Metals Coprecipitation with Barite: Nano-XRF Observation of Enhanced Strontium Incorporation

Hunter, Heather A.; Ling, Florence T.; Peters, Catherine A.

doi:10.1089/ees.2019.0447

Title: Metals Coprecipitation with Barite: Nano-XRF Observation of Enhanced Strontium Incorporation

Abstract

Coprecipitation can be an effective treatment method for the removal of environmentally relevant metals from industrial wastewaters such as produced waters from the oil and gas industry. The precipitation of barite, BaSO4, through the addition of sulfate removes barium while coprecipitating strontium and other alkaline earth metals even when these are present at concentrations below their solubility limit. Among other analytical methods, X-ray fluorescence (XRF) nanospectroscopy at the Hard X-ray Nanoprobe (HXN) beamline at the National Synchrotron Light Source II (NSLS-II) was used to quantify Sr incorporation into barite. Thermodynamic modeling of (Ba,Sr)SO4 solid solutions was done using solid solution—aqueous solution (SS-AS) theory. The quantitative, high-resolution nano-XRF data show clearly that the Sr content in (Ba,Sr)SO4 solid solutions varies widely among particles and even within a single particle. We observed substantial Sr incorporation that is far larger than thermodynamic models predict, likely indicating the formation of metastable solid solutions. We also observed that increasing barite supersaturation of the aqueous phase led to increased Sr incorporation, as predicted by available kinetic models. These results suggest that coprecipitation offers significant potential for designing treatment systems for aqueous metals’ removal in desired metastable compositions. Solution conditions may be optimized to enhance the incorporationmore »« less

Authors:

Hunter, Heather A. ^[1]; Ling, Florence T. ^[1]; Peters, Catherine A. ^[1]

Princeton Univ., NJ (United States). Dept. of Civil & Environmental Engineering

Publication Date:: Wed Apr 01 00:00:00 EDT 2020

Research Org.:: Univ. of Chicago, IL (United States); Brookhaven National Lab. (BNL), Upton, NY (United States)

Sponsoring Org.:: USDOE Office of Science (SC)

OSTI Identifier:: 1800763

Grant/Contract Number:: FG02-92ER14244; SC0012704

Resource Type:: Accepted Manuscript

Journal Name:: Environmental Engineering Science (Online)

Additional Journal Information:: Journal Name: Environmental Engineering Science (Online); Journal Volume: 37; Journal Issue: 4; Journal ID: ISSN 1557-9018

Publisher:: Mary Ann Liebert, Inc.

Country of Publication:: United States

Language:: English

Subject:: 42 ENGINEERING; 54 ENVIRONMENTAL SCIENCES; Engineering; Environmental Sciences & Ecology; barite; coprecipitation; industrial wastewater; metals; solid solution; strontium; trace elements

Citation Formats


                    Hunter, Heather A., Ling, Florence T., and Peters, Catherine A. Metals Coprecipitation with Barite: Nano-XRF Observation of Enhanced Strontium Incorporation.  United States: N. p., 2020. 
Web.  doi:10.1089/ees.2019.0447.

Copy to clipboard


                    Hunter, Heather A., Ling, Florence T., & Peters, Catherine A. Metals Coprecipitation with Barite: Nano-XRF Observation of Enhanced Strontium Incorporation.  United States.  https://doi.org/10.1089/ees.2019.0447

Copy to clipboard


                    Hunter, Heather A., Ling, Florence T., and Peters, Catherine A. Wed .  
"Metals Coprecipitation with Barite: Nano-XRF Observation of Enhanced Strontium Incorporation".  United States.  https://doi.org/10.1089/ees.2019.0447.  https://www.osti.gov/servlets/purl/1800763.

Copy to clipboard


                    
@article{osti_1800763,

  title        = {Metals Coprecipitation with Barite: Nano-XRF Observation of Enhanced Strontium Incorporation},

  author       = {Hunter, Heather A. and Ling, Florence T. and Peters, Catherine A.},

  abstractNote = {Coprecipitation can be an effective treatment method for the removal of environmentally relevant metals from industrial wastewaters such as produced waters from the oil and gas industry. The precipitation of barite, BaSO4, through the addition of sulfate removes barium while coprecipitating strontium and other alkaline earth metals even when these are present at concentrations below their solubility limit. Among other analytical methods, X-ray fluorescence (XRF) nanospectroscopy at the Hard X-ray Nanoprobe (HXN) beamline at the National Synchrotron Light Source II (NSLS-II) was used to quantify Sr incorporation into barite. Thermodynamic modeling of (Ba,Sr)SO4 solid solutions was done using solid solution—aqueous solution (SS-AS) theory. The quantitative, high-resolution nano-XRF data show clearly that the Sr content in (Ba,Sr)SO4 solid solutions varies widely among particles and even within a single particle. We observed substantial Sr incorporation that is far larger than thermodynamic models predict, likely indicating the formation of metastable solid solutions. We also observed that increasing barite supersaturation of the aqueous phase led to increased Sr incorporation, as predicted by available kinetic models. These results suggest that coprecipitation offers significant potential for designing treatment systems for aqueous metals’ removal in desired metastable compositions. Solution conditions may be optimized to enhance the incorporation of Sr by increasing sulfate addition such that the barite saturation index remains above *3 or by increasing the aqueous Sr to Ba ratio.},

