A Polymer-Assisted Spinodal Decomposition Strategy toward Interconnected Porous Sodium Super Ionic Conductor-Structured Polyanion-Type Materials and Their Application as a High-Power Sodium-Ion Battery Cathode
Abstract
A general polymer-assisted spinodal decomposition strategy is used to prepare hierarchically porous sodium super ionic conductor (NASICON)-structured polyanion-type materials (e.g., Na3V2(PO4)3, Li3V2(PO4)3, K3V2(PO4)3, Na4MnV(PO4)3, and Na2TiV(PO4)3) in a tetrahydrofuran/ethanol/H2O synthesis system. Depending on the boiling point of solvents, the selective evaporation of the solvents induces both macrophase separation via spinodal decomposition and mesophase separation via self-assembly of inorganic precursors and amphiphilic block copolymers, leading to the formation of hierarchically porous structures. We find that the resulting hierarchically porous Na3V2(PO4)3 possessing large specific surface area (≈77 m2 g-1) and pore volume (≈0.272 cm3 g-1) shows a high specific capacity of 117.6 mAh g-1 at 0.1 C achieving the theoretical value and a long cycling life with 77% capacity retention over 1000 cycles at 5 C. This method presented here can open a facile avenue to synthesize other hierarchically porous polyanion-type materials.
- Authors:
-
[1];
[5]
- Jilin Univ., Changchun (China). State Key Lab. of Inorganic Synthesis and Preparative Chemistry
- Shanghai Univ. (China). Materials Genome Inst.
- Jilin Univ., Changchun (China). Key Lab. of Physics and Technology for Advanced Batteries, State Key Lab. of Superhard Materials
- Chinese Academy of Sciences (CAS), Changchun (China). State Key Lab. of Rare Earth Resource Utilization, Changchun Inst. of Applied Chemistry
- Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
- Publication Date:
- Research Org.:
- Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES). Materials Sciences & Engineering Division; National Natural Science Foundation of China (NSFC); Ministry of Education of China
- OSTI Identifier:
- 1777692
- Grant/Contract Number:
- AC05-00OR22725; 21671073; 21621001; B17020
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Advanced Science
- Additional Journal Information:
- Journal Volume: n/a; Journal Issue: n/a; Journal ID: ISSN 2198-3844
- Publisher:
- Wiley
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 36 MATERIALS SCIENCE; hierarchically porous structures; macro/mesoporous materials; NASICON-structured materials; self-assembly; spinodal decomposition
Citation Formats
Xiong, Hailong, Qian, Ruicheng, Liu, Zhilin, Zhang, Rui, Sun, Ge, Guo, Bingkong, Du, Fei, Song, Shuyan, Qiao, Zhen‐An, and Dai, Sheng. A Polymer-Assisted Spinodal Decomposition Strategy toward Interconnected Porous Sodium Super Ionic Conductor-Structured Polyanion-Type Materials and Their Application as a High-Power Sodium-Ion Battery Cathode. United States: N. p., 2021.
Web. doi:10.1002/advs.202004943.
Xiong, Hailong, Qian, Ruicheng, Liu, Zhilin, Zhang, Rui, Sun, Ge, Guo, Bingkong, Du, Fei, Song, Shuyan, Qiao, Zhen‐An, & Dai, Sheng. A Polymer-Assisted Spinodal Decomposition Strategy toward Interconnected Porous Sodium Super Ionic Conductor-Structured Polyanion-Type Materials and Their Application as a High-Power Sodium-Ion Battery Cathode. United States. https://doi.org/10.1002/advs.202004943
Xiong, Hailong, Qian, Ruicheng, Liu, Zhilin, Zhang, Rui, Sun, Ge, Guo, Bingkong, Du, Fei, Song, Shuyan, Qiao, Zhen‐An, and Dai, Sheng. Sat .
"A Polymer-Assisted Spinodal Decomposition Strategy toward Interconnected Porous Sodium Super Ionic Conductor-Structured Polyanion-Type Materials and Their Application as a High-Power Sodium-Ion Battery Cathode". United States. https://doi.org/10.1002/advs.202004943. https://www.osti.gov/servlets/purl/1777692.
@article{osti_1777692,
title = {A Polymer-Assisted Spinodal Decomposition Strategy toward Interconnected Porous Sodium Super Ionic Conductor-Structured Polyanion-Type Materials and Their Application as a High-Power Sodium-Ion Battery Cathode},
author = {Xiong, Hailong and Qian, Ruicheng and Liu, Zhilin and Zhang, Rui and Sun, Ge and Guo, Bingkong and Du, Fei and Song, Shuyan and Qiao, Zhen‐An and Dai, Sheng},
abstractNote = {A general polymer-assisted spinodal decomposition strategy is used to prepare hierarchically porous sodium super ionic conductor (NASICON)-structured polyanion-type materials (e.g., Na3V2(PO4)3, Li3V2(PO4)3, K3V2(PO4)3, Na4MnV(PO4)3, and Na2TiV(PO4)3) in a tetrahydrofuran/ethanol/H2O synthesis system. Depending on the boiling point of solvents, the selective evaporation of the solvents induces both macrophase separation via spinodal decomposition and mesophase separation via self-assembly of inorganic precursors and amphiphilic block copolymers, leading to the formation of hierarchically porous structures. We find that the resulting hierarchically porous Na3V2(PO4)3 possessing large specific surface area (≈77 m2 g-1) and pore volume (≈0.272 cm3 g-1) shows a high specific capacity of 117.6 mAh g-1 at 0.1 C achieving the theoretical value and a long cycling life with 77% capacity retention over 1000 cycles at 5 C. This method presented here can open a facile avenue to synthesize other hierarchically porous polyanion-type materials.},
doi = {10.1002/advs.202004943},
journal = {Advanced Science},
number = n/a,
volume = n/a,
place = {United States},
year = {Sat Mar 20 00:00:00 EDT 2021},
month = {Sat Mar 20 00:00:00 EDT 2021}
}
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