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Title: Polymer Zwitterions for Stabilization of CsPbBr3 Perovskite Nanoparticles and Nanocomposite Films

Abstract

Abstract Functional polymers with sulfobetaine or phosphorylcholine zwitterions as pendent groups are demonstrated as both ligands and host matrices for CsPbBr 3 perovskite nanoparticles (PNPs). These polymers produce nanocomposite films with excellent NP dispersion, optical transparency, and impressive resistance to NP degradation upon exposure to water. Multidentate interactions of the zwitterion‐containing copolymers with the PNPs induce dispersed or weakly aggregated nanocomposite morphologies, depending on the extent of zwitterionic functionality in the polymer. Incorporating additional functionality into the polymers, such as benzophenone pendent groups, yields lithographically patternable films, while time‐resolved photoluminescence measurements provide insight into the electronic impact of PNPs in zwitterionic polymer matrices.

Authors:
 [1];  [2];  [1];  [1];  [1];  [1];  [2];  [1]; ORCiD logo [1]
+ Show Author Affiliations
  1. Univ. of Massachusetts, Amherst, MA (United States). Polymer Science and Engineering Dept.
  2. Univ. of Massachusetts, Amherst, MA (United States). Dept. of Chemistry
Publication Date:
Research Org.:
Univ. of Massachusetts, Amherst, MA (United States)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
OSTI Identifier:
1802860
Alternate Identifier(s):
OSTI ID: 1615439
Grant/Contract Number:  
SC0016208
Resource Type:
Accepted Manuscript
Journal Name:
Angewandte Chemie (International Edition)
Additional Journal Information:
Journal Name: Angewandte Chemie (International Edition); Journal Volume: 59; Journal Issue: 27; Journal ID: ISSN 1433-7851
Publisher:
Wiley
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; time-resolved photoluminescence; polymer zwitterions; polymer ligands; perovskite nanoparticles; nanocomposites

Citation Formats

Kim, Hyunki, Hight‐Huf, Nicholas, Kang, Ji‐Hwan, Bisnoff, Phoebe, Sundararajan, Suvin, Thompson, Theo, Barnes, Michael, Hayward, Ryan C., and Emrick, Todd. Polymer Zwitterions for Stabilization of CsPbBr3 Perovskite Nanoparticles and Nanocomposite Films. United States: N. p., 2020. Web. doi:10.1002/anie.201916492.
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Kim, Hyunki, Hight‐Huf, Nicholas, Kang, Ji‐Hwan, Bisnoff, Phoebe, Sundararajan, Suvin, Thompson, Theo, Barnes, Michael, Hayward, Ryan C., & Emrick, Todd. Polymer Zwitterions for Stabilization of CsPbBr3 Perovskite Nanoparticles and Nanocomposite Films. United States. https://doi.org/10.1002/anie.201916492
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Kim, Hyunki, Hight‐Huf, Nicholas, Kang, Ji‐Hwan, Bisnoff, Phoebe, Sundararajan, Suvin, Thompson, Theo, Barnes, Michael, Hayward, Ryan C., and Emrick, Todd. Thu . "Polymer Zwitterions for Stabilization of CsPbBr3 Perovskite Nanoparticles and Nanocomposite Films". United States. https://doi.org/10.1002/anie.201916492. https://www.osti.gov/servlets/purl/1802860.
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@article{osti_1802860,
title = {Polymer Zwitterions for Stabilization of CsPbBr3 Perovskite Nanoparticles and Nanocomposite Films},
author = {Kim, Hyunki and Hight‐Huf, Nicholas and Kang, Ji‐Hwan and Bisnoff, Phoebe and Sundararajan, Suvin and Thompson, Theo and Barnes, Michael and Hayward, Ryan C. and Emrick, Todd},
abstractNote = {Abstract Functional polymers with sulfobetaine or phosphorylcholine zwitterions as pendent groups are demonstrated as both ligands and host matrices for CsPbBr 3 perovskite nanoparticles (PNPs). These polymers produce nanocomposite films with excellent NP dispersion, optical transparency, and impressive resistance to NP degradation upon exposure to water. Multidentate interactions of the zwitterion‐containing copolymers with the PNPs induce dispersed or weakly aggregated nanocomposite morphologies, depending on the extent of zwitterionic functionality in the polymer. Incorporating additional functionality into the polymers, such as benzophenone pendent groups, yields lithographically patternable films, while time‐resolved photoluminescence measurements provide insight into the electronic impact of PNPs in zwitterionic polymer matrices.},
doi = {10.1002/anie.201916492},
journal = {Angewandte Chemie (International Edition)},
number = 27,
volume = 59,
place = {United States},
year = {Thu Mar 05 00:00:00 EST 2020},
month = {Thu Mar 05 00:00:00 EST 2020}
}
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https://doi.org/10.1002/anie.201916492
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Works referenced in this record:

Photovoltaic solar cell technologies: analysing the state of the art
journal, March 2019

  • Nayak, Pabitra K.; Mahesh, Suhas; Snaith, Henry J.
  • Nature Reviews Materials, Vol. 4, Issue 4
  • DOI: 10.1038/s41578-019-0097-0

Encapsulation of Perovskite Nanocrystals into Macroscale Polymer Matrices: Enhanced Stability and Polarization
journal, December 2016

  • Raja, Shilpa N.; Bekenstein, Yehonadav; Koc, Matthew A.
  • ACS Applied Materials & Interfaces, Vol. 8, Issue 51
  • DOI: 10.1021/acsami.6b09443

Functional polymers for growth and stabilization of CsPbBr 3 perovskite nanoparticles
journal, January 2019

  • Kim, Hyunki; So, Soonyong; Ribbe, Alexander
  • Chemical Communications, Vol. 55, Issue 12
  • DOI: 10.1039/C8CC09343A

Light‐Driven Shape Morphing, Assembly, and Motion of Nanocomposite Gel Surfers
journal, May 2019

High Photoluminescence Efficiency and Optically Pumped Lasing in Solution-Processed Mixed Halide Perovskite Semiconductors
journal, March 2014

  • Deschler, Felix; Price, Michael; Pathak, Sandeep
  • The Journal of Physical Chemistry Letters, Vol. 5, Issue 8
  • DOI: 10.1021/jz5005285

Band filling with free charge carriers in organometal halide perovskites
journal, August 2014

CsPbBr 3 QD/AlO x Inorganic Nanocomposites with Exceptional Stability in Water, Light, and Heat
journal, June 2017

  • Loiudice, Anna; Saris, Seryio; Oveisi, Emad
  • Angewandte Chemie, Vol. 129, Issue 36
  • DOI: 10.1002/ange.201703703

Phosphonic Acid Stabilized Colloidal CsPbX 3 (X=Br, I) Perovskite Nanocrystals and Their Surface Chemistry
journal, August 2016

Properties and potential optoelectronic applications of lead halide perovskite nanocrystals
journal, November 2017

  • Kovalenko, Maksym V.; Protesescu, Loredana; Bodnarchuk, Maryna I.
  • Science, Vol. 358, Issue 6364
  • DOI: 10.1126/science.aam7093

Polymer-Enhanced Stability of Inorganic Perovskite Nanocrystals and Their Application in Color Conversion LEDs
journal, July 2016

  • Meyns, Michaela; Perálvarez, Mariano; Heuer-Jungemann, Amelie
  • ACS Applied Materials & Interfaces, Vol. 8, Issue 30
  • DOI: 10.1021/acsami.6b02529

Genesis, challenges and opportunities for colloidal lead halide perovskite nanocrystals
journal, February 2018

  • Akkerman, Quinten A.; Rainò, Gabriele; Kovalenko, Maksym V.
  • Nature Materials, Vol. 17, Issue 5
  • DOI: 10.1038/s41563-018-0018-4

Not just fractal surfaces, but surface fractal aggregates: Derivation of the expression for the structure factor and its applications
journal, December 2016

  • Besselink, R.; Stawski, T. M.; Van Driessche, A. E. S.
  • The Journal of Chemical Physics, Vol. 145, Issue 21
  • DOI: 10.1063/1.4960953

Solution-processed hybrid perovskite photodetectors with high detectivity
journal, November 2014

  • Dou, Letian; Yang, Yang (Micheal); You, Jingbi
  • Nature Communications, Vol. 5, Issue 1
  • DOI: 10.1038/ncomms6404