  doi          = {10.1089/ees.2019.0447},

  journal      = {Environmental Engineering Science (Online)},

  number       = 4,

  volume       = 37,

  place        = {United States},

  year         = {Wed Apr 01 00:00:00 EDT 2020},

  month        = {Wed Apr 01 00:00:00 EDT 2020}

}

Copy to clipboard

Journal Article:

Free Publicly Available Full Text

Accepted Manuscript (DOE)

Publisher's Version of Record

https://doi.org/10.1089/ees.2019.0447

Other availability

Search WorldCat to find libraries that may hold this journal

Save / Share:

Export Metadata

Save to My Library

Works referenced in this record:

On the estimation of surface entropy factor, interfacial tension, dissolution enthalpy and metastable zone-width for substances crystallizing from solution
journal, September 1989

Sangwal, K.
Journal of Crystal Growth, Vol. 97, Issue 2
DOI: 10.1016/0022-0248(89)90221-2

Radium uptake during barite recrystallization at 23±2°C as a function of solution composition: An experimental 133Ba and 226Ra tracer study
journal, June 2010

Curti, E.; Fujiwara, K.; Iijima, K.
Geochimica et Cosmochimica Acta, Vol. 74, Issue 12
DOI: 10.1016/j.gca.2010.03.018

A model of oscillatory zoning in solid solutions grown from aqueous solutions: Applications to the (Ba,Sr)SO 4 system
journal, February 2002

L’Heureux, Ivan; Jamtveit, Bjørn
Geochimica et Cosmochimica Acta, Vol. 66, Issue 3
DOI: 10.1016/S0016-7037(01)00792-X

Celestite (SrSO4(s)) solubility in water, seawater and NaCl solution
journal, January 1987

Reardon, E. J.; Armstrong, D. K.
Geochimica et Cosmochimica Acta, Vol. 51, Issue 1
DOI: 10.1016/0016-7037(87)90007-X

A Critical Review of the Risks to Water Resources from Unconventional Shale Gas Development and Hydraulic Fracturing in the United States
journal, March 2014

Vengosh, Avner; Jackson, Robert B.; Warner, Nathaniel
Environmental Science & Technology, Vol. 48, Issue 15
DOI: 10.1021/es405118y

Vibrational spectroscopy of functional group chemistry and arsenate coordination in ettringite
journal, November 1998

Myneni, Satish C. B.; Traina, Samuel J.; Waychunas, Glenn A.
Geochimica et Cosmochimica Acta, Vol. 62, Issue 21-22
DOI: 10.1016/S0016-7037(98)00221-X

Impact of Shale Gas Development on Regional Water Quality
journal, May 2013

Vidic, R. D.; Brantley, S. L.; Vandenbossche, J. M.
Science, Vol. 340, Issue 6134
DOI: 10.1126/science.1235009

Determination of interfacial tension from crystallization and dissolution data: a comparison with other methods
journal, February 1999

Wu, Wenju; Nancollas, George H.
Advances in Colloid and Interface Science, Vol. 79, Issue 2-3
DOI: 10.1016/S0001-8686(98)00072-4

Crystallization behavior of solid solutions from aqueous solutions: An environmental perspective
journal, September 2016

Prieto, Manuel; Heberling, Frank; Rodríguez-Galán, Rosa M.
Progress in Crystal Growth and Characterization of Materials, Vol. 62, Issue 3
DOI: 10.1016/j.pcrysgrow.2016.05.001

Hydraulic “Fracking”: Are surface water impacts an ecological concern?: Hydraulic fracturing versus surface waters
journal, July 2014

Burton, G. Allen; Basu, Niladri; Ellis, Brian R.
Environmental Toxicology and Chemistry, Vol. 33, Issue 8
DOI: 10.1002/etc.2619

Removal of Radium from Synthetic Shale Gas Brines by Ion Exchange Resin
journal, October 2016

Bi, Yuqiang; Zhang, Hui; Ellis, Brian R.
Environmental Engineering Science, Vol. 33, Issue 10
DOI: 10.1089/ees.2016.0002

Hydraulic Fracturing Fluid Compositions Induce Differential Enrichment of Soil Bacterial Communities
journal, April 2019

