Determination of excited state molecular structures from time-resolved gas-phase X-ray scattering

Yong, Haiwang; Carrascosa, Andrés Moreno; Ma, Lingyu; Stankus, Brian; Minitti, Michael P.; Kirrander, Adam; Weber, Peter M.

doi:10.1039/d0fd00118j

Title: Determination of excited state molecular structures from time-resolved gas-phase X-ray scattering

Abstract

We present a comprehensive investigation of a recently introduced method to determine transient structures of molecules in excited electronic states with sub-ångstrom resolution from time-resolved gas-phase scattering signals.

Authors:

^[1]; Carrascosa, Andrés Moreno ^[1];

^[1]; Stankus, Brian ^[2];

^[3];

^[4];

^[1]

Brown Univ., Providence, RI (United States)
Western Connecticut State Univ., Danbury, CT (United States)
SLAC National Accelerator Lab., Menlo Park, CA (United States)
Brown Univ., Providence, RI (United States); Univ. of Edinburgh (United Kingdom)

Publication Date:: Wed Nov 18 00:00:00 EST 2020

Research Org.:: Brown Univ., Providence, RI (United States); SLAC National Accelerator Lab., Menlo Park, CA (United States)

Sponsoring Org.:: USDOE Office of Science (SC), Basic Energy Sciences (BES). Chemical Sciences, Geosciences & Biosciences Division; USDOE Office of Science (SC), Basic Energy Sciences (BES)

OSTI Identifier:: 1773828

Alternate Identifier(s):: OSTI ID: 1766091; OSTI ID: 1778939

Grant/Contract Number:: SC0017995; SC0020276; AC02-76SF00515

Resource Type:: Accepted Manuscript

Journal Name:: Faraday Discussions

Additional Journal Information:: Journal Volume: 2021; Journal Issue: 228; Journal ID: ISSN 1359-6640

Publisher:: Royal Society of Chemistry

Country of Publication:: United States

Language:: English

Subject:: 74 ATOMIC AND MOLECULAR PHYSICS; x-ray scattering; excited state molecular structures

Citation Formats


                    Yong, Haiwang, Carrascosa, Andrés Moreno, Ma, Lingyu, Stankus, Brian, Minitti, Michael P., Kirrander, Adam, and Weber, Peter M. Determination of excited state molecular structures from time-resolved gas-phase X-ray scattering.  United States: N. p., 2020. 
Web.  doi:10.1039/d0fd00118j.

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                    Yong, Haiwang, Carrascosa, Andrés Moreno, Ma, Lingyu, Stankus, Brian, Minitti, Michael P., Kirrander, Adam, & Weber, Peter M. Determination of excited state molecular structures from time-resolved gas-phase X-ray scattering.  United States.  https://doi.org/10.1039/d0fd00118j

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                    Yong, Haiwang, Carrascosa, Andrés Moreno, Ma, Lingyu, Stankus, Brian, Minitti, Michael P., Kirrander, Adam, and Weber, Peter M. Wed .  
"Determination of excited state molecular structures from time-resolved gas-phase X-ray scattering".  United States.  https://doi.org/10.1039/d0fd00118j.  https://www.osti.gov/servlets/purl/1773828.

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@article{osti_1773828,

  title        = {Determination of excited state molecular structures from time-resolved gas-phase X-ray scattering},

  author       = {Yong, Haiwang and Carrascosa, Andrés Moreno and Ma, Lingyu and Stankus, Brian and Minitti, Michael P. and Kirrander, Adam and Weber, Peter M.},

  abstractNote = {We present a comprehensive investigation of a recently introduced method to determine transient structures of molecules in excited electronic states with sub-ångstrom resolution from time-resolved gas-phase scattering signals.},

  doi          = {10.1039/d0fd00118j},

  journal      = {Faraday Discussions},

  number       = 228,

  volume       = 2021,

  place        = {United States},

  year         = {Wed Nov 18 00:00:00 EST 2020},

  month        = {Wed Nov 18 00:00:00 EST 2020}

}

Copy to clipboard

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Title: Determination of excited state molecular structures from time-resolved gas-phase X-ray scattering

Abstract

Citation Formats

Imaging Molecular Motion: Femtosecond X-Ray Scattering of an Electrocyclic Chemical Reaction journal, June 2015

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Ab Initio Calculation of Total X-ray Scattering from Molecules journal, March 2019

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Ab Initio Calculation of Molecular Diffraction journal, October 2014

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Observation of femtosecond molecular dynamics via pump–probe gas phase x-ray scattering journal, January 2016

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Oscillatory Photoelectron Signal of N -Methylmorpholine as a Test Case for the Algebraic-Diagrammatic Construction Method of Second Order journal, November 2018

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Observation of Structural Wavepacket Motion: The Umbrella Mode in Rydberg-Excited N -Methyl Morpholine journal, July 2017

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Ultrafast x-ray and electron scattering of free molecules: A comparative evaluation journal, May 2020

Imaging Molecular Motion: Femtosecond X-Ray Scattering of an Electrocyclic Chemical Reaction
journal, June 2015

Chemical Applications of X-ray Charge-Density Analysis
journal, June 2001

Ultrafast Diffraction Imaging of the Electrocyclic Ring-Opening Reaction of 1,3-Cyclohexadiene
journal, May 2001

Imaging CF ₃ I conical intersection and photodissociation dynamics with ultrafast electron diffraction
journal, July 2018

The Morse oscillator in position space, momentum space, and phase space
journal, April 1988

Pixel array detector for X-ray free electron laser experiments
journal, September 2011

Simultaneous observation of nuclear and electronic dynamics by ultrafast electron diffraction
journal, May 2020

Excited Electronic States in Total Isotropic Scattering from Molecules
journal, March 2020

First lasing and operation of an ångstrom-wavelength free-electron laser
journal, August 2010

The photochemical ring-opening of 1,3-cyclohexadiene imaged by ultrafast electron diffraction
journal, April 2019

Determining Orientations of Optical Transition Dipole Moments Using Ultrafast X-ray Scattering
journal, October 2018

Ab Initio Calculation of Total X-ray Scattering from Molecules
journal, March 2019

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journal, March 2006

Advances in ultrafast gas-phase x-ray scattering
journal, November 2020

Ab Initio Calculation of Molecular Diffraction
journal, October 2014

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journal, November 2010

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journal, July 2019

Observation of the molecular response to light upon photoexcitation
journal, May 2020

X-ray imaging of chemically active valence electrons during a pericyclic reaction
journal, November 2014

Electron Densities from Gas‐Phase Electron Diffraction Intensities. I. Preliminary Considerations
journal, October 1969

Observation of femtosecond molecular dynamics via pump–probe gas phase x-ray scattering
journal, January 2016

Ultrafast X-ray Diffraction Theory
journal, November 1998

Oscillatory Photoelectron Signal of N -Methylmorpholine as a Test Case for the Algebraic-Diagrammatic Construction Method of Second Order
journal, November 2018

Elastic X-ray scattering from state-selected molecules
journal, October 2016

Mega-electron-volt ultrafast electron diffraction at SLAC National Accelerator Laboratory
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journal, August 1933

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journal, October 2016

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