particles

Abstract

We have studied the ice formation at heterogeneous and homogeneous temperatures, as well as droplet activation and hygroscopicity of soot particles of variable size and composition. Coatings of adipic, malic, and oleic acid were applied to span a relevant range of solubility, and both uncoated and oleic acid coated soot particles were exposed to ozone to simulate atmospheric oxidation. The results are interpreted in terms of onset ice nucleation with a comparison to a well characterized mineral dust particle that acts as an efficient ice nucleus, as well as particle hygroscopicity. At 253K and 243K, we found no evidence of heterogeneous ice nucleation occurring above the level of detection for our experimental conditions. Above water saturation, droplet formation was observed. At 233K, we observe the occurrence of homogeneous ice nucleation for all particles studied. Coatings also did not significantly alter the ice nucleation behavior of soot particles, but aided in the uptake of water. Hygroscopicity studies confirmed that pure soot particles were hydrophobic, and coated soot particles activated as droplets at high water supersaturations. A small amount of heterogeneous ice nucleation either below the detection limit of our instrument or concurrent with droplet formation and/or homogeneous freezing cannot be precluded,more » but we are able to set limits for its frequency. We conclude from our studies that both uncoated and coated soot particles are unlikely to contribute to the global budget of heterogeneous ice nuclei at temperatures between 233K and 253K.« less

Authors:
; ; ; ; ;
Publication Date:
Research Org.:
Pacific Northwest National Lab. (PNNL), Richland, WA (United States)
Sponsoring Org.:
USDOE
OSTI Identifier:
1036927
Report Number(s):
PNNL-SA-79084
KC0302020; TRN: US201206%%669
DOE Contract Number:  
AC05-76RL01830
Resource Type:
Journal Article
Journal Name:
Journal of Geophysical Research. D. (Atmospheres), 116:Article No. D17203
Additional Journal Information:
Journal Volume: 116
Country of Publication:
United States
Language:
English
Subject:
58 GEOSCIENCES; CARBON; COATINGS; DETECTION; DUSTS; FREEZING; HYGROSCOPICITY; NUCLEATION; NUCLEI; OLEIC ACID; OXIDATION; OZONE; SENSITIVITY; SOLUBILITY; SOOT; WATER; WATER SATURATION

Citation Formats

Friedman, Beth J, Kulkarni, Gourihar R, Beranek, Josef, Zelenyuk, Alla, Thornton, Joel A, and Cziczo, Daniel J. Ice Nucleation and Droplet Formation by Bare and Coated Black Carbon Particles. United States: N. p., 2011. Web. doi:10.1029/2011jd015999.
Friedman, Beth J, Kulkarni, Gourihar R, Beranek, Josef, Zelenyuk, Alla, Thornton, Joel A, & Cziczo, Daniel J. Ice Nucleation and Droplet Formation by Bare and Coated Black Carbon Particles. United States. https://doi.org/10.1029/2011jd015999
Friedman, Beth J, Kulkarni, Gourihar R, Beranek, Josef, Zelenyuk, Alla, Thornton, Joel A, and Cziczo, Daniel J. 2011. "Ice Nucleation and Droplet Formation by Bare and Coated Black Carbon Particles". United States. https://doi.org/10.1029/2011jd015999.
@article{osti_1036927,
title = {Ice Nucleation and Droplet Formation by Bare and Coated Black Carbon Particles},
author = {Friedman, Beth J and Kulkarni, Gourihar R and Beranek, Josef and Zelenyuk, Alla and Thornton, Joel A and Cziczo, Daniel J},
abstractNote = {We have studied the ice formation at heterogeneous and homogeneous temperatures, as well as droplet activation and hygroscopicity of soot particles of variable size and composition. Coatings of adipic, malic, and oleic acid were applied to span a relevant range of solubility, and both uncoated and oleic acid coated soot particles were exposed to ozone to simulate atmospheric oxidation. The results are interpreted in terms of onset ice nucleation with a comparison to a well characterized mineral dust particle that acts as an efficient ice nucleus, as well as particle hygroscopicity. At 253K and 243K, we found no evidence of heterogeneous ice nucleation occurring above the level of detection for our experimental conditions. Above water saturation, droplet formation was observed. At 233K, we observe the occurrence of homogeneous ice nucleation for all particles studied. Coatings also did not significantly alter the ice nucleation behavior of soot particles, but aided in the uptake of water. Hygroscopicity studies confirmed that pure soot particles were hydrophobic, and coated soot particles activated as droplets at high water supersaturations. A small amount of heterogeneous ice nucleation either below the detection limit of our instrument or concurrent with droplet formation and/or homogeneous freezing cannot be precluded, but we are able to set limits for its frequency. We conclude from our studies that both uncoated and coated soot particles are unlikely to contribute to the global budget of heterogeneous ice nuclei at temperatures between 233K and 253K.},
doi = {10.1029/2011jd015999},
url = {https://www.osti.gov/biblio/1036927}, journal = {Journal of Geophysical Research. D. (Atmospheres), 116:Article No. D17203},
number = ,
volume = 116,
place = {United States},
year = {Thu Oct 13 00:00:00 EDT 2011},
month = {Thu Oct 13 00:00:00 EDT 2011}
}