Lozano, Tania M.; McCutchan, Aubrey Lynn; Krzmarzick, Mark James
Environmental Engineering Science, Vol. 36, Issue 4
DOI: 10.1089/ees.2018.0271

Chemical dissolution of oilfield strontium sulfate (SrSO4) scale by chelating agents
journal, July 2019

Coll de Pasquali, Daniela; Horai, Edward; Real, Md Isreq
Applied Geochemistry, Vol. 106
DOI: 10.1016/j.apgeochem.2019.05.004

The kinetics of nucleation of solid solutions from aqueous solutions: a new model for calculating non-equilibrium distribution coefficients
journal, January 2002

Pina, C. M.; Putnis, A.
Geochimica et Cosmochimica Acta, Vol. 66, Issue 2
DOI: 10.1016/S0016-7037(01)00770-0

Impact of Aluminum and Iron (III) Ions on Removal of Fluoride Ion (F ⁻ ) by Calcite
journal, November 2019

Toumari, Arman; Stenstrom, Michael K.; Suffet, I. H. (Mel)
Environmental Engineering Science, Vol. 36, Issue 11
DOI: 10.1089/ees.2019.0189

Geochemical evaluation of flowback brine from Marcellus gas wells in Pennsylvania, USA
journal, January 2013

Haluszczak, Lara O.; Rose, Arthur W.; Kump, Lee R.
Applied Geochemistry, Vol. 28
DOI: 10.1016/j.apgeochem.2012.10.002

Thermodynamic properties of the (Ba,Pb)SO4 solid solution under ambient conditions: Implications for the behavior of Pb and Ra in the environment
journal, March 2013

Fernández-González, Angeles; Carneiro, Joana; Katsikopoulos, Dionisis
Geochimica et Cosmochimica Acta, Vol. 105
DOI: 10.1016/j.gca.2012.11.042

How well suited are current thermodynamic models to predict or interpret the composition of (Ba,Sr)SO4 solid-solutions in geothermal scalings?
journal, June 2017

Heberling, Frank; Schild, Dieter; Degering, Detlev
Geothermal Energy, Vol. 5, Issue 1
DOI: 10.1186/s40517-017-0068-x

A new technique for removing strontium from seawater by coprecipitation with barite
journal, October 2018

Tokunaga, Kohei; Kozai, Naofumi; Takahashi, Yoshio
Journal of Hazardous Materials, Vol. 359
DOI: 10.1016/j.jhazmat.2018.07.044

Coprecipitation of radionuclides with calcite: estimation of partition coefficients based on a review of laboratory investigations and geochemical data
journal, June 1999

Curti, Enzo
Applied Geochemistry, Vol. 14, Issue 4
DOI: 10.1016/S0883-2927(98)00065-1

Contrasting sources and mobility of trace metals in recent sediments of western Lake Erie
journal, October 2018

Yuan, Fasong; Chaffin, Justin D.; Xue, Bin
Journal of Great Lakes Research, Vol. 44, Issue 5
DOI: 10.1016/j.jglr.2018.07.016

A conceptual model for near-surface kinetic controls on the trace-element and stable isotope composition of abiogenic calcite crystals 1 1Associate editor: R.H. Byrne
journal, April 2004

Watson, E. Bruce
Geochimica et Cosmochimica Acta, Vol. 68, Issue 7
DOI: 10.1016/j.gca.2003.10.003

Life Cycle Water Consumption and Wastewater Generation Impacts of a Marcellus Shale Gas Well
journal, January 2014

Jiang, Mohan; Hendrickson, Chris T.; VanBriesen, Jeanne M.
Environmental Science & Technology, Vol. 48, Issue 3
DOI: 10.1021/es4047654

Radium removal in a large scale evaporitic system
journal, February 2013

Rosenberg, Yoav Oved; Metz, Volker; Ganor, Jiwchar
Geochimica et Cosmochimica Acta, Vol. 103
DOI: 10.1016/j.gca.2012.10.046

Nucleation, growth, and zoning phenomena in crystallizing (Ba,Sr)CO3, Ba(SO4,CrO4), (Ba,Sr)SO4, and (Cd,Ca)CO3 solid solutions from aqueous solutions
journal, August 1997

Prieto, M.; Fernández-González, A.; Putnis, A.
Geochimica et Cosmochimica Acta, Vol. 61, Issue 16
DOI: 10.1016/S0016-7037(97)00160-9

Nucleation and growth kinetics of RaxBa1−xSO4 solid solution in NaCl aqueous solutions
journal, January 2014

Rosenberg, Yoav O.; Sadeh, Yonatan; Metz, Volker
Geochimica et Cosmochimica Acta, Vol. 125
DOI: 10.1016/j.gca.2013.09.041

On-site treatment of flowback and produced water from shale gas hydraulic fracturing: A review and economic evaluation
journal, December 2018

