Tunable Broad Light Emission from 3D “Hollow” Bromide Perovskites through Defect Engineering
Abstract
We report hybrid halide perovskites consisting of corner-sharing metal halide octahedra and small cuboctahedral cages filled with counter cations have proven to be prominent candidates for many high-performance optoelectronic devices. The stability limits of their three-dimensional perovskite framework are defined by the size range of the cations present in the cages of the structure. In some cases, the stability of the perovskite-type structure can be extended even when the counterions violate the size and shape requirements, as is the case in the so-called "hollow" perovskites. In this work, we engineered a new family of 3D highly defective yet crystalline "hollow" bromide perovskites with general formula (FA)1-x(en)x(Pb)1-0.7x(Br)3-0.4x (FA = formamidinium (FA+), en = ethylenediammonium (en2+), x = 0-0.44). Pair distribution function analysis shed light on the local structural coherence, revealing a wide distribution of Pb-Pb distances in the crystal structure as a consequence of the Pb/Br-deficient nature and en inclusion in the lattice. By manipulating the number of Pb/Br vacancies, we finely tune the optical properties of the pristine FAPbBr3 by blue shifting the band gap from 2.20 to 2.60 eV for the x = 0.42 en sample. A most unexpected outcome was that at x > 0.33 en incorporation, themore »
- Authors:
-
[1];
[1];
[1];
[2];
[3];
[3];
[4];
[1];
[1];
[3];
[1]
- Northwestern Univ., Evanston, IL (United States)
- Argonne National Lab. (ANL), Lemont, IL (United States)
- Univ. of California, Santa Barbara, CA (United States)
- Univ. Lille (France)
- Publication Date:
- Research Org.:
- Argonne National Lab. (ANL), Argonne, IL (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES); National Science Foundation (NSF); European Union (EU)
- OSTI Identifier:
- 1864311
- Grant/Contract Number:
- AC02-06CH11357; SC0012541; DMR-1720139; ECCS-1542205; DMR-1720256; 795091; IR-RMN-THC-FR-3050 CNRS
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Journal of the American Chemical Society
- Additional Journal Information:
- Journal Volume: 143; Journal Issue: 18; Journal ID: ISSN 0002-7863
- Publisher:
- American Chemical Society (ACS)
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; anions; cations; crystal structure; diffraction; perovskites
Citation Formats
Spanopoulos, Ioannis, Hadar, Ido, Ke, Weijun, Guo, Peijun, Mozur, Eve M., Morgan, Emily, Wang, Shuxin, Zheng, Ding, Padgaonkar, Suyog, Manjunatha Reddy, G. N., Weiss, Emily A., Hersam, Mark C., Seshadri, Ram, Schaller, Richard D., and Kanatzidis, Mercouri G. Tunable Broad Light Emission from 3D “Hollow” Bromide Perovskites through Defect Engineering. United States: N. p., 2021.
Web. doi:10.1021/jacs.1c01727.
Spanopoulos, Ioannis, Hadar, Ido, Ke, Weijun, Guo, Peijun, Mozur, Eve M., Morgan, Emily, Wang, Shuxin, Zheng, Ding, Padgaonkar, Suyog, Manjunatha Reddy, G. N., Weiss, Emily A., Hersam, Mark C., Seshadri, Ram, Schaller, Richard D., & Kanatzidis, Mercouri G. Tunable Broad Light Emission from 3D “Hollow” Bromide Perovskites through Defect Engineering. United States. https://doi.org/10.1021/jacs.1c01727
Spanopoulos, Ioannis, Hadar, Ido, Ke, Weijun, Guo, Peijun, Mozur, Eve M., Morgan, Emily, Wang, Shuxin, Zheng, Ding, Padgaonkar, Suyog, Manjunatha Reddy, G. N., Weiss, Emily A., Hersam, Mark C., Seshadri, Ram, Schaller, Richard D., and Kanatzidis, Mercouri G. Tue .
"Tunable Broad Light Emission from 3D “Hollow” Bromide Perovskites through Defect Engineering". United States. https://doi.org/10.1021/jacs.1c01727. https://www.osti.gov/servlets/purl/1864311.
