Corrosion of Al2O3/Cr and Ti2O3/Cr composites in flowing air and CO2 at 750°C

Nguyen, Thuan Dinh; Caccia, Mario; McCormack, Camilla K.; Itskos, Grigorios; Sandhage, Kenneth H.

doi:10.1016/j.corsci.2020.109115

Title: Corrosion of Al₂O₃/Cr and Ti₂O₃/Cr composites in flowing air and CO₂ at 750°C

Abstract

Hot-pressed Al₂O₃/Cr and Ti₂O₃/Cr composites were exposed to synthetic air or CO₂ at 750 °C. The Al₂O₃/Cr composites formed external Cr₂O₃ scales, and exhibited slow parabolic oxidation kinetics, in both gases. The Cr₂O₃ scales formed in CO₂ possessed finer grains, and thickened at a faster rate, than Cr₂O₃ scales formed in air. The Ti₂O₃/Cr composites formed thick external TiO₂ scales with internal oxidation zones that also contained Cr₂O₃ scales on subsurface Cr grains. After 20 h at 750 °C, the Ti₂O₃/Cr composites exhibited parabolic oxidation kinetics in both gases, although the oxidation rates were significantly higher than for the Al₂O₃/Cr composites.

Authors:

Nguyen, Thuan Dinh ^[1]; Caccia, Mario ^[1]; McCormack, Camilla K. ^[1]; Itskos, Grigorios ^[1]; Sandhage, Kenneth H. ^[1]

Purdue Univ., West Lafayette, IN (United States). School of Materials Engineering

Publication Date:: Fri Nov 13 00:00:00 EST 2020

Research Org.:: Purdue Univ., West Lafayette, IN (United States)

Sponsoring Org.:: USDOE Office of Energy Efficiency and Renewable Energy (EERE), Renewable Power Office. Solar Energy Technologies Office

OSTI Identifier:: 1848831

Alternate Identifier(s):: OSTI ID: 1775707

Grant/Contract Number:: EE0008527

Resource Type:: Accepted Manuscript

Journal Name:: Corrosion Science

Additional Journal Information:: Journal Volume: 179; Journal Issue: C; Journal ID: ISSN 0010-938X

Publisher:: Elsevier

Country of Publication:: United States

Language:: English

Subject:: 36 MATERIALS SCIENCE; 42 ENGINEERING; Materials Science; Metallurgy & Metallurgical Engineering; A. Ceramic matrix composites; B. SEM; B. TEM; C. High temperature corrosion; C. Oxidation; C. Kinetic parameters

Citation Formats


                    Nguyen, Thuan Dinh, Caccia, Mario, McCormack, Camilla K., Itskos, Grigorios, and Sandhage, Kenneth H. Corrosion of Al2O3/Cr and Ti2O3/Cr composites in flowing air and CO2 at 750°C.  United States: N. p., 2020. 
Web.  doi:10.1016/j.corsci.2020.109115.

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                    Nguyen, Thuan Dinh, Caccia, Mario, McCormack, Camilla K., Itskos, Grigorios, & Sandhage, Kenneth H. Corrosion of Al2O3/Cr and Ti2O3/Cr composites in flowing air and CO2 at 750°C.  United States.  https://doi.org/10.1016/j.corsci.2020.109115

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                    Nguyen, Thuan Dinh, Caccia, Mario, McCormack, Camilla K., Itskos, Grigorios, and Sandhage, Kenneth H. Fri .  
"Corrosion of Al2O3/Cr and Ti2O3/Cr composites in flowing air and CO2 at 750°C".  United States.  https://doi.org/10.1016/j.corsci.2020.109115.  https://www.osti.gov/servlets/purl/1848831.

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@article{osti_1848831,

  title        = {Corrosion of Al2O3/Cr and Ti2O3/Cr composites in flowing air and CO2 at 750°C},

  author       = {Nguyen, Thuan Dinh and Caccia, Mario and McCormack, Camilla K. and Itskos, Grigorios and Sandhage, Kenneth H.},

  abstractNote = {Hot-pressed Al2O3/Cr and Ti2O3/Cr composites were exposed to synthetic air or CO2 at 750 °C. The Al2O3/Cr composites formed external Cr2O3 scales, and exhibited slow parabolic oxidation kinetics, in both gases. The Cr2O3 scales formed in CO2 possessed finer grains, and thickened at a faster rate, than Cr2O3 scales formed in air. The Ti2O3/Cr composites formed thick external TiO2 scales with internal oxidation zones that also contained Cr2O3 scales on subsurface Cr grains. After 20 h at 750 °C, the Ti2O3/Cr composites exhibited parabolic oxidation kinetics in both gases, although the oxidation rates were significantly higher than for the Al2O3/Cr composites.},

  doi          = {10.1016/j.corsci.2020.109115},

  journal      = {Corrosion Science},

  number       = C,

  volume       = 179,

  place        = {United States},

  year         = {Fri Nov 13 00:00:00 EST 2020},

  month        = {Fri Nov 13 00:00:00 EST 2020}

}

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Title: Corrosion of Al2O3/Cr and Ti2O3/Cr composites in flowing air and CO2 at 750°C