Mohammad-Pajooh, Ehsan; Weichgrebe, Dirk; Cuff, Graham
Chemosphere, Vol. 212
DOI: 10.1016/j.chemosphere.2018.08.145

Solid-Solution Solubilities and Thermodynamics: Sulfates, Carbonates and Halides
journal, January 2000

Glynn, P.
Reviews in Mineralogy and Geochemistry, Vol. 40, Issue 1
DOI: 10.2138/rmg.2000.40.10

Coprecipitation in the barite isostructural family: 1. binary mixing properties
journal, August 2004

Zhu, Chen
Geochimica et Cosmochimica Acta, Vol. 68, Issue 16
DOI: 10.1016/j.gca.2003.10.014

Reaction paths and equilibrium end-points in solid-solution aqueous-solution systems
journal, February 1990

Glynn, Pierre D.; Reardon, Eric J.; Plummer, L. Niel
Geochimica et Cosmochimica Acta, Vol. 54, Issue 2
DOI: 10.1016/0016-7037(90)90317-E

Co-precipitation of Radium with Barium and Strontium Sulfate and Its Impact on the Fate of Radium during Treatment of Produced Water from Unconventional Gas Extraction
journal, March 2014

Zhang, Tieyuan; Gregory, Kelvin; Hammack, Richard W.
Environmental Science & Technology, Vol. 48, Issue 8
DOI: 10.1021/es405168b

Incorporation of Metals into Calcite in a Deep Anoxic Granite Aquifer
journal, January 2018

Drake, Henrik; Mathurin, Frédéric A.; Zack, Thomas
Environmental Science & Technology, Vol. 52, Issue 2
DOI: 10.1021/acs.est.7b05258

Nanospectroscopy Captures Nanoscale Compositional Zonation in Barite Solid Solutions
journal, August 2018

Ling, Florence T.; Hunter, Heather A.; Fitts, Jeffrey P.
Scientific Reports, Vol. 8, Issue 1
DOI: 10.1038/s41598-018-31335-3

Thermodynamics of Solid Solution-Aqueous Solution Systems
journal, January 2009

Prieto, M.
Reviews in Mineralogy and Geochemistry, Vol. 70, Issue 1
DOI: 10.2138/rmg.2009.70.2

Organic–mineral interfacial chemistry drives heterogeneous nucleation of Sr-rich (Ba _x , Sr _{1− x} )SO ₄ from undersaturated solution
journal, May 2019

Deng, Ning; Stack, Andrew G.; Weber, Juliane
Proceedings of the National Academy of Sciences, Vol. 116, Issue 27
DOI: 10.1073/pnas.1821065116

Unraveling the Effects of Strontium Incorporation on Barite Growth—In Situ and Ex Situ Observations Using Multiscale Chemical Imaging
journal, July 2018

Weber, Juliane; Bracco, Jacquelyn N.; Poplawsky, Jonathan D.
Crystal Growth & Design, Vol. 18, Issue 9
DOI: 10.1021/acs.cgd.8b00839

Element mobilization from Bakken shales as a function of water chemistry
journal, April 2016

Wang, Lin; Burns, Scott; Giammar, Daniel E.
Chemosphere, Vol. 149
DOI: 10.1016/j.chemosphere.2016.01.107

An Apatite II permeable reactive barrier to remediate groundwater containing Zn, Pb and Cd
journal, August 2006

Conca, James L.; Wright, Judith
Applied Geochemistry, Vol. 21, Issue 8
DOI: 10.1016/j.apgeochem.2006.06.008

Scale formation in porous media and its impact on reservoir performance during water flooding
journal, March 2017

Hajirezaie, Sassan; Wu, Xingru; Peters, Catherine A.
Journal of Natural Gas Science and Engineering, Vol. 39
DOI: 10.1016/j.jngse.2017.01.019

Review of technologies for oil and gas produced water treatment
journal, October 2009

Fakhru’l-Razi, Ahmadun; Pendashteh, Alireza; Abdullah, Luqman Chuah
Journal of Hazardous Materials, Vol. 170, Issue 2-3
DOI: 10.1016/j.jhazmat.2009.05.044

Kinetics and Equilibrium of Barium and Strontium Sulfate Formation in Marcellus Shale Flowback Water
journal, May 2014

He, Can; Li, Meng; Liu, Wenshi
Journal of Environmental Engineering, Vol. 140, Issue 5
DOI: 10.1061/(ASCE)EE.1943-7870.0000807

Impact of Water Chemistry on Element Mobilization from Eagle Ford Shale
journal, April 2015

Wang, Lin; Fortner, John D.; Giammar, Daniel E.
Environmental Engineering Science, Vol. 32, Issue 4
DOI: 10.1089/ees.2014.0342

