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Title: A study of polyether-polyol- and polyester-polyol-based rigid urethane foam systems

For the past 10 years polyurethane polymers have been one of the fastest growing segments of the plastics industry. Over 900 million pounds of polyurethanes were used in 1970. Approximately 30% of this amount was consumed in the form of rigid urethane foam products. This study undertakes a comparison of the properties of rigid urethane foams based on both a polyester polyol and polyether polyol of the same hydroxyl number prepared from alpha methylglucoside. This comparison of ester and ether polyols in urethane foams is closer than in previous studies because: (1) both types of polyols are based on alpha methylglucoside; (2) they both have the same hydroxyl number and functionality; and (3) the rigid foams in which they are used have been formulated to have essentially the same crosslink density. Several physical and thermal properties of the foam systems were determined. A discussion of test results as they relate to the presence of the ester and ether linkages in the polyols is presented.
 [1] ;  [1] ;  [1]
  1. Allied-Signal Aerospace Co., Kansas City, MO (United States). Kansas City Div.
Publication Date:
OSTI Identifier:
Report Number(s):
BDX--613-531; CONF--710913--1
ON: DE95003899;; TRN: AHC29502%%142
DOE Contract Number:
Resource Type:
Technical Report
Resource Relation:
Conference: 162. national meeting of the American Chemical Society,Washington, DC (United States),12-17 Sep 1971; Other Information: PBD: Sep 1971
Research Org:
Allied-Signal Aerospace Co., Kansas City, MO (United States). Kansas City Div.
Sponsoring Org:
USDOE, Washington, DC (United States)
Country of Publication:
United States
36 MATERIALS SCIENCE; PLASTIC FOAMS; COMPRESSION STRENGTH; THERMAL DEGRADATION; THERMODYNAMIC PROPERTIES; POLYURETHANES; COMPARATIVE EVALUATIONS; ELASTOMERS; POLYETHYLENE GLYCOLS; POLYESTERS; CROSS-LINKING; EXPERIMENTAL DATA; ACTIVATION ENERGY; MOLECULAR WEIGHT; OXIDATION Plastic Foams; Compression Strength; Thermal Degradation; Thermodynamic Properties; Polyurethanes; Comparative Evaluations; Elastomers; Polyethylene Glycols; Polyesters; Cross-Linking; Experimental Data; Activation Energy; Molecular Weight; Oxidation 360600; OTHER MATERIALS