Cathodoluminescence of Ultrathin Twisted Ge1–xSnxS van der Waals Nanoribbon Waveguides
Abstract
Abstract Ultrathin van der Waals semiconductors have shown extraordinary optoelectronic and photonic properties. Propagating photonic modes make layered crystal waveguides attractive for photonic circuitry and for studying hybrid light–matter states. Accessing guided modes by conventional optics is challenging due to the limited spatial resolution and poor out‐of‐plane far‐field coupling. Scanning near‐field optical microscopy can overcome these issues and can characterize waveguide modes down to a resolution of tens of nanometers, albeit for planar samples or nanostructures with moderate height variations. Electron microscopy provides atomic‐scale localization also for more complex geometries, and recent advances have extended the accessible excitations from interband transitions to phonons. Here, bottom‐up synthesized layered semiconductor (Ge 1– x Sn x S) nanoribbons with an axial twist and deep subwavelength thickness are demonstrated as a platform for realizing waveguide modes, and cathodoluminescence spectroscopy is introduced as a tool to characterize them. Combined experiments and simulations show the excitation of guided modes by the electron beam and their efficient detection via photons emitted in the ribbon plane, which enables the measurement of key properties such as the evanescent field into the vacuum cladding with nanometer resolution. The results identify van der Waals waveguides operating in the infrared and highlightmore »
- Authors:
-
- Univ. of Nebraska, Lincoln, NE (United States)
- Publication Date:
- Research Org.:
- Univ. of Nebraska, Lincoln, NE (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES); US Department of the Navy, Office of Naval Research (ONR)
- OSTI Identifier:
- 1780782
- Alternate Identifier(s):
- OSTI ID: 1804198
- Grant/Contract Number:
- SC0016343; N00014-19-1-2384
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Advanced Materials
- Additional Journal Information:
- Journal Volume: 33; Journal Issue: 3; Journal ID: ISSN 0935-9648
- Publisher:
- Wiley
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 36 MATERIALS SCIENCE; Layered Materials; Nanoribbons; Alloys; Excitons; Nanophotonics
Citation Formats
Sutter, Peter, Khorashad, Larousse Khosravi, Argyropoulos, Christos, and Sutter, Eli. Cathodoluminescence of Ultrathin Twisted Ge1–xSnxS van der Waals Nanoribbon Waveguides. United States: N. p., 2020.
Web. doi:10.1002/adma.202006649.
Sutter, Peter, Khorashad, Larousse Khosravi, Argyropoulos, Christos, & Sutter, Eli. Cathodoluminescence of Ultrathin Twisted Ge1–xSnxS van der Waals Nanoribbon Waveguides. United States. https://doi.org/10.1002/adma.202006649
Sutter, Peter, Khorashad, Larousse Khosravi, Argyropoulos, Christos, and Sutter, Eli. Sun .
"Cathodoluminescence of Ultrathin Twisted Ge1–xSnxS van der Waals Nanoribbon Waveguides". United States. https://doi.org/10.1002/adma.202006649. https://www.osti.gov/servlets/purl/1780782.
@article{osti_1780782,
title = {Cathodoluminescence of Ultrathin Twisted Ge1–xSnxS van der Waals Nanoribbon Waveguides},
author = {Sutter, Peter and Khorashad, Larousse Khosravi and Argyropoulos, Christos and Sutter, Eli},
abstractNote = {Abstract Ultrathin van der Waals semiconductors have shown extraordinary optoelectronic and photonic properties. Propagating photonic modes make layered crystal waveguides attractive for photonic circuitry and for studying hybrid light–matter states. Accessing guided modes by conventional optics is challenging due to the limited spatial resolution and poor out‐of‐plane far‐field coupling. Scanning near‐field optical microscopy can overcome these issues and can characterize waveguide modes down to a resolution of tens of nanometers, albeit for planar samples or nanostructures with moderate height variations. Electron microscopy provides atomic‐scale localization also for more complex geometries, and recent advances have extended the accessible excitations from interband transitions to phonons. Here, bottom‐up synthesized layered semiconductor (Ge 1– x Sn x S) nanoribbons with an axial twist and deep subwavelength thickness are demonstrated as a platform for realizing waveguide modes, and cathodoluminescence spectroscopy is introduced as a tool to characterize them. Combined experiments and simulations show the excitation of guided modes by the electron beam and their efficient detection via photons emitted in the ribbon plane, which enables the measurement of key properties such as the evanescent field into the vacuum cladding with nanometer resolution. The results identify van der Waals waveguides operating in the infrared and highlight an electron‐microscopy‐based approach for probing complex‐shaped nanophotonic structures.},
doi = {10.1002/adma.202006649},
journal = {Advanced Materials},
number = 3,
volume = 33,
place = {United States},
year = {Sun Dec 06 00:00:00 EST 2020},
month = {Sun Dec 06 00:00:00 EST 2020}
}
Works referenced in this record:
Photonics and optoelectronics of 2D semiconductor transition metal dichalcogenides
journal, March 2016
- Mak, Kin Fai; Shan, Jie
- Nature Photonics, Vol. 10, Issue 4
Emerging Photoluminescence in Monolayer MoS2
journal, April 2010
- Splendiani, Andrea; Sun, Liang; Zhang, Yuanbo
- Nano Letters, Vol. 10, Issue 4, p. 1271-1275
Atomically Thin A New Direct-Gap Semiconductor
journal, September 2010
- Mak, Kin Fai; Lee, Changgu; Hone, James
- Physical Review Letters, Vol. 105, Issue 13, Article No.136805
Probing dark excitons in atomically thin semiconductors via near-field coupling to surface plasmon polaritons
journal, June 2017
- Zhou, You; Scuri, Giovanni; Wild, Dominik S.