Effective Removal of Selenite and Selenate Ions from Aqueous Solution by Barite
journal, July 2017

Tokunaga, Kohei; Takahashi, Yoshio
Environmental Science & Technology, Vol. 51, Issue 16
DOI: 10.1021/acs.est.7b01219

Barite–Celestine Geochemistry and Environments of Formation
journal, January 2000

Hanor, Jeffrey S.
Reviews in Mineralogy and Geochemistry, Vol. 40, Issue 1
DOI: 10.2138/rmg.2000.40.4

A unified approach to model uptake kinetics of trace elements in complex aqueous – solid solution systems
journal, February 2014

Thien, Bruno M. J.; Kulik, Dmitrii A.; Curti, Enzo
Applied Geochemistry, Vol. 41
DOI: 10.1016/j.apgeochem.2013.12.002

Solubility of pyromorphite Pb5(PO4)3Cl–mimetite Pb5(AsO4)3Cl solid solution series
journal, April 2011

Flis, Justyna; Manecki, Maciej; Bajda, Tomasz
Geochimica et Cosmochimica Acta, Vol. 75, Issue 7
DOI: 10.1016/j.gca.2011.01.021

Removal of heavy metal ions from wastewaters: A review
journal, March 2011

Fu, Fenglian; Wang, Qi
Journal of Environmental Management, Vol. 92, Issue 3
DOI: 10.1016/j.jenvman.2010.11.011

Current perspective on produced water management challenges during hydraulic fracturing for oil and gas recovery
journal, January 2015

Gregory, Kelvin; Mohan, Arvind Murali
Environmental Chemistry, Vol. 12, Issue 3
DOI: 10.1071/EN15001

Simulation of the nucleation and growth of binary solid solutions in aqueous solutions
journal, January 2010

Noguera, C.; Fritz, B.; Clément, A.
Chemical Geology, Vol. 269, Issue 1-2
DOI: 10.1016/j.chemgeo.2009.05.025

The Nucleation Kinetics of Barium Sulfate in NaCl Solutions up to 6 m and 90°C
journal, September 1995

He, Shiliang; Oddo, John E.; Tomson, Mason B.
Journal of Colloid and Interface Science, Vol. 174, Issue 2
DOI: 10.1006/jcis.1995.1397

Similar Records in DOE PAGES and OSTI.GOV collections:

Nanospectroscopy Captures Nanoscale Compositional Zonation in Barite Solid Solutions

Journal Article Ling, Florence T. ; Hunter, Heather A. ; Fitts, Jeffrey P. ; ... - Scientific Reports

Scientists have long suspected that compositionally zoned particles can form under far-from equilibrium precipitation conditions, but their inferences have been based on bulk solid and solution measurements. We are the first to directly observe nanoscale trace element compositional zonation in <10 µm-sized particles using X-ray fluorescence nanospectroscopy at the Hard X-ray Nanoprobe (HXN) Beamline at National Synchrotron Light Source II (NSLS-II). Through high-resolution images, compositional zonation was observed in barite (BaSO₄) particles precipitated from aqueous solution, in which Sr²⁺ cations as well as HAsO₄^2- anions were co-precipitated into (Ba,Sr)SO₄ or Ba(SO₄,HAsO₄) solid solutions. Under high salinity conditions (NaCl ≥ 1.0more »« less
Cited by 17
https://doi.org/10.1038/s41598-018-31335-3
Thermodynamic model for the solubility of BaSeO4(cr) in the aqueous Ba2+-SeO42--Na+-H+-OH--H2O system: Extending to high selenate concentrations

Journal Article Rai, Dhanpat ; Felmy, Andrew R. ; Moore, Dean A. ; ... - Radiochimica Acta, 102(9):817-830

The solubility of Ba(SeO4, SO4) precipitates was determined as a function of the BaSeO4 mole fractions, ranging from 0.0015 to 0.3830, and time with an equilibration period extending to as long as 302 days. Equilibrium/steady state conditions in this system are reached in ≤ 65 days. Pitzer’s ion interaction model was used to calculate solid and aqueous phase activity coefficients. Thermodynamic analyses showed that the data do not satisfy Gibbs-Duhem equation, thereby demonstrating that a single-solid solution phase does not control both the selenate and sulfate concentrations. Our extensive data with log10 [Ba]) ranging from -3.6 to -5.9 mol.kg-1, log10more »« less
https://doi.org/10.1515/ract-2013-2206
Unraveling the Effects of Strontium Incorporation on Barite Growth—In Situ and Ex Situ Observations Using Multiscale Chemical Imaging

Journal Article Weber, Juliane ; Bracco, Jacquelyn N. ; Poplawsky, Jonathan D. ; ... - Crystal Growth and Design