Abstract

Citation Formats

Mechanical and thermomechanical properties of commercially pure chromium and chromium alloys journal, February 2002

Oxidation or Nitridation Behavior of Pure Chromium and Chromium Alloys Containing 10 mass%Ni or Fe in Atmospheric Heating journal, January 2006

Thermodynamic calculation of the O-Ti system journal, August 1997

High Temperature Oxidation of Cr-ZrO2-Al2O3 Composite Fabricated by Mechanical Alloying and Spark Plasma Sintering journal, March 2006

Cation Tracer Diffusion in Cr2O3 and Cr2O3-0.09 wt% Y2O3 journal, December 1987

Turbines can use CO 2 to cut CO 2 journal, May 2017

On the mechanism of oxidation of iron-16·4% chromium at high temperature journal, January 1964

Factors affecting isothermal oxidation of pure chromium in air journal, January 2018

Challenges in Developing Oxidation-Resistant Chromium-Based Alloys for Applications Above 900°C journal, August 2016

The Supercritical Carbon Dioxide Power Cycle: Comparison to Other Advanced Power Cycles journal, June 2006

Corrosion of 9Cr Steel in CO2 at Intermediate Temperature I: Mechanism of Void-Induced Duplex Oxide Formation journal, September 2011

Carburisation of ferritic Fe–Cr alloys by low carbon activity gases journal, September 2011

Effect of oxide grain structure on the high-temperature oxidation of Cr journal, October 1975

Atom probe study of impurity segregation at grain boundaries in chromia scales grown in CO2 gas journal, March 2018

Alumina-chromium cermets by hot-pressing of nanocomposite powders journal, November 1998

Concentrating Solar Power journal, August 2015

Effects of Fe on the oxidation/internal nitridation behavior and tensile properties of Cr and oxide dispersion ductilized Cr journal, May 2005

Anion Transport in Growing Cr2O3 Scales journal, January 1991

High-temperature crystal chemistry of Ti2O3: structural changes accompanying the semiconductor–metal transition journal, May 1977

The growth and structure of oxide films formed on single crystal (100) and polycrystalline Cr between 550 and 900 °C journal, October 1987

Ceramic–metal composites for heat exchangers in concentrated solar power plants journal, October 2018

Cr-O (chromium-oxygen) journal, August 1997

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Kinetics of the Oxidation of Chromium journal, January 1957

The Effect of CO2 Pressure on Chromia Scale Microstructure at 750°C journal, June 2018

The Al-O (Aluminum-Oxygen) system journal, December 1985

Diffusion of cations in chromia layers grown on iron-base alloys journal, February 1992

Penetration of protective chromia scales by carbon journal, April 2014

X-Ray Diffraction to Study the Oxidation Mechanism of Chromium at Elevated Temperatures journal, August 2004

Grid flexibility and storage required to achieve very high penetration of variable renewable electricity journal, March 2011

Title: Corrosion of Al₂O₃/Cr and Ti₂O₃/Cr composites in flowing air and CO₂ at 750°C

Mechanical and thermomechanical properties of commercially pure chromium and chromium alloys
journal, February 2002

Oxidation or Nitridation Behavior of Pure Chromium and Chromium Alloys Containing 10 mass%Ni or Fe in Atmospheric Heating
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Thermodynamic calculation of the O-Ti system
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High Temperature Oxidation of Cr-ZrO₂-Al₂O₃ Composite Fabricated by Mechanical Alloying and Spark Plasma Sintering
journal, March 2006

Cation Tracer Diffusion in Cr2O3 and Cr2O3-0.09 wt% Y2O3
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On the mechanism of oxidation of iron-16·4% chromium at high temperature
journal, January 1964

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Challenges in Developing Oxidation-Resistant Chromium-Based Alloys for Applications Above 900°C
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The Supercritical Carbon Dioxide Power Cycle: Comparison to Other Advanced Power Cycles
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