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Title: Effect of Increased Water Vapor Levels on TBC Lifetime

Conference ·
OSTI ID:1030614

To investigate the effect of increased water vapor levels on thermal barrier coating (TBC) lifetime, furnace cycle tests were performed at 1150 C in air with 10 vol.% water vapor (similar to natural gas combustion) and 90 vol.%. Either Pt diffusion or Pt-modified aluminide bond coatings were applied to specimens from the same batch of a commercial second-generation single-crystal superalloy and commercial vapor-deposited yttria-stabilized zirconia (YSZ) top coats were applied. Three coatings of each type were furnace cycled to failure to compare the average lifetimes obtained in dry O{sub 2}, using the same superalloy batch and coating types. Average lifetimes with Pt diffusion coatings were unaffected by the addition of water vapor. In contrast, the average lifetime of Pt-modified aluminide coatings was reduced by more than 50% with 10% water vapor but only slightly reduced by 90% water vapor. Based on roughness measurements from similar specimens without a YSZ coating, the addition of 10% water vapor increased the rate of coating roughening more than 90% water vapor. Qualitatively, the amount of {beta}-phase depletion in the coatings exposed in 10% water vapor did not appear to be accelerated.

Research Organization:
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
Sponsoring Organization:
FE USDOE - Office of Fossil Energy (FE)
DOE Contract Number:
DE-AC05-00OR22725
OSTI ID:
1030614
Resource Relation:
Conference: ICMCTF, San Diego, CA, USA, 20110502, 20110506
Country of Publication:
United States
Language:
English