A New Multidentate Hexacarboxylic Acid for the Construction of Porous Metal−Organic Frameworks of Diverse Structures and Porosities
- Fudan
Three porous metal-organic frameworks have been constructed from the new developed C3-symmetric hexacarboxylic acid 3,3{prime},3{double_prime},5,5{prime},5{double_prime}-benzene-1,3,5-triyl-hexabenzoic acid (H{sub 6}BHB) of different NaCl- and Al{sub 2}O{sub 3}-type topologies. The activated metal-organic frameworks (MOFs) exhibit permanent porosities as revealed in their gas and vapor adsorption isotherms, highlighting the promise of this new ligand for the construction of porous MOFs for gas storage and separation.
- Research Organization:
- Argonne National Lab. (ANL), Argonne, IL (United States). Advanced Photon Source (APS)
- Sponsoring Organization:
- USDOE
- OSTI ID:
- 1002548
- Journal Information:
- Cryst. Growth Des., Vol. 10, Issue (6) ; 06, 2010
- Country of Publication:
- United States
- Language:
- ENGLISH
Similar Records
Exciton Migration and Amplified Quenching on Two-Dimensional Metal–Organic Layers
Reticular exploration of uranium-based metal—organic frameworks with hexacarboxylate building units
An Isoreticular Series of Metal-Organic Frameworks with Dendritic Hexacarboxylate Ligands and Exceptionally High Gas-Uptake Capacity
Journal Article
·
Wed May 10 00:00:00 EDT 2017
· Journal of the American Chemical Society
·
OSTI ID:1002548
+5 more
Reticular exploration of uranium-based metal—organic frameworks with hexacarboxylate building units
Journal Article
·
Fri Feb 28 00:00:00 EST 2020
· Nano Research
·
OSTI ID:1002548
+7 more
An Isoreticular Series of Metal-Organic Frameworks with Dendritic Hexacarboxylate Ligands and Exceptionally High Gas-Uptake Capacity
Journal Article
·
Fri Oct 01 00:00:00 EDT 2010
· Angewandte Chemie (International Edition)
·
OSTI ID:1002548
+1 more