Expeditious synthesis of covalent organic frameworks: a review
Abstract
Covalent organic frameworks (COFs), a burgeoning class of crystalline porous materials constructed by covalently connecting organic building blocks, have garnered tremendous attention. The predominant solvothermal synthesis of COFs usually requires high temperature and long reaction times (three days or longer), which creates substantial obstacles for their accelerated discovery and exploration in practical applications. Hence, the expeditious synthesis of COFs without compromising their inherent properties is exceedingly appealing from the viewpoint of cost, time, and energy footprint. To overcome the sluggishness of the synthesis, considerable efforts have been invested in the rapid synthesis of high-quality COFs through innovations in energy source, catalyst, solvent, monomer, nucleation, and workup activation, leading to a drastic reduction of reaction time from multiple days to a few hours, and even to seconds in some cases. In this contribution, we provide a comprehensive overview of the advances in expediting the synthesis science of COFs. Though a nascent effort, six prevalent strategies have been identified for the rapid synthesis of COFs, which have led to intriguing applications in a diverse range of areas including gas adsorption, separation, heterogeneous catalysis, environmental remediation, and photodynamic therapy. We also outline the major challenges and perspectives on the future directions empowered bymore »
- Authors:
-
- Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)
- China University of Geosciences, Beijing (China)
- South China Normal University, Guangzhou (China)
- Beijing University of Chemical Technology (China)
- Publication Date:
- Research Org.:
- Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES). Scientific User Facilities Division
- OSTI Identifier:
- 1832460
- Alternate Identifier(s):
- OSTI ID: 1644371
- Grant/Contract Number:
- AC02-05CH11231
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Journal of Materials Chemistry. A
- Additional Journal Information:
- Journal Volume: 8; Journal Issue: 32; Journal ID: ISSN 2050-7488
- Publisher:
- Royal Society of Chemistry
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
Citation Formats
Li, Xinle, Yang, Chongqing, Sun, Bing, Cai, Songliang, Chen, Ziman, Lv, Yongqin, Zhang, Jian, and Liu, Yi. Expeditious synthesis of covalent organic frameworks: a review. United States: N. p., 2020.
Web. doi:10.1039/d0ta05894g.
Li, Xinle, Yang, Chongqing, Sun, Bing, Cai, Songliang, Chen, Ziman, Lv, Yongqin, Zhang, Jian, & Liu, Yi. Expeditious synthesis of covalent organic frameworks: a review. United States. https://doi.org/10.1039/d0ta05894g
Li, Xinle, Yang, Chongqing, Sun, Bing, Cai, Songliang, Chen, Ziman, Lv, Yongqin, Zhang, Jian, and Liu, Yi. Wed .
"Expeditious synthesis of covalent organic frameworks: a review". United States. https://doi.org/10.1039/d0ta05894g. https://www.osti.gov/servlets/purl/1832460.
@article{osti_1832460,
title = {Expeditious synthesis of covalent organic frameworks: a review},
author = {Li, Xinle and Yang, Chongqing and Sun, Bing and Cai, Songliang and Chen, Ziman and Lv, Yongqin and Zhang, Jian and Liu, Yi},
abstractNote = {Covalent organic frameworks (COFs), a burgeoning class of crystalline porous materials constructed by covalently connecting organic building blocks, have garnered tremendous attention. The predominant solvothermal synthesis of COFs usually requires high temperature and long reaction times (three days or longer), which creates substantial obstacles for their accelerated discovery and exploration in practical applications. Hence, the expeditious synthesis of COFs without compromising their inherent properties is exceedingly appealing from the viewpoint of cost, time, and energy footprint. To overcome the sluggishness of the synthesis, considerable efforts have been invested in the rapid synthesis of high-quality COFs through innovations in energy source, catalyst, solvent, monomer, nucleation, and workup activation, leading to a drastic reduction of reaction time from multiple days to a few hours, and even to seconds in some cases. In this contribution, we provide a comprehensive overview of the advances in expediting the synthesis science of COFs. Though a nascent effort, six prevalent strategies have been identified for the rapid synthesis of COFs, which have led to intriguing applications in a diverse range of areas including gas adsorption, separation, heterogeneous catalysis, environmental remediation, and photodynamic therapy. We also outline the major challenges and perspectives on the future directions empowered by expeditious COF synthesis.},
doi = {10.1039/d0ta05894g},
journal = {Journal of Materials Chemistry. A},
number = 32,
volume = 8,
place = {United States},
year = {Wed Jan 01 00:00:00 EST 2020},
month = {Wed Jan 01 00:00:00 EST 2020}
}
Web of Science
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Rapid Synthesis of High Surface Area Imine‐Linked 2D Covalent Organic Frameworks by Avoiding Pore Collapse During Isolation
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Manipulation of Amorphous-to-Crystalline Transformation: Towards the Construction of Covalent Organic Framework Hybrid Microspheres with NIR Photothermal Conversion Ability
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Nucleation and growth of 2D covalent organic frameworks: polymerization and crystallization of COF monomers
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Two-Dimensional Chemiresistive Covalent Organic Framework with High Intrinsic Conductivity
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