@article{osti_1864311,
title = {Tunable Broad Light Emission from 3D “Hollow” Bromide Perovskites through Defect Engineering},
author = {Spanopoulos, Ioannis and Hadar, Ido and Ke, Weijun and Guo, Peijun and Mozur, Eve M. and Morgan, Emily and Wang, Shuxin and Zheng, Ding and Padgaonkar, Suyog and Manjunatha Reddy, G. N. and Weiss, Emily A. and Hersam, Mark C. and Seshadri, Ram and Schaller, Richard D. and Kanatzidis, Mercouri G.},
abstractNote = {We report hybrid halide perovskites consisting of corner-sharing metal halide octahedra and small cuboctahedral cages filled with counter cations have proven to be prominent candidates for many high-performance optoelectronic devices. The stability limits of their three-dimensional perovskite framework are defined by the size range of the cations present in the cages of the structure. In some cases, the stability of the perovskite-type structure can be extended even when the counterions violate the size and shape requirements, as is the case in the so-called "hollow" perovskites. In this work, we engineered a new family of 3D highly defective yet crystalline "hollow" bromide perovskites with general formula (FA)1-x(en)x(Pb)1-0.7x(Br)3-0.4x (FA = formamidinium (FA+), en = ethylenediammonium (en2+), x = 0-0.44). Pair distribution function analysis shed light on the local structural coherence, revealing a wide distribution of Pb-Pb distances in the crystal structure as a consequence of the Pb/Br-deficient nature and en inclusion in the lattice. By manipulating the number of Pb/Br vacancies, we finely tune the optical properties of the pristine FAPbBr3 by blue shifting the band gap from 2.20 to 2.60 eV for the x = 0.42 en sample. A most unexpected outcome was that at x > 0.33 en incorporation, the material exhibits strong broad light emission (1% photoluminescence quantum yield (PLQY)) that is maintained after exposure to air for more than a year. This is the first example of strong broad light emission from a 3D hybrid halide perovskite, demonstrating that meticulous defect engineering is an excellent tool for customizing the optical properties of these semiconductors.},
doi = {10.1021/jacs.1c01727},
journal = {Journal of the American Chemical Society},
number = 18,
volume = 143,
place = {United States},
year = {Tue Apr 27 00:00:00 EDT 2021},
month = {Tue Apr 27 00:00:00 EDT 2021}
}
Free Publicly Available Full Text
Publisher's Version of Record
Other availability
Search WorldCat to find libraries that may hold this journal
Save to My Library
You must Sign In or Create an Account in order to save documents to your library.
Works referenced in this record:
Intriguing Optoelectronic Properties of Metal Halide Perovskites
journal, June 2016
- Manser, Joseph S.; Christians, Jeffrey A.; Kamat, Prashant V.
- Chemical Reviews, Vol. 116, Issue 21
Reentrant Structural and Optical Properties and Large Positive Thermal Expansion in Perovskite Formamidinium Lead Iodide
journal, November 2016
- Fabini, Douglas H.; Stoumpos, Constantinos C.; Laurita, Geneva
- Angewandte Chemie International Edition, Vol. 55, Issue 49
One-dimensional organic lead halide perovskites with efficient bluish white-light emission
journal, January 2017
- Yuan, Zhao; Zhou, Chenkun; Tian, Yu
- Nature Communications, Vol. 8, Issue 1
Crystal and Magnetic Structures of Ca 4 Mn 3 O 10 , an n = 3 Ruddlesden−Popper Compound
journal, February 1998
- Battle, P. D.; Green, M. A.; Lago, J.
- Chemistry of Materials, Vol. 10, Issue 2
Photophysics in Cs 3 Cu 2 X 5 (X = Cl, Br, or I): Highly Luminescent Self-Trapped Excitons from Local Structure Symmetrization
journal, March 2020
- Lian, Linyuan; Zheng, Moyan; Zhang, Peng
- Chemistry of Materials, Vol. 32, Issue 8
Tuning Ionic and Electronic Conductivities in the “Hollow” Perovskite { en }MAPbI 3
journal, January 2021
- Senocrate, Alessandro; Spanopoulos, Ioannis; Zibouche, Nourdine
- Chemistry of Materials, Vol. 33, Issue 2
Defect Tolerance and Intolerance in Metal‐Halide Perovskites
journal, August 2020
- Kim, Guan‐Woo; Petrozza, Annamaria
- Advanced Energy Materials, Vol. 10, Issue 37
Beyond crystallography: the study of disorder, nanocrystallinity and crystallographically challenged materials with pair distribution functions
journal, January 2004
- Billinge, Simon J. L.; Kanatzidis, M. G.
