Structure Analysis of Natural Wangdaodeite—LiNbO3-Type FeTiO3
Abstract
This paper reports the first structure refinement of natural wangdaodeite, LiNbO3-type FeTiO3 from the Ries impact structure. Wangdaodeite occurs together with recrystallized ilmenite clasts in shock melt veins which have experienced peak shock pressures of between 17 and 22 GPa. Comparison of natural and synthetic wangdaodeite points toward a correlation between the distortion of ferrate- and titanate-polyhedra and the c/a ratio of the unit cell. The Raman spectrum of wangdaodeite is calculated based on the refined structure. Comparison to the reported spectrum of the type-material shows that the Raman peak at 738–740 cm-1 is indicative for this phase, whereas other features in type-wangdaodeite are tentatively assigned to disordered ilmenite.
- Authors:
-
- Univ. of Nevada, Las Vegas, NV (United States)
- California Institute of Technology (CalTech), Pasadena, CA (United States)
- Argonne National Lab. (ANL), Argonne, IL (United States)
- Publication Date:
- Research Org.:
- Argonne National Lab. (ANL), Argonne, IL (United States). Advanced Photon Source (APS)
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 1734921
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Minerals
- Additional Journal Information:
- Journal Volume: 10; Journal Issue: 12; Journal ID: ISSN 2075-163X
- Publisher:
- MDPI
- Country of Publication:
- United States
- Language:
- ENGLISH
- Subject:
- 58 GEOSCIENCES
Citation Formats
Tschauner, Oliver, Ma, Chi, Newville, Matthew G., and Lanzirotti, Antonio. Structure Analysis of Natural Wangdaodeite—LiNbO3-Type FeTiO3. United States: N. p., 2020.
Web. doi:10.3390/min10121072.
Tschauner, Oliver, Ma, Chi, Newville, Matthew G., & Lanzirotti, Antonio. Structure Analysis of Natural Wangdaodeite—LiNbO3-Type FeTiO3. United States. https://doi.org/10.3390/min10121072
Tschauner, Oliver, Ma, Chi, Newville, Matthew G., and Lanzirotti, Antonio. Mon .
"Structure Analysis of Natural Wangdaodeite—LiNbO3-Type FeTiO3". United States. https://doi.org/10.3390/min10121072. https://www.osti.gov/servlets/purl/1734921.
@article{osti_1734921,
title = {Structure Analysis of Natural Wangdaodeite—LiNbO3-Type FeTiO3},
author = {Tschauner, Oliver and Ma, Chi and Newville, Matthew G. and Lanzirotti, Antonio},
abstractNote = {This paper reports the first structure refinement of natural wangdaodeite, LiNbO3-type FeTiO3 from the Ries impact structure. Wangdaodeite occurs together with recrystallized ilmenite clasts in shock melt veins which have experienced peak shock pressures of between 17 and 22 GPa. Comparison of natural and synthetic wangdaodeite points toward a correlation between the distortion of ferrate- and titanate-polyhedra and the c/a ratio of the unit cell. The Raman spectrum of wangdaodeite is calculated based on the refined structure. Comparison to the reported spectrum of the type-material shows that the Raman peak at 738–740 cm-1 is indicative for this phase, whereas other features in type-wangdaodeite are tentatively assigned to disordered ilmenite.},
doi = {10.3390/min10121072},
journal = {Minerals},
number = 12,
volume = 10,
place = {United States},
year = {Mon Nov 30 00:00:00 EST 2020},
month = {Mon Nov 30 00:00:00 EST 2020}
}
Works referenced in this record:
Coexistence of Weak Ferromagnetism and Ferroelectricity in the High Pressure -Type Phase of
journal, July 2009
- Varga, T.; Kumar, A.; Vlahos, E.
- Physical Review Letters, Vol. 103, Issue 4
A new dense silica polymorph: A possible link between tetrahedrally and octahedrally coordinated silica
journal, February 2004
- Luo, Sheng-Nian; Tschauner, Oliver; Asimow, Paul D.
- American Mineralogist, Vol. 89, Issue 2-3
In situ high-pressure study of LiNbO 3 -type FeTiO 3 : X-ray diffraction and Mössbauer spectroscopy
journal, September 2010
- Wu, X.; Steinle-Neumann, G.; Narygina, O.
- High Pressure Research, Vol. 30, Issue 3
A new mineral with an olivine structure and pyroxene composition in the shock-induced melt veins of Tenham L6 chondrite
journal, February 2011
- Xie, Z.; Sharp, T. G.; Leinenweber, K.
- American Mineralogist, Vol. 96, Issue 2-3
Unquenchable high-pressure perovskite polymorphs of MnSnO3 and FeTiO3
journal, December 1991
- Leinenweber, Kurt; Utsumi, Wataru; Tsuchida, Yoshihiko
- Physics and Chemistry of Minerals, Vol. 18, Issue 4
Calorimetric study of high pressure polymorphism in FeTiO3: Stability of the perovskite phase
journal, August 1994
- Mehta, Apurva; Leinenweber, Kurt; Navrotsky, Alexandra
- Physics and Chemistry of Minerals, Vol. 21, