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Title: Predicting liquid densities of organic compounds: II, Nitrogen and sulfur compounds

Correlations of liquid densities have been extended to more classes of organic compounds. The products of liquid density and molecular weight at or near 20{degrees}C were previously found to be linear functions of the number and types of carbon atoms in the molecule. Cyclic carbon atoms contributed more to density than carbon atoms not part of a ring structure. Carbon atoms which occupy two rings have since been found to contribute even different increments. Additional databases of liquid densities have been set up for compounds with cyclic oxygen atoms, cyclic and noncyclic nitrogen atoms, and cyclic and noncyclic sulfur atoms. Correlation parameters have been obtained by fitting these data by least squares minimization.
Authors:
;
Publication Date:
OSTI Identifier:
10133173
Report Number(s):
LA-UR--93-179; CONF-9211192--1
ON: DE93007343
DOE Contract Number:
W-7405-ENG-36
Resource Type:
Conference
Resource Relation:
Conference: Chemical defense research meeting,Edgewood, MD (United States),18 Nov 1992; Other Information: PBD: [1993]
Research Org:
Los Alamos National Lab., NM (United States)
Sponsoring Org:
USDOE, Washington, DC (United States)
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY; ORGANIC COMPOUNDS; DENSITY; MOLECULAR WEIGHT; OXYGEN; NITROGEN; SULFUR; HYDROCARBONS; AROMATICS 400201; CHEMICAL AND PHYSICOCHEMICAL PROPERTIES