Stability of Electrodeposition at Solid-Solid Interfaces and Implications for Metal Anodes

Ahmad, Zeeshan; Viswanathan, Venkatasubramanian

doi:10.1103/physrevlett.119.056003

Title: Stability of Electrodeposition at Solid-Solid Interfaces and Implications for Metal Anodes

Abstract

We generalize the conditions for stable electrodeposition at isotropic solid-solid interfaces using a kinetic model which incorporates the effects of stresses and surface tension at the interface. We develop a stability diagram that shows two regimes of stability: a previously known pressure-driven mechanism and a new density-driven stability mechanism that is governed by the relative density of metal in the two phases. We show that inorganic solids and solid polymers generally do not lead to stable electrodeposition, and provide design guidelines for achieving stable electrodeposition.

Authors:

Ahmad, Zeeshan ^[1]; Viswanathan, Venkatasubramanian ^[1]

Carnegie Mellon Univ., Pittsburgh, PA (United States)

Publication Date:: Fri Aug 04 00:00:00 EDT 2017

Research Org.:: Carnegie Mellon Univ., Pittsburgh, PA (United States); 24M Technologies, Inc., Cambridge, MA (United States); Massachusetts Inst. of Technology (MIT), Cambridge, MA (United States)

Sponsoring Org.:: USDOE Advanced Research Projects Agency - Energy (ARPA-E); USDOE Office of Energy Efficiency and Renewable Energy (EERE), Transportation Office. Vehicle Technologies Office

OSTI Identifier:: 1881504

Alternate Identifier(s):: OSTI ID: 1374071; OSTI ID: 1536538

Grant/Contract Number:: AR0000774; EE0007810

Resource Type:: Accepted Manuscript

Journal Name:: Physical Review Letters

Additional Journal Information:: Journal Volume: 119; Journal Issue: 5; Journal ID: ISSN 0031-9007

Publisher:: American Physical Society (APS)

Country of Publication:: United States

Language:: English

Subject:: 75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND SUPERFLUIDITY; Electrochemical properties; Interface & surface thermodynamics; Batteries; Solid-solid interfaces

Citation Formats


                    Ahmad, Zeeshan, and Viswanathan, Venkatasubramanian. Stability of Electrodeposition at Solid-Solid Interfaces and Implications for Metal Anodes.  United States: N. p., 2017. 
Web.  doi:10.1103/physrevlett.119.056003.

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                    Ahmad, Zeeshan, & Viswanathan, Venkatasubramanian. Stability of Electrodeposition at Solid-Solid Interfaces and Implications for Metal Anodes.  United States.  https://doi.org/10.1103/physrevlett.119.056003

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                    Ahmad, Zeeshan, and Viswanathan, Venkatasubramanian. Fri .  
"Stability of Electrodeposition at Solid-Solid Interfaces and Implications for Metal Anodes".  United States.  https://doi.org/10.1103/physrevlett.119.056003.  https://www.osti.gov/servlets/purl/1881504.

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@article{osti_1881504,

  title        = {Stability of Electrodeposition at Solid-Solid Interfaces and Implications for Metal Anodes},

  author       = {Ahmad, Zeeshan and Viswanathan, Venkatasubramanian},

  abstractNote = {We generalize the conditions for stable electrodeposition at isotropic solid-solid interfaces using a kinetic model which incorporates the effects of stresses and surface tension at the interface. We develop a stability diagram that shows two regimes of stability: a previously known pressure-driven mechanism and a new density-driven stability mechanism that is governed by the relative density of metal in the two phases. We show that inorganic solids and solid polymers generally do not lead to stable electrodeposition, and provide design guidelines for achieving stable electrodeposition.},

  doi          = {10.1103/physrevlett.119.056003},

  journal      = {Physical Review Letters},

  number       = 5,

  volume       = 119,

  place        = {United States},

  year         = {Fri Aug 04 00:00:00 EDT 2017},

  month        = {Fri Aug 04 00:00:00 EDT 2017}

}

Copy to clipboard

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Title: Stability of Electrodeposition at Solid-Solid Interfaces and Implications for Metal Anodes

Abstract

Citation Formats

Interface morphology development during stress corrosion cracking: Part I. Via surface diffusion journal, July 1972

Revised effective ionic radii and systematic studies of interatomic distances in halides and chalcogenides journal, September 1976

Charting the complete elastic properties of inorganic crystalline compounds journal, March 2015

Dendritic and Fractal Patterns in Electrolytic Metal Deposits journal, March 1986

Anomalous Scaling of the Surface Width during Cu Electrodeposition text, January 2001

Electrochemical aspects of the generation of ramified metallic electrodeposits journal, December 1990

Crystallography Open Database – an open-access collection of crystal structures journal, May 2009