- Nature Nanotechnology, Vol. 12, Issue 9
Probing excitonic dark states in single-layer tungsten disulphide
journal, August 2014
- Ye, Ziliang; Cao, Ting; O’Brien, Kevin
- Nature, Vol. 513, Issue 7517
Observation of biexcitons in monolayer WSe2
journal, May 2015
- You, Yumeng; Zhang, Xiao-Xiao; Berkelbach, Timothy C.
- Nature Physics, Vol. 11, Issue 6
Optically active quantum dots in monolayer WSe2
journal, May 2015
- Srivastava, Ajit; Sidler, Meinrad; Allain, Adrien V.
- Nature Nanotechnology, Vol. 10, Issue 6
Single quantum emitters in monolayer semiconductors
journal, May 2015
- He, Yu-Ming; Clark, Genevieve; Schaibley, John R.
- Nature Nanotechnology, Vol. 10, Issue 6
Control of valley polarization in monolayer MoS2 by optical helicity
journal, June 2012
- Mak, Kin Fai; He, Keliang; Shan, Jie
- Nature Nanotechnology, Vol. 7, Issue 8
Accessing valley degree of freedom in bulk Tin(II) sulfide at room temperature
journal, April 2018
- Lin, Shuren; Carvalho, Alexandra; Yan, Shancheng
- Nature Communications, Vol. 9, Issue 1
Imaging exciton–polariton transport in MoSe2 waveguides
journal, May 2017
- Hu, F.; Luan, Y.; Scott, M. E.
- Nature Photonics, Vol. 11, Issue 6
Nano-optical imaging of waveguide modes revealing light-exciton interactions
journal, August 2016
- Fei, Z.; Scott, M. E.; Gosztola, D. J.
- Physical Review B, Vol. 94, Issue 8
Germanium Sulfide Nano-Optics Probed by STEM-Cathodoluminescence Spectroscopy
journal, June 2018
- Sutter, Peter; Argyropoulos, Christos; Sutter, Eli
- Nano Letters, Vol. 18, Issue 7
Gate-tuning of graphene plasmons revealed by infrared nano-imaging
journal, June 2012
- Fei, Z.; Rodin, A. S.; Andreev, G. O.
- Nature, Vol. 487, Issue 7405
Electronic and plasmonic phenomena at graphene grain boundaries
journal, October 2013
- Fei, Z.; Rodin, A. S.; Gannett, W.
- Nature Nanotechnology, Vol. 8, Issue 11
Optical nano-imaging of gate-tunable graphene plasmons
journal, June 2012
- Chen, Jianing; Badioli, Michela; Alonso-González, Pablo
- Nature, Vol. 487, Issue 7405
Photonic crystals for nano-light in moiré graphene superlattices
journal, December 2018
- Sunku, S. S.; Ni, G. X.; Jiang, B. Y.
- Science, Vol. 362, Issue 6419
Graphene on hexagonal boron nitride as a tunable hyperbolic metamaterial
journal, June 2015
- Dai, S.; Ma, Q.; Liu, M. K.