- Chemical Communications, Issue 7
Cesium Substitution Disrupts Concerted Cation Dynamics in Formamidinium Hybrid Perovskites
journal, May 2020
- Mozur, Eve M.; Hope, Michael A.; Trowbridge, Julia C.
- Chemistry of Materials, Vol. 32, Issue 14
The Renaissance of Halide Perovskites and Their Evolution as Emerging Semiconductors
journal, September 2015
- Stoumpos, Constantinos C.; Kanatzidis, Mercouri G.
- Accounts of Chemical Research, Vol. 48, Issue 10
Prospects for LED lighting
journal, April 2009
- Pimputkar, Siddha; Speck, James S.; DenBaars, Steven P.
- Nature Photonics, Vol. 3, Issue 4
Structure-Dependent Photoluminescence in Low-Dimensional Ethylammonium, Propylammonium, and Butylammonium Lead Iodide Perovskites
journal, December 2019
- Lin, Chang-Wei; Liu, Fangzhou; Chen, Ting-Yang
- ACS Applied Materials & Interfaces, Vol. 12, Issue 4
Exciton Self-Trapping in Hybrid Lead Halides: Role of Halogen
journal, July 2019
- Gautier, Romain; Paris, Michael; Massuyeau, Florian
- Journal of the American Chemical Society, Vol. 141, Issue 32
Structural Diversity in White-Light-Emitting Hybrid Lead Bromide Perovskites
journal, September 2018
- Mao, Lingling; Guo, Peijun; Kepenekian, Mikaël
- Journal of the American Chemical Society, Vol. 140, Issue 40
Structures, Phase Transitions and Tricritical Behavior of the Hybrid Perovskite Methyl Ammonium Lead Iodide
journal, October 2016
- Whitfield, P. S.; Herron, N.; Guise, W. E.
- Scientific Reports, Vol. 6, Issue 1
Efficient perovskite light-emitting diodes featuring nanometre-sized crystallites
journal, January 2017
- Xiao, Zhengguo; Kerner, Ross A.; Zhao, Lianfeng
- Nature Photonics, Vol. 11, Issue 2
Phase Behavior and Polymorphism of Formamidinium Lead Iodide
journal, May 2018
- Weber, Oliver J.; Ghosh, Dibyajyoti; Gaines, Sam
- Chemistry of Materials, Vol. 30, Issue 11
Orange to Red, Emission-Tunable Mn-Doped Two-Dimensional Perovskites with High Luminescence and Stability
journal, August 2019
- Sun, Chun; Gao, Zhiyuan; Deng, Yuchen
- ACS Applied Materials & Interfaces, Vol. 11, Issue 37
Geometry Distortion and Small Polaron Binding Energy Changes with Ionic Substitution in Halide Perovskites
journal, December 2018
- Neukirch, Amanda J.; Abate, Iwnetim I.; Zhou, Liujiang
- The Journal of Physical Chemistry Letters, Vol. 9, Issue 24
Low-bandgap mixed tin–lead iodide perovskite absorbers with long carrier lifetimes for all-perovskite tandem solar cells
journal, March 2017
- Zhao, Dewei; Yu, Yue; Wang, Changlei
- Nature Energy, Vol. 2, Issue 4
Proton Irradiation Tolerance of High-Efficiency Perovskite Absorbers for Space Applications
journal, October 2019
- Kanaya, Shusaku; Kim, Gyu Min; Ikegami, Masashi
- The Journal of Physical Chemistry Letters, Vol. 10, Issue 22
Tackling the Defects, Stability, and Photoluminescence of CsPbX 3 Perovskite Nanocrystals
journal, June 2019
- Seth, Sudipta; Ahmed, Tasnim; De, Apurba
- ACS Energy Letters, Vol. 4, Issue 7
Organic–Inorganic Perovskites: Structural Versatility for Functional Materials Design
journal, March 2016
- Saparov, Bayrammurad; Mitzi, David B.
