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Title: Poly[bis(N,N-dimethylformamide-[kappa]O)([mu]4-naphthalene-1,5-disulfonato)magnesium(II)]

The structure of the title compound, [Mg(C{sub 10}H{sub 6}O{sub 6}S{sub 2})(C{sub 3}H{sub 7}NO){sub 2}]{sub n}, consists of MgO{sub 6} octahedra ({bar 1} symmetry) connected to naphthalene-1,5-disulfonate ligands ({bar 1} symmetry) in the equatoral plane, forming a two-dimensional network propagating parallel to (010). The coordination sphere of the Mg atom is completed by the O atoms of two N,N-dimethylformamide (DMF) molecules in the axial positions. The title compound represents the first time the naphthalene-1,5-disulfonate anion is bound directly to a Mg{sup 2+} atom. Disorder over two positions was found in the DMF molecule in a 0.518 (8):0.482 (8) ratio.
Authors:
; ;  [1]
  1. (SBU)
Publication Date:
OSTI Identifier:
1022257
Resource Type:
Journal Article
Resource Relation:
Journal Name: Acta Crystallogr. E; Journal Volume: 66; Journal Issue: (6) ; 06, 2010
Research Org:
Advanced Photon Source (APS), Argonne National Laboratory (ANL), Argonne, IL (US)
Sponsoring Org:
NSF
Country of Publication:
United States
Language:
ENGLISH
Subject:
71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSICS; ANIONS; ATOMS; SYMMETRY