- Nature Nanotechnology, Vol. 10, Issue 8
Highly confined low-loss plasmons in graphene–boron nitride heterostructures
journal, December 2014
- Woessner, Achim; Lundeberg, Mark B.; Gao, Yuanda
- Nature Materials, Vol. 14, Issue 4
Tunable Phonon Polaritons in Atomically Thin van der Waals Crystals of Boron Nitride
journal, March 2014
- Dai, S.; Fei, Z.; Ma, Q.
- Science, Vol. 343, Issue 6175
Probing low-energy hyperbolic polaritons in van der Waals crystals with an electron microscope
journal, July 2017
- Govyadinov, Alexander A.; Konečná, Andrea; Chuvilin, Andrey
- Nature Communications, Vol. 8, Issue 1
Guiding of visible photons at the ångström thickness limit
journal, August 2019
- Zhang, Xingwang; De-Eknamkul, Chawina; Gu, Jie
- Nature Nanotechnology, Vol. 14, Issue 9
Two-dimensional exciton–polariton—light guiding by transition metal dichalcogenide monolayers
journal, January 2015
- Khurgin, Jacob B.
- Optica, Vol. 2, Issue 8
Verfeinerung der Struktur von Germanium(II)-sulfid, GeS
journal, April 1978
- Bissert, G.; Hesse, K. -F.
- Acta Crystallographica Section B Structural Crystallography and Crystal Chemistry, Vol. 34, Issue 4
Twisted and coiled ultralong multilayer graphene ribbons
journal, June 2011
- Cranford, Steven; Buehler, Markus J.
- Modelling and Simulation in Materials Science and Engineering, Vol. 19, Issue 5
1D Wires of 2D Layered Materials: Germanium Sulfide Nanowires as Efficient Light Emitters
journal, December 2017
- Sutter, Eli; Sutter, Peter
- ACS Applied Nano Materials, Vol. 1, Issue 3
Chiral twisted van der Waals nanowires
journal, April 2019
- Sutter, Peter; Wimer, Shawn; Sutter, Eli
- Nature, Vol. 570, Issue 7761
Vapor–Liquid–Solid Growth and Optoelectronics of Gallium Sulfide van der Waals Nanowires
journal, May 2020
- Sutter, Eli; French, Jacob S.; Sutter, Stephan
- ACS Nano, Vol. 14, Issue 5
Large excitonic effects in group-IV sulfide monolayers
journal, December 2015
- Tuttle, Blair R.; Alhassan, Saeed M.; Pantelides, Sokrates T.
- Physical Review B, Vol. 92, Issue 23
Optical absorption band edge in single-crystal GeS
journal, August 1975
- Wiley, J. D.; Breitschwerdt, A.; Schönherr, E.
- Solid State Communications, Vol. 17, Issue 3
The indirect forbidden fundamental absorption edge in single-crystal germanium sulphide
journal, May 1988
- Elkorashy, A. M.
- Journal of Physics C: Solid State Physics, Vol. 21, Issue 13
Extremely confined gap surface-plasmon modes excited by electrons
journal, June 2014
- Raza, Søren; Stenger, Nicolas; Pors, Anders
- Nature Communications, Vol. 5, Issue 1
Cathodoluminescence in the scanning transmission electron microscope
journal, May 2017
- Kociak, M.; Zagonel, L. F.
- Ultramicroscopy, Vol. 176
Near-Field Electron Energy Loss Spectroscopy of Nanoparticles
journal, January 1998
- Cohen, H.; Maniv, T.; Tenne, R.
- Physical Review Letters, Vol. 80, Issue 4
Reversible MoS 2 Origami with Spatially Resolved and Reconfigurable Photosensitivity
journal, September 2019
- Xu, Weinan; Li, Tengfei; Qin, Zhao
- Nano Letters, Vol. 19, Issue 11
Two-dimensional materials in functional three-dimensional architectures with applications in photodetection and imaging
journal, April 2018
- Lee, Wonho; Liu, Yuan; Lee, Yongjun
- Nature Communications, Vol. 9, Issue 1
Silicon waveguide based TE mode converter
journal, January 2010
- Zhang, Jing; Liow, Tsung-Yang; Yu, Mingbin
- Optics Express, Vol. 18, Issue 24
Photonic Floquet topological insulators
journal, April 2013
- Rechtsman, Mikael C.; Zeuner, Julia M.; Plotnik, Yonatan
- Nature, Vol. 496, Issue 7444
Reflectivity of single-crystal GeS from 0.1 to 30 eV
journal, July 1976
- Wiley, J. D.; Buckel, W. J.; Braun, W.
- Physical Review B, Vol. 14, Issue 2