- Chemical Reviews, Vol. 116, Issue 7
Molecular‐Level Insight into Correlation between Surface Defects and Stability of Methylammonium Lead Halide Perovskite Under Controlled Humidity
journal, November 2020
- Akhavan Kazemi, Mohammad Ali; Raval, Parth; Cherednichekno, Kirill
- Small Methods, Vol. 5, Issue 2
Enhanced Stability and Band Gap Tuning of α-[HC(NH 2 ) 2 ]PbI 3 Hybrid Perovskite by Large Cation Integration
journal, May 2019
- Leblanc, Antonin; Mercier, Nicolas; Allain, Magali
- ACS Applied Materials & Interfaces, Vol. 11, Issue 23
Synthesis, optoelectronic properties and applications of halide perovskites
journal, January 2020
- Chouhan, Lata; Ghimire, Sushant; Subrahmanyam, Challapalli
- Chemical Society Reviews, Vol. 49, Issue 10
Aqueous acid-based synthesis of lead-free tin halide perovskites with near-unity photoluminescence quantum efficiency
journal, January 2019
- Wang, Aifei; Guo, Yanyan; Zhou, Zhaobo
- Chemical Science, Vol. 10, Issue 17
Efficient and stable emission of warm-white light from lead-free halide double perovskites
journal, November 2018
- Luo, Jiajun; Wang, Xiaoming; Li, Shunran
- Nature, Vol. 563, Issue 7732
Structural origins of broadband emission from layered Pb–Br hybrid perovskites
journal, January 2017
- Smith, Matthew D.; Jaffe, Adam; Dohner, Emma R.
- Chemical Science, Vol. 8, Issue 6
Applications of pair distribution function methods to contemporary problems in materials chemistry
journal, January 2011
- Young, Callum A.; Goodwin, Andrew L.
- Journal of Materials Chemistry, Vol. 21, Issue 18
Defects in halide perovskites: The lattice as a boojum?
journal, June 2020
- Kumar, Sujit; Hodes, Gary; Cahen, David
- MRS Bulletin, Vol. 45, Issue 6
Lead halide inorganic–organic hybrids incorporating diammonium cations
journal, January 2012
- Lemmerer, Andreas; Billing, David G.
- CrystEngComm, Vol. 14, Issue 6
Insight into the structures and dynamics of organic semiconductors through solid-state NMR spectroscopy
journal, September 2020
- Seifrid, Martin; Reddy, G. N. Manjunatha; Chmelka, Bradley F.
- Nature Reviews Materials
Halide Perovskites: Poor Man's High-Performance Semiconductors
journal, May 2016
- Stoumpos, Constantinos C.; Kanatzidis, Mercouri G.
- Advanced Materials, Vol. 28, Issue 28
Solution‐Processable Perovskite Solar Cells toward Commercialization: Progress and Challenges
journal, April 2019
- Wang, Peng; Wu, Yihui; Cai, Bing
- Advanced Functional Materials, Vol. 29, Issue 47
Ruddlesden–Popper Hybrid Lead Iodide Perovskite 2D Homologous Semiconductors
journal, April 2016
- Stoumpos, Constantinos C.; Cao, Duyen H.; Clark, Daniel J.
- Chemistry of Materials, Vol. 28, Issue 8, p. 2852-2867
Superior Photovoltaic Properties of Lead Halide Perovskites: Insights from First-Principles Theory
journal, February 2015
- Yin, Wan-Jian; Shi, Tingting; Yan, Yanfa
- The Journal of Physical Chemistry C, Vol. 119, Issue 10
Control of Crystal Structures and Optical Properties with Hybrid Formamidinium and 2-Hydroxyethylammonium Cations for Mesoscopic Carbon-Electrode Tin-Based Perovskite Solar Cells
journal, August 2018
- Tsai, Cheng-Min; Lin, Yu-Pei; Pola, Murali Krishna
- ACS Energy Letters, Vol. 3, Issue 9
Variable dimensionality in ‘hollow’ hybrid tin iodide perovskites
journal, January 2020
- McNulty, Jason A.; Slawin, Alexandra M. Z.; Lightfoot, Philip
- Dalton Transactions, Vol. 49, Issue 43
Radiative lifetime-encoded unicolour security tags using perovskite nanocrystals
journal, February 2021
- Yakunin, Sergii; Chaaban, Jana; Benin, Bogdan M.
- Nature Communications, Vol. 12, Issue 1
Crystal Structure and Photoconductivity of Cæsium Plumbohalides
journal, November 1958
- MØLler, Chr. Kn.