Modulated Formation of MOF-5 Nanoparticles—A SANS Analysis
journal, March 2012

  • Nayuk, R.; Zacher, D.; Schweins, R.
  • The Journal of Physical Chemistry C, Vol. 116, Issue 10
  • DOI: 10.1021/jp3003728

Perovskite light-emitting diodes with external quantum efficiency exceeding 20 per cent
journal, October 2018

Excitons versus free charges in organo-lead tri-halide perovskites
journal, April 2014

  • D’Innocenzo, Valerio; Grancini, Giulia; Alcocer, Marcelo J. P.
  • Nature Communications, Vol. 5, Issue 1
  • DOI: 10.1038/ncomms4586

All-Inorganic Colloidal Perovskite Quantum Dots: A New Class of Lasing Materials with Favorable Characteristics
journal, October 2015

The structure of chain end-grafted nanoparticle/homopolymer nanocomposites
journal, January 2011

Microscopic Observation of Aging of Silica Particles in Unvulcanized Rubber
journal, November 2010

  • Shinohara, Yuya; Kishimoto, Hiroyuki; Yagi, Naoto
  • Macromolecules, Vol. 43, Issue 22
  • DOI: 10.1021/ma102095b

Multifaceted Excited State of CH 3 NH 3 PbI 3 . Charge Separation, Recombination, and Trapping
journal, May 2015

  • Christians, Jeffrey A.; Manser, Joseph S.; Kamat, Prashant V.
  • The Journal of Physical Chemistry Letters, Vol. 6, Issue 11
  • DOI: 10.1021/acs.jpclett.5b00594

Colloidal CsPbX 3 (X = Cl, Br, I) Nanocrystals 2.0: Zwitterionic Capping Ligands for Improved Durability and Stability
journal, February 2018

Synthesis and Stabilization of Colloidal Perovskite Nanocrystals by Multidentate Polymer Micelles
journal, May 2017

  • Hou, Shaocong; Guo, Yuzheng; Tang, Yuguo
  • ACS Applied Materials & Interfaces, Vol. 9, Issue 22
  • DOI: 10.1021/acsami.7b03445

CsPbBr 3 QD/AlO x Inorganic Nanocomposites with Exceptional Stability in Water, Light, and Heat
journal, June 2017

  • Loiudice, Anna; Saris, Seryio; Oveisi, Emad
  • Angewandte Chemie International Edition, Vol. 56, Issue 36
  • DOI: 10.1002/anie.201703703

Functional Polymer Nanocomposites Enhanced by Nanorods
journal, December 2013

  • Hore, Michael J. A.; Composto, Russell J.
  • Macromolecules, Vol. 47, Issue 3
  • DOI: 10.1021/ma402179w

Stable and conductive lead halide perovskites facilitated by X-type ligands
journal, January 2017

  • Ruan, Longfei; Shen, Wei; Wang, Aifei
  • Nanoscale, Vol. 9, Issue 21
  • DOI: 10.1039/C7NR02125A

Small-angle scattering from porous solids with fractal geometry
journal, August 1986

Recombination Kinetics in Organic-Inorganic Perovskites: Excitons, Free Charge, and Subgap States
journal, September 2014

High Charge Carrier Mobilities and Lifetimes in Organolead Trihalide Perovskites
journal, December 2013

  • Wehrenfennig, Christian; Eperon, Giles E.; Johnston, Michael B.
  • Advanced Materials, Vol. 26, Issue 10
  • DOI: 10.1002/adma.201305172

Highly Dynamic Ligand Binding and Light Absorption Coefficient of Cesium Lead Bromide Perovskite Nanocrystals
journal, January 2016

Mean-field models of structure and dispersion of polymer-nanoparticle mixtures
journal, January 2010

  • Ganesan, Venkat; Ellison, Christopher J.; Pryamitsyn, Victor
  • Soft Matter, Vol. 6, Issue 17
  • DOI: 10.1039/b926992d

Nanocrystals of Cesium Lead Halide Perovskites (CsPbX 3 , X = Cl, Br, and I): Novel Optoelectronic Materials Showing Bright Emission with Wide Color Gamut
journal, February 2015

  • Protesescu, Loredana; Yakunin, Sergii; Bodnarchuk, Maryna I.
  • Nano Letters, Vol. 15, Issue 6
  • DOI: 10.1021/nl5048779
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