Ion-Conducting Thermoresponsive Films Based on Polymer-Grafted Cellulose Nanocrystals
Abstract
Mechanically robust, thermo-responsive, ion-conducting nanocomposite films are prepared from poly(2-phenylethyl methacrylate) grafted cellulose nanocrystals (MxG-CNC-g-PPMA). One-component nanocomposite films of the polymer grafted nanoparticle (PGN) MxG-CNC-g-PPMA are imbibed with 30 wt% imidazolium-based ionic liquid, to produce flexible ion-conducting films. These films with 1-hexyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide (MxG-CNC-g-PPMA/[H]) not only displays remarkable improvements in toughness (>25 times) and tensile strength (>70 times) relative to the corresponding nanocomposites consisting of the ionic liquid imbibed in the two component CNC/PPMA nanocomposite, but also shows higher ionic conductivity than the corresponding neat PPMA with the same wt.% of ionic liquid. Notably, the one-component film containing 1-ethyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide (MxG-CNC-g-PPMA/[E]) exhibits temperature responsive ionic conduction. The ionic conductivity decreases at around 60°C as a consequence of the lower critical solution temperature (LCST) phase transition of the grafted polymer in the ionic liquid, which leads to phase separation. Moreover, holding the MxG-CNC-g-PPMA/[E] film at room temperature for 24 hours returns the film to its original homogenous state. These materials exhibit properties relevant to thermal cutoff safety devices (e.g., thermal fuse) where a reduction in conductivity above a critical temperature is needed.
- Authors:
-
[3];
[3]
- Univ. of Chicago, IL (United States); Argonne National Lab. (ANL), Lemont, IL (United States). Joint Center for Energy Storage Research (JCESR)
- Univ. of Chicago, IL (United States)
- Univ. of Chicago, IL (United States); Argonne National Lab. (ANL), Lemont, IL (United States). Joint Center for Energy Storage Research (JCESR); Argonne National Lab. (ANL), Lemont, IL (United States)
- Publication Date:
- Research Org.:
- Argonne National Lab. (ANL), Argonne, IL (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES); US Army Research Office (ARO); National Science Foundation (NSF)
- OSTI Identifier:
- 1810546
- Grant/Contract Number:
- AC02-06CH11357; W911NF-15-1- 0190; W911NF-18-1-0287; DMR-1420709; DMR2011854
- Resource Type:
- Accepted Manuscript
- Journal Name:
- ACS Applied Materials and Interfaces
- Additional Journal Information:
- Journal Volume: 12; Journal Issue: 48; Journal ID: ISSN 1944-8244
- Publisher:
- American Chemical Society (ACS)
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 36 MATERIALS SCIENCE; thermal-responsive polymers; polymer-grafted nanoparticles; cellulose nanocrystals; smart materials; nanocomposites; polymer films; salts; ionic conductivity; solvents; polymers
Citation Formats
Kato, Ryo, Lettow, James H., Patel, Shrayesh N., and Rowan, Stuart J. Ion-Conducting Thermoresponsive Films Based on Polymer-Grafted Cellulose Nanocrystals. United States: N. p., 2020.
Web. doi:10.1021/acsami.0c16059.
Kato, Ryo, Lettow, James H., Patel, Shrayesh N., & Rowan, Stuart J. Ion-Conducting Thermoresponsive Films Based on Polymer-Grafted Cellulose Nanocrystals. United States. https://doi.org/10.1021/acsami.0c16059
Kato, Ryo, Lettow, James H., Patel, Shrayesh N., and Rowan, Stuart J. Tue .
"Ion-Conducting Thermoresponsive Films Based on Polymer-Grafted Cellulose Nanocrystals". United States. https://doi.org/10.1021/acsami.0c16059. https://www.osti.gov/servlets/purl/1810546.
@article{osti_1810546,
title = {Ion-Conducting Thermoresponsive Films Based on Polymer-Grafted Cellulose Nanocrystals},
author = {Kato, Ryo and Lettow, James H. and Patel, Shrayesh N. and Rowan, Stuart J.},
abstractNote = {Mechanically robust, thermo-responsive, ion-conducting nanocomposite films are prepared from poly(2-phenylethyl methacrylate) grafted cellulose nanocrystals (MxG-CNC-g-PPMA). One-component nanocomposite films of the polymer grafted nanoparticle (PGN) MxG-CNC-g-PPMA are imbibed with 30 wt% imidazolium-based ionic liquid, to produce flexible ion-conducting films. These films with 1-hexyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide (MxG-CNC-g-PPMA/[H]) not only displays remarkable improvements in toughness (>25 times) and tensile strength (>70 times) relative to the corresponding nanocomposites consisting of the ionic liquid imbibed in the two component CNC/PPMA nanocomposite, but also shows higher ionic conductivity than the corresponding neat PPMA with the same wt.% of ionic liquid. Notably, the one-component film containing 1-ethyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide (MxG-CNC-g-PPMA/[E]) exhibits temperature responsive ionic conduction. The ionic conductivity decreases at around 60°C as a consequence of the lower critical solution temperature (LCST) phase transition of the grafted polymer in the ionic liquid, which leads to phase separation. Moreover, holding the MxG-CNC-g-PPMA/[E] film at room temperature for 24 hours returns the film to its original homogenous state. These materials exhibit properties relevant to thermal cutoff safety devices (e.g., thermal fuse) where a reduction in conductivity above a critical temperature is needed.},
doi = {10.1021/acsami.0c16059},
journal = {ACS Applied Materials and Interfaces},
number = 48,
volume = 12,
place = {United States},
year = {Tue Nov 17 00:00:00 EST 2020},
month = {Tue Nov 17 00:00:00 EST 2020}
}
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