- Nature, Vol. 182, Issue 4647
Ethylenediammonium-Based “Hollow” Pb/Sn Perovskites with Ideal Band Gap Yield Solar Cells with Higher Efficiency and Stability
journal, May 2019
- Ke, Weijun; Spanopoulos, Ioannis; Tu, Qing
- Journal of the American Chemical Society, Vol. 141, Issue 21
Phase Stability, Phase Transformation Kinetics, and Conductivity of Y2O3-Bi2O3 Solid Electrolytes Containing Aliovalent Dopants
journal, August 1991
- Fung, Kuan Zong; Virkar, Anil V.
- Journal of the American Ceramic Society, Vol. 74, Issue 8
Semiconducting Tin and Lead Iodide Perovskites with Organic Cations: Phase Transitions, High Mobilities, and Near-Infrared Photoluminescent Properties
journal, July 2013
- Stoumpos, Constantinos C.; Malliakas, Christos D.; Kanatzidis, Mercouri G.
- Inorganic Chemistry, Vol. 52, Issue 15, p. 9019-9038
Electron-hole diffusion lengths > 175 μm in solution-grown CH 3 NH 3 PbI 3 single crystals
journal, January 2015
- Dong, Qingfeng; Fang, Yanjun; Shao, Yuchuan
- Science, Vol. 347, Issue 6225
Defect Engineering in 2D Perovskite by Mn(II) Doping for Light-Emitting Applications
journal, August 2019
- Cortecchia, Daniele; Mróz, Wojciech; Neutzner, Stefanie
- Chem, Vol. 5, Issue 8
Local Structure of Disordered Bi 0.5 K 0.5 TiO 3 Investigated by Pair Distribution Function Analysis and First-Principles Calculations
journal, May 2017
- Jiang, Bo; Grande, Tor; Selbach, Sverre M.
- Chemistry of Materials, Vol. 29, Issue 10
Highly Efficient Broadband Yellow Phosphor Based on Zero-Dimensional Tin Mixed-Halide Perovskite
journal, December 2017
- Zhou, Chenkun; Tian, Yu; Yuan, Zhao
- ACS Applied Materials & Interfaces, Vol. 9, Issue 51
Uniaxial Expansion of the 2D Ruddlesden–Popper Perovskite Family for Improved Environmental Stability
journal, March 2019
- Spanopoulos, Ioannis; Hadar, Ido; Ke, Weijun
- Journal of the American Chemical Society, Vol. 141, Issue 13
Thermal quenching of photoluminescence in Ga(AsBi)
journal, January 2015
- Shakfa, M. K.; Wiemer, M.; Ludewig, P.
- Journal of Applied Physics, Vol. 117, Issue 2
Morphology-Independent Stable White-Light Emission from Self-Assembled Two-Dimensional Perovskites Driven by Strong Exciton–Phonon Coupling to the Organic Framework
journal, April 2017
- Thirumal, Krishnamoorthy; Chong, Wee Kiang; Xie, Wei
- Chemistry of Materials, Vol. 29, Issue 9
Perovskite and Organic Solar Cells on a Rocket Flight
journal, September 2020
- Reb, Lennart K.; Böhmer, Michael; Predeschly, Benjamin
- Joule, Vol. 4, Issue 9
Structural Evolution in Methylammonium Lead Iodide CH 3 NH 3 PbI 3
journal, October 2015
- Ong, Khuong P.; Goh, Teck Wee; Xu, Qiang
- The Journal of Physical Chemistry A, Vol. 119, Issue 44
Atomic-level passivation mechanism of ammonium salts enabling highly efficient perovskite solar cells
journal, July 2019
- Alharbi, Essa A.; Alyamani, Ahmed Y.; Kubicki, Dominik J.
- Nature Communications, Vol. 10, Issue 1
Probing the energy levels of perovskite solar cells via Kelvin probe and UV ambient pressure photoemission spectroscopy
journal, January 2016
- Harwell, J. R.; Baikie, T. K.; Baikie, I. D.
- Physical Chemistry Chemical Physics, Vol. 18, Issue 29
Tunable Near-Infrared Luminescence in Tin Halide Perovskite Devices
journal, June 2016
- Lai, May L.; Tay, Timothy Y. S.; Sadhanala, Aditya
- The Journal of Physical Chemistry Letters, Vol. 7, Issue 14
Broadband Defects Emission and Enhanced Ligand Raman Scattering in 0D Cs 3 Bi 2 I 9 Colloidal Nanocrystals
journal, November 2018
- Paternò, Giuseppe M.; Mishra, Nimai; Barker, Alex J.
