New Insights on the Structure of Electrochemically Deposited Lithium Metal and Its Solid Electrolyte Interphases via Cryogenic TEM
Abstract
Lithium metal has been considered the “holy grail” anode material for rechargeable batteries despite the fact that its dendritic growth and low Coulombic efficiency (CE) have crippled its practical use for decades. Its high chemical reactivity and low stability make it difficult to explore the intrinsic chemical and physical properties of the electrochemically deposited lithium (EDLi) and its accompanying solid electrolyte interphase (SEI). To prevent the dendritic growth and enhance the electrochemical reversibility, it is crucial to understand the nano- and mesostructures of EDLi. However, Li metal is very sensitive to beam damage and has low contrast for commonly used characterization techniques such as electron microscopy. Inspired by biological imaging techniques, this work demonstrates the power of cryogenic (cryo)-electron microscopy to reveal the detailed structure of EDLi and the SEI composition at the nanoscale while minimizing beam damage during imaging. Surprisingly, the results show that the nucleation-dominated EDLi (5 min at 0.5 mA cm–2) is amorphous, while there is some crystalline LiF present in the SEI. The EDLi grown from various electrolytes with different additives exhibits distinctive surface properties. Consequently, these results highlight the importance of the SEI and its relationship with the CE. Furthermore, our findings not only illustratemore »
- Authors:
-
- Univ. of California San Diego, La Jolla, CA (United States); Pacific Northwest National Lab. (PNNL), Richland, WA (United States)
- Pacific Northwest National Lab. (PNNL), Richland, WA (United States)
- Publication Date:
- Research Org.:
- Univ. of California, San Diego, CA (United States)
- Sponsoring Org.:
- USDOE Office of Energy Efficiency and Renewable Energy (EERE), Transportation Office. Vehicle Technologies Office; National Science Foundation (NSF)
- OSTI Identifier:
- 1770699
- Grant/Contract Number:
- EE0007744; ECCS-1542148; CHE-1338173; AC02-05CH11231
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Nano Letters
- Additional Journal Information:
- Journal Volume: 17; Journal Issue: 12; Journal ID: ISSN 1530-6984
- Publisher:
- American Chemical Society
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; Li metal; electrochemical deposition; SEI; cryogenic TEM; metals; electrodes; deposition; surface chemistry; electrolytes
Citation Formats
Wang, Xuefeng, Zhang, Minghao, Alvarado, Judith, Wang, Shen, Sina, Mahsa, Lu, Bingyu, Bouwer, James, Xu, Wu, Xiao, Jie, Zhang, Ji-Guang, Liu, Jun, and Meng, Ying Shirley. New Insights on the Structure of Electrochemically Deposited Lithium Metal and Its Solid Electrolyte Interphases via Cryogenic TEM. United States: N. p., 2017.
Web. doi:10.1021/acs.nanolett.7b03606.
Wang, Xuefeng, Zhang, Minghao, Alvarado, Judith, Wang, Shen, Sina, Mahsa, Lu, Bingyu, Bouwer, James, Xu, Wu, Xiao, Jie, Zhang, Ji-Guang, Liu, Jun, & Meng, Ying Shirley. New Insights on the Structure of Electrochemically Deposited Lithium Metal and Its Solid Electrolyte Interphases via Cryogenic TEM. United States. https://doi.org/10.1021/acs.nanolett.7b03606
Wang, Xuefeng, Zhang, Minghao, Alvarado, Judith, Wang, Shen, Sina, Mahsa, Lu, Bingyu, Bouwer, James, Xu, Wu, Xiao, Jie, Zhang, Ji-Guang, Liu, Jun, and Meng, Ying Shirley. Wed .
"New Insights on the Structure of Electrochemically Deposited Lithium Metal and Its Solid Electrolyte Interphases via Cryogenic TEM". United States. https://doi.org/10.1021/acs.nanolett.7b03606. https://www.osti.gov/servlets/purl/1770699.
@article{osti_1770699,
title = {New Insights on the Structure of Electrochemically Deposited Lithium Metal and Its Solid Electrolyte Interphases via Cryogenic TEM},
author = {Wang, Xuefeng and Zhang, Minghao and Alvarado, Judith and Wang, Shen and Sina, Mahsa and Lu, Bingyu and Bouwer, James and Xu, Wu and Xiao, Jie and Zhang, Ji-Guang and Liu, Jun and Meng, Ying Shirley},
abstractNote = {Lithium metal has been considered the “holy grail” anode material for rechargeable batteries despite the fact that its dendritic growth and low Coulombic efficiency (CE) have crippled its practical use for decades. Its high chemical reactivity and low stability make it difficult to explore the intrinsic chemical and physical properties of the electrochemically deposited lithium (EDLi) and its accompanying solid electrolyte interphase (SEI). To prevent the dendritic growth and enhance the electrochemical reversibility, it is crucial to understand the nano- and mesostructures of EDLi. However, Li metal is very sensitive to beam damage and has low contrast for commonly used characterization techniques such as electron microscopy. Inspired by biological imaging techniques, this work demonstrates the power of cryogenic (cryo)-electron microscopy to reveal the detailed structure of EDLi and the SEI composition at the nanoscale while minimizing beam damage during imaging. Surprisingly, the results show that the nucleation-dominated EDLi (5 min at 0.5 mA cm–2) is amorphous, while there is some crystalline LiF present in the SEI. The EDLi grown from various electrolytes with different additives exhibits distinctive surface properties. Consequently, these results highlight the importance of the SEI and its relationship with the CE. Furthermore, our findings not only illustrate the capabilities of cryogenic microscopy for beam (thermal)-sensitive materials but also yield crucial structural information on the EDLi evolution with and without electrolyte additives.},
doi = {10.1021/acs.nanolett.7b03606},
journal = {Nano Letters},
number = 12,
volume = 17,
place = {United States},
year = {Wed Nov 01 00:00:00 EDT 2017},
month = {Wed Nov 01 00:00:00 EDT 2017}
}
Web of Science
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