Single-Ion Conducting Polymer Electrolytes for Solid-State Lithium–Metal Batteries: Design, Performance, and Challenges
Abstract
Abstract Realizing solid‐state lithium batteries with higher energy density and enhanced safety compared to the conventional liquid lithium‐ion batteries is one of the primary research and development goals set for next‐generation batteries in this decade. In this regard, polymer electrolytes have been widely researched as solid electrolytes due to their excellent processability, flexibility, and low weight. With high cationic transference numbers ( t Li + close to 1), single‐ion conducting polymer electrolytes (SICPEs) have tremendous advantages compared to polymer electrolyte systems ( t Li + < 0.4) because of their potential to reduce the buildup of ion concentration gradients and suppress growth of lithium dendrites. The current review covers the fundamentals of SICPEs, including anionic unit synthesis, polymer structure design, and film fabrication, along with simulation and experimental results in solid‐state lithium–metal battery applications. A perspective on current challenges, possible solutions, and potential research directions of SICPEs is also discussed to provide the research community with the critical technical aspects that may advance SICPEs as solid electrolytes in next‐generation energy storage systems.
- Authors:
-
[1];
[3];
[1]
- Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
- Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Univ. of Tennessee, Knoxville, TN (United States)
- Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Univ. of Tennessee, Knoxville, TN (United States). Bredesen Center for Interdisciplinary Research and Graduate Education
- Publication Date:
- Research Org.:
- Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- OSTI Identifier:
- 1777706
- Alternate Identifier(s):
- OSTI ID: 1804544
- Grant/Contract Number:
- AC05-00OR22725; DE‐AC05‐00OR22725
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Advanced Energy Materials
- Additional Journal Information:
- Journal Volume: 11; Journal Issue: 14; Journal ID: ISSN 1614-6832
- Publisher:
- Wiley
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 25 ENERGY STORAGE; high energy density; lithium-metal batteries; polymer electrolytes; single-ion conducting
Citation Formats
Zhu, Jiadeng, Zhang, Zhen, Zhao, Sheng, Westover, Andrew, Belharouak, Ilias, and Cao, Pengfei. Single-Ion Conducting Polymer Electrolytes for Solid-State Lithium–Metal Batteries: Design, Performance, and Challenges. United States: N. p., 2021.
Web. doi:10.1002/aenm.202003836.
Zhu, Jiadeng, Zhang, Zhen, Zhao, Sheng, Westover, Andrew, Belharouak, Ilias, & Cao, Pengfei. Single-Ion Conducting Polymer Electrolytes for Solid-State Lithium–Metal Batteries: Design, Performance, and Challenges. United States. https://doi.org/10.1002/aenm.202003836
Zhu, Jiadeng, Zhang, Zhen, Zhao, Sheng, Westover, Andrew, Belharouak, Ilias, and Cao, Pengfei. Sun .
"Single-Ion Conducting Polymer Electrolytes for Solid-State Lithium–Metal Batteries: Design, Performance, and Challenges". United States. https://doi.org/10.1002/aenm.202003836. https://www.osti.gov/servlets/purl/1777706.
@article{osti_1777706,
title = {Single-Ion Conducting Polymer Electrolytes for Solid-State Lithium–Metal Batteries: Design, Performance, and Challenges},
author = {Zhu, Jiadeng and Zhang, Zhen and Zhao, Sheng and Westover, Andrew and Belharouak, Ilias and Cao, Pengfei},
abstractNote = {Abstract Realizing solid‐state lithium batteries with higher energy density and enhanced safety compared to the conventional liquid lithium‐ion batteries is one of the primary research and development goals set for next‐generation batteries in this decade. In this regard, polymer electrolytes have been widely researched as solid electrolytes due to their excellent processability, flexibility, and low weight. With high cationic transference numbers ( t Li + close to 1), single‐ion conducting polymer electrolytes (SICPEs) have tremendous advantages compared to polymer electrolyte systems ( t Li + < 0.4) because of their potential to reduce the buildup of ion concentration gradients and suppress growth of lithium dendrites. The current review covers the fundamentals of SICPEs, including anionic unit synthesis, polymer structure design, and film fabrication, along with simulation and experimental results in solid‐state lithium–metal battery applications. A perspective on current challenges, possible solutions, and potential research directions of SICPEs is also discussed to provide the research community with the critical technical aspects that may advance SICPEs as solid electrolytes in next‐generation energy storage systems.},
doi = {10.1002/aenm.202003836},
journal = {Advanced Energy Materials},
number = 14,
volume = 11,
place = {United States},
year = {Sun Feb 28 00:00:00 EST 2021},
month = {Sun Feb 28 00:00:00 EST 2021}
}
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