- Advanced Functional Materials, Vol. 29, Issue 21
Defect configuration and phase stability of cubic versus tetragonal yttria-stabilized zirconia
journal, May 2012
- Ding, Hepeng; Virkar, Anil V.; Liu, Feng
- Solid State Ionics, Vol. 215
Low-frequency lattice phonons in halide perovskites explain high defect tolerance toward electron-hole recombination
journal, February 2020
- Chu, Weibin; Zheng, Qijing; Prezhdo, Oleg V.
- Science Advances, Vol. 6, Issue 7
Nouvelles familles de phases MIMII2Nb3O10 a feuillets “perovskites”
journal, November 1981
- Dion, Michel; Ganne, Marcel; Tournoux, Michel
- Materials Research Bulletin, Vol. 16, Issue 11
Understanding the physical properties of hybrid perovskites for photovoltaic applications
journal, July 2017
- Huang, Jinsong; Yuan, Yongbo; Shao, Yuchuan
- Nature Reviews Materials, Vol. 2, Issue 7
Hollow metal halide perovskite nanocrystals with efficient blue emissions
journal, April 2020
- Worku, Michael; Tian, Yu; Zhou, Chenkun
- Science Advances, Vol. 6, Issue 17
Enhanced photovoltaic performance and stability with a new type of hollow 3D perovskite {en}FASnI 3
journal, August 2017
- Ke, Weijun; Stoumpos, Constantinos C.; Zhu, Menghua
- Science Advances, Vol. 3, Issue 8
Solid-State NMR and NQR Spectroscopy of Lead-Halide Perovskite Materials
journal, September 2020
- Piveteau, Laura; Morad, Viktoriia; Kovalenko, Maksym V.
- Journal of the American Chemical Society, Vol. 142, Issue 46
Hybrid Dion–Jacobson 2D Lead Iodide Perovskites
journal, February 2018
- Mao, Lingling; Ke, Weijun; Pedesseau, Laurent
- Journal of the American Chemical Society, Vol. 140, Issue 10
Unraveling the Chemical Nature of the 3D “Hollow” Hybrid Halide Perovskites
journal, April 2018
- Spanopoulos, Ioannis; Ke, Weijun; Stoumpos, Constantinos C.
- Journal of the American Chemical Society, Vol. 140, Issue 17
CsPbX 3 Quantum Dots for Lighting and Displays: Room-Temperature Synthesis, Photoluminescence Superiorities, Underlying Origins and White Light-Emitting Diodes
journal, February 2016
- Li, Xiaoming; Wu, Ye; Zhang, Shengli
- Advanced Functional Materials, Vol. 26, Issue 15
Broadband Photoluminescence in 2D Organic–Inorganic Hybrid Perovskites: (C 7 H 18 N 2 )PbBr 4 and (C 9 H 22 N 2 )PbBr 4
journal, March 2020
- Deng, Chenkai; Zhou, Guojun; Chen, Da
- The Journal of Physical Chemistry Letters, Vol. 11, Issue 8
Advanced Strategies of Passivating Perovskite Defects for High‐Performance Solar Cells
journal, September 2020
- Sun, Chuang; Xu, Lei; Lai, Xilin
- ENERGY & ENVIRONMENTAL MATERIALS, Vol. 4, Issue 3
Near-infrared emitting microspheres of LaAlO3:Mn4+: Defects engineering via Ge4+ doping for greatly enhanced luminescence and improved afterglow
journal, June 2020
- Li, Siyuan; Zhu, Qi; Li, Xiaodong
- Journal of Alloys and Compounds, Vol. 827
Crystal Structure Evolution and Notable Thermal Expansion in Hybrid Perovskites Formamidinium Tin Iodide and Formamidinium Lead Bromide
journal, October 2017
- Schueller, Emily C.; Laurita, Geneva; Fabini, Douglas H.