Electrolytes for high-energy lithium batteries journal, December 2011

Self-Similarity of Diffusion-Limited Aggregates and Electrodeposition Clusters journal, November 1988

The surface energy of metals journal, August 1998

Stress-Driven Phase Transformation and the Roughening of Solid-Solid Interfaces journal, March 2008

Computer simulations of dense-branching patterns journal, November 1993

The Impact of Elastic Deformation on Deposition Kinetics at Lithium/Polymer Interfaces journal, January 2005

Towards High-Safe Lithium Metal Anodes: Suppressing Lithium Dendrites via Tuning Surface Energy journal, July 2016

Lithium metal anodes for rechargeable batteries journal, January 2014

Stabilizing electrodeposition in elastic solid electrolytes containing immobilized anions journal, July 2016

The Effect of Interfacial Deformation on Electrodeposition Kinetics journal, January 2004

Fractal Structures of Zinc Metal Leaves Grown by Electrodeposition journal, July 1984

The electrolytic growth of dendrites from ionic solutions journal, August 1962

Morphology of grain growth in response to diffusion induced elastic stresses: cubic systems journal, May 1993

Resolution of the Modulus versus Adhesion Dilemma in Solid Polymer Electrolytes for Rechargeable Lithium Metal Batteries journal, January 2012

Thin Film Materials book, July 2010

A short review of failure mechanisms of lithium metal and lithiated graphite anodes in liquid electrolyte solutions journal, June 2002

Elastic Properties of Alkali Superionic Conductor Electrolytes from First Principles Calculations journal, November 2015

Morphological Stability of a Particle Growing by Diffusion or Heat Flow journal, February 1963

Computer Simulation of Dendritic Electrodeposition journal, January 1985

Singularities in nonlocal interface dynamics journal, November 1984

Influence of Electrolyte Modulus on the Local Current Density at a Dendrite Tip on a Lithium Metal Electrode journal, January 2016

Commentary: The Materials Project: A materials genome approach to accelerating materials innovation journal, July 2013

Anomalous Scaling of the Surface Width during Cu Electrodeposition journal, January 2001

Thermodynamics and roughening of solid-solid interfaces journal, March 2009

Fingerlike Aggregates in Thin-Layer Electrodeposition journal, May 1996

Design principles for electrolytes and interfaces for stable lithium-metal batteries journal, September 2016

Stability of a Planar Interface During Solidification of a Dilute Binary Alloy journal, February 1964

Standard Partial Molar Volumes of Electrolytes and Ions in Nonaqueous Solvents journal, July 2004

Ion volumes: a comparison journal, September 2002

Current-Voltage Relations for Electrochemical Thin Films journal, January 2005

Stress-driven phase transformation and the roughening of solid-solid interfaces text, January 2007

Electrodeposited Multilayer Thin Films journal, August 1994

Direct observation of lithium dendrites inside garnet-type lithium-ion solid electrolyte journal, August 2015

Interplay of capillary and elastic driving forces during microstructural evolution: Applications of a digital image model journal, April 1998

Quantifying the promise of ‘beyond’ Li–ion batteries journal, November 2015

Electro–Chemo–Mechanical Issues at the Interfaces in Solid‐State Lithium Metal Batteries journal, April 2019

Nonequilibrium Theory of Epigenomic Microphase Separation in the Cell Nucleus text, January 2019

Fundamentals of inorganic solid-state electrolytes for batteries journal, August 2019

Electroconvection and Morphological Instabilities in Potentiostatic Electrodeposition across Liquid Electrolytes with Polymer Additives journal, January 2018

Metal Electrode Surfaces Can Roughen Despite the Constraint of a Stiff Electrolyte journal, January 2019

Mechanical Stress Induced Current Focusing and Fracture in Grain Boundaries journal, January 2019

Integrating transposable elements in the 3D genome journal, February 2020

Stress-driven lithium dendrite growth mechanism and dendrite mitigation by electroplating on soft substrates journal, March 2018

Disentangling lattice and electronic contributions to the metal–insulator transition from bulk vs. layer confined RNiO 3 journal, July 2019

Magnetic Polymer Models for Epigenomic Organisation and Phase Separation text, January 2018

Linear stability analysis of transient electrodeposition in charged porous media: suppression of dendritic growth by surface conduction text, January 2019

Machine Learning Enabled Computational Screening of Inorganic Solid Electrolytes for Suppression of Dendrite Formation in Lithium Metal Anodes journal, August 2018

Interface morphology development during stress corrosion cracking: Part I. Via surface diffusion
journal, July 1972

Revised effective ionic radii and systematic studies of interatomic distances in halides and chalcogenides
journal, September 1976

Charting the complete elastic properties of inorganic crystalline compounds
journal, March 2015