Impurity ions influence mineral growth rates through a variety of kinetic and thermodynamic processes that also affect partitioning of the impurity ion between the solid and solution. Here, the effect of an impurity ion, strontium, on Barite (BaSO₄) (001) growth rates was studied using a combination of high-resolution in situ microscopy with ex situ chemical imaging techniques. In the presence of strontium,more »« less
Cited by 18
https://doi.org/10.1021/acs.cgd.8b00839

Full Text Available
Selenite and Selenate Sequestration during Coprecipitation with Barite: Insights from Mineralization Processes of Adsorption, Nucleation, and Growth

Journal Article Deng, Ning ; Zuo, Xiaobing ; Stack, Andrew G. ; ... - Environmental Science and Technology

Coprecipitation of selenium oxyanions with barite is a facile way to sequester Se in the environments. However, the chemical composition of Se-barite coprecipitates usually deviates from that predicted from thermodynamic calculations. This discrepancy was resolved by considering variations in nucleation and growth rates controlled by ion–mineral interactions, solubility, and interfacial energy. For homogeneous precipitation, ~10% of sulfate, higher than thermodynamic predictions (<0.3%), was substituted by Se(IV) or Se(VI) oxyanion, which was attributed to adsorption-induced entrapment during crystal growth. For heterogeneous precipitation, thiol- and carboxylic-based organic films, utilized as model interfaces to mimic the natural organic-abundant environments, further enhanced the sequestrationmore »« less
https://doi.org/10.1021/acs.est.2c03292

Full Text Available
Inorganic Ba-Sn Nanocomposite Materials for Sulfate Sequestration from Complex Aqueous Solutions

Journal Article Johnson, Isaac ; Chatterjee, Sayandev ; Hall, Gabriel B. ; ... - Environmental Science Nano

Selective sequestration of sulfate (SO42-) in the form of barite (BaSO4) from alkaline solutions of high ionic strength containing carbonate at high concentrations resembling legacy radioactive waste generated during plutonium cold war era production is problematic due to the preferential formation of BaCO3. Incorporation of sulfate into the insoluble and thermally stable BaSO4 phase can potentially benefit radioactive waste processing in reducing operational challenges and suppressing volatilization of other waste components such as technetium-99. To enhance selectivity of SO42- sequestration, a series of Ba(II)-Sn(IV) materials was prepared using simple hydrothermal synthesis from different Sn(II) and Sn(IV) precursors. Structural characterization indicatedmore »« less
https://doi.org/10.1039/C7EN01241A

Similar Records

Title: Metals Coprecipitation with Barite: Nano-XRF Observation of Enhanced Strontium Incorporation

Abstract

Citation Formats

On the estimation of surface entropy factor, interfacial tension, dissolution enthalpy and metastable zone-width for substances crystallizing from solution journal, September 1989

Radium uptake during barite recrystallization at 23±2°C as a function of solution composition: An experimental 133Ba and 226Ra tracer study journal, June 2010

A model of oscillatory zoning in solid solutions grown from aqueous solutions: Applications to the (Ba,Sr)SO 4 system journal, February 2002

Celestite (SrSO4(s)) solubility in water, seawater and NaCl solution journal, January 1987

A Critical Review of the Risks to Water Resources from Unconventional Shale Gas Development and Hydraulic Fracturing in the United States journal, March 2014

Vibrational spectroscopy of functional group chemistry and arsenate coordination in ettringite journal, November 1998

Impact of Shale Gas Development on Regional Water Quality journal, May 2013

Determination of interfacial tension from crystallization and dissolution data: a comparison with other methods journal, February 1999

Crystallization behavior of solid solutions from aqueous solutions: An environmental perspective journal, September 2016

Hydraulic “Fracking”: Are surface water impacts an ecological concern?: Hydraulic fracturing versus surface waters journal, July 2014

Removal of Radium from Synthetic Shale Gas Brines by Ion Exchange Resin journal, October 2016

Hydraulic Fracturing Fluid Compositions Induce Differential Enrichment of Soil Bacterial Communities journal, April 2019

Chemical dissolution of oilfield strontium sulfate (SrSO4) scale by chelating agents journal, July 2019

The kinetics of nucleation of solid solutions from aqueous solutions: a new model for calculating non-equilibrium distribution coefficients journal, January 2002

Impact of Aluminum and Iron (III) Ions on Removal of Fluoride Ion (F − ) by Calcite journal, November 2019

Geochemical evaluation of flowback brine from Marcellus gas wells in Pennsylvania, USA journal, January 2013

Thermodynamic properties of the (Ba,Pb)SO4 solid solution under ambient conditions: Implications for the behavior of Pb and Ra in the environment journal, March 2013

How well suited are current thermodynamic models to predict or interpret the composition of (Ba,Sr)SO4 solid-solutions in geothermal scalings? journal, June 2017

