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Title: Gradient cell–structured high-entropy alloy with exceptional strength and ductility

Abstract

We report that similar to conventional materials, most multicomponent high-entropy alloys (HEAs) lose ductility as they gain strength. In this study, we controllably introduced gradient nanoscaled dislocation cell structures in a stable single-phase HEA with face-centered cubic structure, thus resulting in enhanced strength without apparent loss of ductility. Upon application of strain, the sample-level structural gradient induces progressive formation of a high density of tiny stacking faults (SFs) and twins, nucleating from abundant low-angle dislocation cells. Furthermore, the SF-induced plasticity and the resultant refined structures, coupled with intensively accumulated dislocations, contribute to plasticity, increased strength, and work hardening. These findings offer a promising paradigm for tailoring properties with gradient dislocation cells at the nanoscale and advance our fundamental understanding of the intrinsic deformation behavior of HEAs.

Authors:
ORCiD logo [1]; ORCiD logo [2]; ORCiD logo [3]; ORCiD logo [1]; ORCiD logo [3]; ORCiD logo [4]; ORCiD logo [3]; ORCiD logo [5]; ORCiD logo [1]
  1. Chinese Academy of Sciences (CAS), Shenyang (China)
  2. Chinese Academy of Sciences (CAS), Shenyang (China); Univ. of Science and Technology of China, Shenyang
  3. Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
  4. Argonne National Lab. (ANL), Lemont, IL (United States)
  5. Univ. of Tennessee, Knoxville, TN (United States)
Publication Date:
Research Org.:
Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States); Argonne National Laboratory (ANL), Argonne, IL (United States)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES); National Science Foundation of China; Frontier Science and International partnership; Youth Innovation Promotion Association; Chinese Academy of Sciences (CAS); LiaoNing Revitalization Talents Program; National Science Foundation (NSF); US Army Research Office
OSTI Identifier:
1878719
Alternate Identifier(s):
OSTI ID: 1869780
Grant/Contract Number:  
AC05-00OR22725; AC02-06CH11357; 51931010; 92163202; 52122104; 52071321; GJHZ2029; 2019196; XLYC1802026; DMR-1611180; DMR-1809640; W911NF-13-1-0438; W911NF-19-2-0049
Resource Type:
Accepted Manuscript
Journal Name:
Science
Additional Journal Information:
Journal Volume: 374; Journal Issue: 6570; Journal ID: ISSN 0036-8075
Publisher:
AAAS
Country of Publication:
United States
Language:
English
Subject:
36 MATERIALS SCIENCE; deformation; high entropy alloy

Citation Formats

Pan, Qingsong, Zhang, Liangxue, Feng, Rui, Lu, Qiuhong, An, Ke, Chuang, Andrew Chihpin, Poplawsky, Jonathan D., Liaw, Peter K., and Lu, Lei. Gradient cell–structured high-entropy alloy with exceptional strength and ductility. United States: N. p., 2021. Web. doi:10.1126/science.abj8114.
Pan, Qingsong, Zhang, Liangxue, Feng, Rui, Lu, Qiuhong, An, Ke, Chuang, Andrew Chihpin, Poplawsky, Jonathan D., Liaw, Peter K., & Lu, Lei. Gradient cell–structured high-entropy alloy with exceptional strength and ductility. United States. https://doi.org/10.1126/science.abj8114
Pan, Qingsong, Zhang, Liangxue, Feng, Rui, Lu, Qiuhong, An, Ke, Chuang, Andrew Chihpin, Poplawsky, Jonathan D., Liaw, Peter K., and Lu, Lei. Thu . "Gradient cell–structured high-entropy alloy with exceptional strength and ductility". United States. https://doi.org/10.1126/science.abj8114. https://www.osti.gov/servlets/purl/1878719.
@article{osti_1878719,
title = {Gradient cell–structured high-entropy alloy with exceptional strength and ductility},
author = {Pan, Qingsong and Zhang, Liangxue and Feng, Rui and Lu, Qiuhong and An, Ke and Chuang, Andrew Chihpin and Poplawsky, Jonathan D. and Liaw, Peter K. and Lu, Lei},
abstractNote = {We report that similar to conventional materials, most multicomponent high-entropy alloys (HEAs) lose ductility as they gain strength. In this study, we controllably introduced gradient nanoscaled dislocation cell structures in a stable single-phase HEA with face-centered cubic structure, thus resulting in enhanced strength without apparent loss of ductility. Upon application of strain, the sample-level structural gradient induces progressive formation of a high density of tiny stacking faults (SFs) and twins, nucleating from abundant low-angle dislocation cells. Furthermore, the SF-induced plasticity and the resultant refined structures, coupled with intensively accumulated dislocations, contribute to plasticity, increased strength, and work hardening. These findings offer a promising paradigm for tailoring properties with gradient dislocation cells at the nanoscale and advance our fundamental understanding of the intrinsic deformation behavior of HEAs.},
doi = {10.1126/science.abj8114},
journal = {Science},
number = 6570,
volume = 374,
place = {United States},
year = {Thu Sep 23 00:00:00 EDT 2021},
month = {Thu Sep 23 00:00:00 EDT 2021}
}

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