Dendritic and Fractal Patterns in Electrolytic Metal Deposits
journal, March 1986

Anomalous Scaling of the Surface Width during Cu Electrodeposition
text, January 2001

Electrochemical aspects of the generation of ramified metallic electrodeposits
journal, December 1990

Crystallography Open Database – an open-access collection of crystal structures
journal, May 2009

Electrolytes for high-energy lithium batteries
journal, December 2011

Self-Similarity of Diffusion-Limited Aggregates and Electrodeposition Clusters
journal, November 1988

The surface energy of metals
journal, August 1998

Stress-Driven Phase Transformation and the Roughening of Solid-Solid Interfaces
journal, March 2008

Computer simulations of dense-branching patterns
journal, November 1993

The Impact of Elastic Deformation on Deposition Kinetics at Lithium/Polymer Interfaces
journal, January 2005

Towards High-Safe Lithium Metal Anodes: Suppressing Lithium Dendrites via Tuning Surface Energy
journal, July 2016

Lithium metal anodes for rechargeable batteries
journal, January 2014

Stabilizing electrodeposition in elastic solid electrolytes containing immobilized anions
journal, July 2016

The Effect of Interfacial Deformation on Electrodeposition Kinetics
journal, January 2004

Fractal Structures of Zinc Metal Leaves Grown by Electrodeposition
journal, July 1984

The electrolytic growth of dendrites from ionic solutions
journal, August 1962

Morphology of grain growth in response to diffusion induced elastic stresses: cubic systems
journal, May 1993

Resolution of the Modulus versus Adhesion Dilemma in Solid Polymer Electrolytes for Rechargeable Lithium Metal Batteries
journal, January 2012

Thin Film Materials
book, July 2010

A short review of failure mechanisms of lithium metal and lithiated graphite anodes in liquid electrolyte solutions
journal, June 2002

Elastic Properties of Alkali Superionic Conductor Electrolytes from First Principles Calculations
journal, November 2015

Morphological Stability of a Particle Growing by Diffusion or Heat Flow
journal, February 1963

Computer Simulation of Dendritic Electrodeposition
journal, January 1985

Singularities in nonlocal interface dynamics
journal, November 1984

Influence of Electrolyte Modulus on the Local Current Density at a Dendrite Tip on a Lithium Metal Electrode
journal, January 2016

Commentary: The Materials Project: A materials genome approach to accelerating materials innovation
journal, July 2013

Anomalous Scaling of the Surface Width during Cu Electrodeposition
journal, January 2001

Thermodynamics and roughening of solid-solid interfaces
journal, March 2009

Fingerlike Aggregates in Thin-Layer Electrodeposition
journal, May 1996

Design principles for electrolytes and interfaces for stable lithium-metal batteries
journal, September 2016

Stability of a Planar Interface During Solidification of a Dilute Binary Alloy
journal, February 1964

Standard Partial Molar Volumes of Electrolytes and Ions in Nonaqueous Solvents
journal, July 2004

Ion volumes: a comparison
journal, September 2002

Current-Voltage Relations for Electrochemical Thin Films
journal, January 2005

Stress-driven phase transformation and the roughening of solid-solid interfaces
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Electrodeposited Multilayer Thin Films
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Direct observation of lithium dendrites inside garnet-type lithium-ion solid electrolyte
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Interplay of capillary and elastic driving forces during microstructural evolution: Applications of a digital image model
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Quantifying the promise of ‘beyond’ Li–ion batteries
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Electro–Chemo–Mechanical Issues at the Interfaces in Solid‐State Lithium Metal Batteries
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Nonequilibrium Theory of Epigenomic Microphase Separation in the Cell Nucleus
text, January 2019

Fundamentals of inorganic solid-state electrolytes for batteries
journal, August 2019

Electroconvection and Morphological Instabilities in Potentiostatic Electrodeposition across Liquid Electrolytes with Polymer Additives
journal, January 2018

Metal Electrode Surfaces Can Roughen Despite the Constraint of a Stiff Electrolyte
journal, January 2019

Mechanical Stress Induced Current Focusing and Fracture in Grain Boundaries
journal, January 2019

Integrating transposable elements in the 3D genome
journal, February 2020

Stress-driven lithium dendrite growth mechanism and dendrite mitigation by electroplating on soft substrates
journal, March 2018

Disentangling lattice and electronic contributions to the metal–insulator transition from bulk vs. layer confined RNiO ₃
journal, July 2019

Magnetic Polymer Models for Epigenomic Organisation and Phase Separation
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Linear stability analysis of transient electrodeposition in charged porous media: suppression of dendritic growth by surface conduction
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Machine Learning Enabled Computational Screening of Inorganic Solid Electrolytes for Suppression of Dendrite Formation in Lithium Metal Anodes
journal, August 2018