A new technique for removing strontium from seawater by coprecipitation with barite journal, October 2018

Coprecipitation of radionuclides with calcite: estimation of partition coefficients based on a review of laboratory investigations and geochemical data journal, June 1999

Contrasting sources and mobility of trace metals in recent sediments of western Lake Erie journal, October 2018

A conceptual model for near-surface kinetic controls on the trace-element and stable isotope composition of abiogenic calcite crystals 1 1Associate editor: R.H. Byrne journal, April 2004

Life Cycle Water Consumption and Wastewater Generation Impacts of a Marcellus Shale Gas Well journal, January 2014

Radium removal in a large scale evaporitic system journal, February 2013

Nucleation, growth, and zoning phenomena in crystallizing (Ba,Sr)CO3, Ba(SO4,CrO4), (Ba,Sr)SO4, and (Cd,Ca)CO3 solid solutions from aqueous solutions journal, August 1997

Nucleation and growth kinetics of RaxBa1−xSO4 solid solution in NaCl aqueous solutions journal, January 2014

On-site treatment of flowback and produced water from shale gas hydraulic fracturing: A review and economic evaluation journal, December 2018

Solid-Solution Solubilities and Thermodynamics: Sulfates, Carbonates and Halides journal, January 2000

Coprecipitation in the barite isostructural family: 1. binary mixing properties journal, August 2004

Reaction paths and equilibrium end-points in solid-solution aqueous-solution systems journal, February 1990

Co-precipitation of Radium with Barium and Strontium Sulfate and Its Impact on the Fate of Radium during Treatment of Produced Water from Unconventional Gas Extraction journal, March 2014

Incorporation of Metals into Calcite in a Deep Anoxic Granite Aquifer journal, January 2018

Nanospectroscopy Captures Nanoscale Compositional Zonation in Barite Solid Solutions journal, August 2018

Thermodynamics of Solid Solution-Aqueous Solution Systems journal, January 2009

Organic–mineral interfacial chemistry drives heterogeneous nucleation of Sr-rich (Ba x , Sr 1− x )SO 4 from undersaturated solution journal, May 2019

Unraveling the Effects of Strontium Incorporation on Barite Growth—In Situ and Ex Situ Observations Using Multiscale Chemical Imaging journal, July 2018

Element mobilization from Bakken shales as a function of water chemistry journal, April 2016

An Apatite II permeable reactive barrier to remediate groundwater containing Zn, Pb and Cd journal, August 2006

Scale formation in porous media and its impact on reservoir performance during water flooding journal, March 2017

Review of technologies for oil and gas produced water treatment journal, October 2009

Kinetics and Equilibrium of Barium and Strontium Sulfate Formation in Marcellus Shale Flowback Water journal, May 2014

Impact of Water Chemistry on Element Mobilization from Eagle Ford Shale journal, April 2015

Effective Removal of Selenite and Selenate Ions from Aqueous Solution by Barite journal, July 2017

Barite–Celestine Geochemistry and Environments of Formation journal, January 2000

A unified approach to model uptake kinetics of trace elements in complex aqueous – solid solution systems journal, February 2014

Solubility of pyromorphite Pb5(PO4)3Cl–mimetite Pb5(AsO4)3Cl solid solution series journal, April 2011

Removal of heavy metal ions from wastewaters: A review journal, March 2011

Current perspective on produced water management challenges during hydraulic fracturing for oil and gas recovery journal, January 2015

Simulation of the nucleation and growth of binary solid solutions in aqueous solutions journal, January 2010

The Nucleation Kinetics of Barium Sulfate in NaCl Solutions up to 6 m and 90°C journal, September 1995

On the estimation of surface entropy factor, interfacial tension, dissolution enthalpy and metastable zone-width for substances crystallizing from solution
journal, September 1989

Radium uptake during barite recrystallization at 23±2°C as a function of solution composition: An experimental 133Ba and 226Ra tracer study
journal, June 2010

A model of oscillatory zoning in solid solutions grown from aqueous solutions: Applications to the (Ba,Sr)SO 4 system
journal, February 2002

Celestite (SrSO4(s)) solubility in water, seawater and NaCl solution
journal, January 1987

A Critical Review of the Risks to Water Resources from Unconventional Shale Gas Development and Hydraulic Fracturing in the United States
journal, March 2014

Vibrational spectroscopy of functional group chemistry and arsenate coordination in ettringite
journal, November 1998

Impact of Shale Gas Development on Regional Water Quality
journal, May 2013

Determination of interfacial tension from crystallization and dissolution data: a comparison with other methods
journal, February 1999

Crystallization behavior of solid solutions from aqueous solutions: An environmental perspective
journal, September 2016

Hydraulic “Fracking”: Are surface water impacts an ecological concern?: Hydraulic fracturing versus surface waters
journal, July 2014

