Tailorable multifunctionalities in ultrathin 2D Bi-based layered supercell structures
Abstract
Two-dimensional (2D) materials with robust ferromagnetic behavior have attracted great interest because of their potential applications in next-generation nanoelectronic devices. Aside from graphene and transition metal dichalcogenides, Bi-based layered oxide materials are a group of prospective candidates due to their superior room-temperature multiferroic response. In this work, an ultrathin Bi3Fe2Mn2O10+δ layered supercell (BFMO322 LS) structure was deposited on an LaAlO3 (LAO) (001) substrate using pulsed laser deposition. Microstructural analysis suggests that a layered supercell (LS) structure consisting of two-layer-thick Bi–O slabs and two-layer-thick Mn/Fe–O octahedra slabs was formed on top of the pseudo-perovskite interlayer (IL). A robust saturation magnetization value of 129 and 96 emu cm-3 is achieved in a 12.3 nm thick film in the in-plane (IP) and out-of-plane (OP) directions, respectively. The ferromagnetism, dielectric permittivity, and optical bandgap of the ultrathin BFMO films can be effectively tuned by thickness and morphology variation. In addition, the anisotropy of all ultrathin BFMO films switches from OP dominating to IP dominating as the thickness increases. This study demonstrates the ultrathin BFMO film with tunable multifunctionalities as a promising candidate for novel integrated spintronic devices.
- Authors:
-
[1];
[1];
[2];
[1]
- Purdue Univ., West Lafayette, IN (United States)
- Sandia National Lab. (SNL-NM), Albuquerque, NM (United States)
- Publication Date:
- Research Org.:
- Sandia National Lab. (SNL-NM), Albuquerque, NM (United States)
- Sponsoring Org.:
- USDOE National Nuclear Security Administration (NNSA); US Department of the Navy, Office of Naval Research (ONR); National Science Foundation (NSF)
- OSTI Identifier:
- 1828785
- Alternate Identifier(s):
- OSTI ID: 1823180
- Report Number(s):
- SAND-2021-12554J
Journal ID: ISSN 2040-3364; 700739
- Grant/Contract Number:
- NA0003525; N00014-1-20-2600; DMR-1809520; DMR-2016453; N00014-17-1-2087; N00014-20-1-2043
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Nanoscale
- Additional Journal Information:
- Journal Volume: 13; Journal Issue: 39; Journal ID: ISSN 2040-3364
- Publisher:
- Royal Society of Chemistry
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 77 NANOSCIENCE AND NANOTECHNOLOGY; ultrathin layered oxide; BFMO322 layered supercell (LS); anisotropy; multiferroics
Citation Formats
He, Zihao, Gao, Xingyao, Zhang, Di, Lu, Ping, Wang, Xuejing, Kalaswad, Matias, Rutherford, Bethany X., and Wang, Haiyan. Tailorable multifunctionalities in ultrathin 2D Bi-based layered supercell structures. United States: N. p., 2021.
Web. doi:10.1039/d1nr04975e.
He, Zihao, Gao, Xingyao, Zhang, Di, Lu, Ping, Wang, Xuejing, Kalaswad, Matias, Rutherford, Bethany X., & Wang, Haiyan. Tailorable multifunctionalities in ultrathin 2D Bi-based layered supercell structures. United States. https://doi.org/10.1039/d1nr04975e
He, Zihao, Gao, Xingyao, Zhang, Di, Lu, Ping, Wang, Xuejing, Kalaswad, Matias, Rutherford, Bethany X., and Wang, Haiyan. Tue .
"Tailorable multifunctionalities in ultrathin 2D Bi-based layered supercell structures". United States. https://doi.org/10.1039/d1nr04975e. https://www.osti.gov/servlets/purl/1828785.
@article{osti_1828785,
title = {Tailorable multifunctionalities in ultrathin 2D Bi-based layered supercell structures},
author = {He, Zihao and Gao, Xingyao and Zhang, Di and Lu, Ping and Wang, Xuejing and Kalaswad, Matias and Rutherford, Bethany X. and Wang, Haiyan},
abstractNote = {Two-dimensional (2D) materials with robust ferromagnetic behavior have attracted great interest because of their potential applications in next-generation nanoelectronic devices. Aside from graphene and transition metal dichalcogenides, Bi-based layered oxide materials are a group of prospective candidates due to their superior room-temperature multiferroic response. In this work, an ultrathin Bi3Fe2Mn2O10+δ layered supercell (BFMO322 LS) structure was deposited on an LaAlO3 (LAO) (001) substrate using pulsed laser deposition. Microstructural analysis suggests that a layered supercell (LS) structure consisting of two-layer-thick Bi–O slabs and two-layer-thick Mn/Fe–O octahedra slabs was formed on top of the pseudo-perovskite interlayer (IL). A robust saturation magnetization value of 129 and 96 emu cm-3 is achieved in a 12.3 nm thick film in the in-plane (IP) and out-of-plane (OP) directions, respectively. The ferromagnetism, dielectric permittivity, and optical bandgap of the ultrathin BFMO films can be effectively tuned by thickness and morphology variation. In addition, the anisotropy of all ultrathin BFMO films switches from OP dominating to IP dominating as the thickness increases. This study demonstrates the ultrathin BFMO film with tunable multifunctionalities as a promising candidate for novel integrated spintronic devices.},
doi = {10.1039/d1nr04975e},
journal = {Nanoscale},
number = 39,
volume = 13,
place = {United States},
year = {Tue Jun 22 00:00:00 EDT 2021},
month = {Tue Jun 22 00:00:00 EDT 2021}
}
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