N-doped honeycomb-like porous carbon towards high-performance supercapacitor
Abstract
Biomass-derived porous carbon with developed pore structure is critical to achieving high performance electrode materials. In this work, we report a grape-based honeycomb-like porous carbon (GHPC) prepared by KOH activation and carbonization, followed by N-doping (NGHPC). The obtained NGHPC exhibits a unique honeycomb-like structure with hierarchically interconnected micro/mesopores, and high specific surface area of 1268 m2/g. As a supercapacitor electrode, the NGPHC electrode exhibits a remarkable specific capacitance of 275 F/g at 0.5 A/g in a three-electrode cell. Moreover, the NGHPC//NGHPC symmetric supercapacitor displays a high energy density of 12.6 Wh/kg, and excellent cycling stability of approximately 95.2% capacitance retention after 5000 cycles at 5 A/g. The excellent electrochemical performance of NGHPC is ascribed to its high specific surface area, honeycomb-like structure and high-content of pyrodinic-N (36.29%). It is believed that grape-based carbon materials show great potential as advanced electrode materials for supercapacitors.
- Authors:
-
[4];
[1]
- Nanjing Forestry University (China)
- Massachusetts Inst. of Technology (MIT), Cambridge, MA (United States)
- Qingdao University of Science and Technology (China)
- Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
- Publication Date:
- Research Org.:
- Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- OSTI Identifier:
- 1817509
- Grant/Contract Number:
- AC05-00OR22725
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Chinese Chemical Letters
- Additional Journal Information:
- Journal Volume: 31; Journal Issue: 7; Journal ID: ISSN 1001-8417
- Publisher:
- Elsevier
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; Grape; Honeycomb-like; Porous carbon; Activation; Supercapacitor
Citation Formats
Wang, Feng, Chen, Lian, Li, Huiling, Duan, Gaigai, He, Shuijian, Zhang, Lin, Zhang, Guoying, Zhou, Zhengping, and Jiang, Shaohua. N-doped honeycomb-like porous carbon towards high-performance supercapacitor. United States: N. p., 2020.
Web. doi:10.1016/j.cclet.2020.02.020.
Wang, Feng, Chen, Lian, Li, Huiling, Duan, Gaigai, He, Shuijian, Zhang, Lin, Zhang, Guoying, Zhou, Zhengping, & Jiang, Shaohua. N-doped honeycomb-like porous carbon towards high-performance supercapacitor. United States. https://doi.org/10.1016/j.cclet.2020.02.020
Wang, Feng, Chen, Lian, Li, Huiling, Duan, Gaigai, He, Shuijian, Zhang, Lin, Zhang, Guoying, Zhou, Zhengping, and Jiang, Shaohua. Thu .
"N-doped honeycomb-like porous carbon towards high-performance supercapacitor". United States. https://doi.org/10.1016/j.cclet.2020.02.020. https://www.osti.gov/servlets/purl/1817509.
@article{osti_1817509,
title = {N-doped honeycomb-like porous carbon towards high-performance supercapacitor},
author = {Wang, Feng and Chen, Lian and Li, Huiling and Duan, Gaigai and He, Shuijian and Zhang, Lin and Zhang, Guoying and Zhou, Zhengping and Jiang, Shaohua},
abstractNote = {Biomass-derived porous carbon with developed pore structure is critical to achieving high performance electrode materials. In this work, we report a grape-based honeycomb-like porous carbon (GHPC) prepared by KOH activation and carbonization, followed by N-doping (NGHPC). The obtained NGHPC exhibits a unique honeycomb-like structure with hierarchically interconnected micro/mesopores, and high specific surface area of 1268 m2/g. As a supercapacitor electrode, the NGPHC electrode exhibits a remarkable specific capacitance of 275 F/g at 0.5 A/g in a three-electrode cell. Moreover, the NGHPC//NGHPC symmetric supercapacitor displays a high energy density of 12.6 Wh/kg, and excellent cycling stability of approximately 95.2% capacitance retention after 5000 cycles at 5 A/g. The excellent electrochemical performance of NGHPC is ascribed to its high specific surface area, honeycomb-like structure and high-content of pyrodinic-N (36.29%). It is believed that grape-based carbon materials show great potential as advanced electrode materials for supercapacitors.},
doi = {10.1016/j.cclet.2020.02.020},
journal = {Chinese Chemical Letters},
number = 7,
volume = 31,
place = {United States},
year = {Thu Feb 13 00:00:00 EST 2020},
month = {Thu Feb 13 00:00:00 EST 2020}
}
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