Removal of Radium from Synthetic Shale Gas Brines by Ion Exchange Resin
journal, October 2016

Hydraulic Fracturing Fluid Compositions Induce Differential Enrichment of Soil Bacterial Communities
journal, April 2019

Chemical dissolution of oilfield strontium sulfate (SrSO4) scale by chelating agents
journal, July 2019

The kinetics of nucleation of solid solutions from aqueous solutions: a new model for calculating non-equilibrium distribution coefficients
journal, January 2002

Impact of Aluminum and Iron (III) Ions on Removal of Fluoride Ion (F ⁻ ) by Calcite
journal, November 2019

Geochemical evaluation of flowback brine from Marcellus gas wells in Pennsylvania, USA
journal, January 2013

Thermodynamic properties of the (Ba,Pb)SO4 solid solution under ambient conditions: Implications for the behavior of Pb and Ra in the environment
journal, March 2013

How well suited are current thermodynamic models to predict or interpret the composition of (Ba,Sr)SO4 solid-solutions in geothermal scalings?
journal, June 2017

A new technique for removing strontium from seawater by coprecipitation with barite
journal, October 2018

Coprecipitation of radionuclides with calcite: estimation of partition coefficients based on a review of laboratory investigations and geochemical data
journal, June 1999

Contrasting sources and mobility of trace metals in recent sediments of western Lake Erie
journal, October 2018

A conceptual model for near-surface kinetic controls on the trace-element and stable isotope composition of abiogenic calcite crystals 1 1Associate editor: R.H. Byrne
journal, April 2004

Life Cycle Water Consumption and Wastewater Generation Impacts of a Marcellus Shale Gas Well
journal, January 2014

Radium removal in a large scale evaporitic system
journal, February 2013

Nucleation, growth, and zoning phenomena in crystallizing (Ba,Sr)CO3, Ba(SO4,CrO4), (Ba,Sr)SO4, and (Cd,Ca)CO3 solid solutions from aqueous solutions
journal, August 1997

Nucleation and growth kinetics of RaxBa1−xSO4 solid solution in NaCl aqueous solutions
journal, January 2014

On-site treatment of flowback and produced water from shale gas hydraulic fracturing: A review and economic evaluation
journal, December 2018

Solid-Solution Solubilities and Thermodynamics: Sulfates, Carbonates and Halides
journal, January 2000

Coprecipitation in the barite isostructural family: 1. binary mixing properties
journal, August 2004

Reaction paths and equilibrium end-points in solid-solution aqueous-solution systems
journal, February 1990

Co-precipitation of Radium with Barium and Strontium Sulfate and Its Impact on the Fate of Radium during Treatment of Produced Water from Unconventional Gas Extraction
journal, March 2014

Incorporation of Metals into Calcite in a Deep Anoxic Granite Aquifer
journal, January 2018

Nanospectroscopy Captures Nanoscale Compositional Zonation in Barite Solid Solutions
journal, August 2018

Thermodynamics of Solid Solution-Aqueous Solution Systems
journal, January 2009

Organic–mineral interfacial chemistry drives heterogeneous nucleation of Sr-rich (Ba _x , Sr _{1− x} )SO ₄ from undersaturated solution
journal, May 2019

Unraveling the Effects of Strontium Incorporation on Barite Growth—In Situ and Ex Situ Observations Using Multiscale Chemical Imaging
journal, July 2018

Element mobilization from Bakken shales as a function of water chemistry
journal, April 2016

An Apatite II permeable reactive barrier to remediate groundwater containing Zn, Pb and Cd
journal, August 2006

Scale formation in porous media and its impact on reservoir performance during water flooding
journal, March 2017

Review of technologies for oil and gas produced water treatment
journal, October 2009

Kinetics and Equilibrium of Barium and Strontium Sulfate Formation in Marcellus Shale Flowback Water
journal, May 2014

Impact of Water Chemistry on Element Mobilization from Eagle Ford Shale
journal, April 2015

Effective Removal of Selenite and Selenate Ions from Aqueous Solution by Barite
journal, July 2017

Barite–Celestine Geochemistry and Environments of Formation
journal, January 2000

A unified approach to model uptake kinetics of trace elements in complex aqueous – solid solution systems
journal, February 2014

Solubility of pyromorphite Pb5(PO4)3Cl–mimetite Pb5(AsO4)3Cl solid solution series
journal, April 2011

Removal of heavy metal ions from wastewaters: A review
journal, March 2011

Current perspective on produced water management challenges during hydraulic fracturing for oil and gas recovery
journal, January 2015

Simulation of the nucleation and growth of binary solid solutions in aqueous solutions
journal, January 2010

The Nucleation Kinetics of Barium Sulfate in NaCl Solutions up to 6 m and 90°C
journal, September 1995