- Inorganic Chemistry, Vol. 57, Issue 2
Single‐Component White‐Light Emission in 2D Hybrid Perovskites with Hybridized Halogen Atoms
journal, September 2019
- Zhou, Guojun; Li, Mingze; Zhao, Jing
- Advanced Optical Materials, Vol. 7, Issue 24
Metal halide perovskites for light-emitting diodes
journal, September 2020
- Liu, Xiao-Ke; Xu, Weidong; Bai, Sai
- Nature Materials, Vol. 20, Issue 1
Electron-Hole Diffusion Lengths Exceeding 1 Micrometer in an Organometal Trihalide Perovskite Absorber
journal, October 2013
- Stranks, S. D.; Eperon, G. E.; Grancini, G.
- Science, Vol. 342, Issue 6156, p. 341-344
Lattice Dynamics and Phase Transitions of Strontium Titanate
journal, May 1964
- Cowley, R. A.
- Physical Review, Vol. 134, Issue 4A
Lead- and Iodide-Deficient (CH 3 NH 3 )PbI 3 ( d -MAPI): The Bridge between 2D and 3D Hybrid Perovskites
journal, November 2017
- Leblanc, Antonin; Mercier, Nicolas; Allain, Magali
- Angewandte Chemie International Edition, Vol. 56, Issue 50
Model of temperature quenching of photoluminescence in disordered semiconductors and comparison to experiment
journal, June 2006
- Rubel, O.; Baranovskii, S. D.; Hantke, K.
- Physical Review B, Vol. 73, Issue 23
Halide lead perovskites for ionizing radiation detection
journal, March 2019
- Wei, Haotong; Huang, Jinsong
- Nature Communications, Vol. 10, Issue 1
Water-Stable 1D Hybrid Tin(II) Iodide Emits Broad Light with 36% Photoluminescence Quantum Efficiency
journal, April 2020
- Spanopoulos, Ioannis; Hadar, Ido; Ke, Weijun
- Journal of the American Chemical Society, Vol. 142, Issue 19
Structural Phase Transition and Electrical Conductivity of the Perovskite CH 3 NH 3 Sn 1 - x Pb x Br 3 and CsSnBr 3
journal, September 1990
- Yamada, Koji; Kawaguchi, Hiroshi; Matsui, Takashi
- Bulletin of the Chemical Society of Japan, Vol. 63, Issue 9
The chemical bond and atomic displacements in SrTiO3 from X-ray diffraction analysis
journal, December 1995
- Abramov, Yu. A.; Tsirelson, V. G.; Zavodnik, V. E.
- Acta Crystallographica Section B Structural Science, Vol. 51, Issue 6
Electron–phonon coupling in hybrid lead halide perovskites
journal, May 2016
- Wright, Adam D.; Verdi, Carla; Milot, Rebecca L.
- Nature Communications, Vol. 7, Issue 1
Small Cyclic Diammonium Cation Templated (110)-Oriented 2D Halide (X = I, Br, Cl) Perovskites with White-Light Emission
journal, April 2019
- Li, Xiaotong; Guo, Peijun; Kepenekian, Mikaël
- Chemistry of Materials, Vol. 31, Issue 9
Diammonium Cations in the FASnI 3 Perovskite Structure Lead to Lower Dark Currents and More Efficient Solar Cells
journal, May 2018
- Ke, Weijun; Stoumpos, Constantinos C.; Spanopoulos, Ioannis
- ACS Energy Letters, Vol. 3, Issue 7
Suppression of phase transitions and glass phase signatures in mixed cation halide perovskites
journal, October 2020
- Simenas, Mantas; Balciunas, Sergejus; Wilson, Jacob N.
- Nature Communications, Vol. 11, Issue 1
New Type of 2D Perovskites with Alternating Cations in the Interlayer Space, (C(NH 2 ) 3 )(CH 3 NH 3 ) n Pb n I 3 n +1 : Structure, Properties, and Photovoltaic Performance
journal, November 2017
- Soe, Chan Myae Myae; Stoumpos, Constantinos C.; Kepenekian, Mikaël
- Journal of the American Chemical Society, Vol. 139, Issue 45
Hybrid Organic-Inorganic Perovskites (HOIPs): Opportunities and Challenges
journal, July 2015
- Berry, Joseph; Buonassisi, Tonio; Egger, David A.
- Advanced Materials, Vol. 27, Issue 35
Solution-Processed Tin-Based Perovskite for Near-Infrared Lasing
journal, July 2016
- Xing, Guichuan; Kumar, Mulmudi Hemant; Chong, Wee Kiang
- Advanced Materials, Vol. 28, Issue 37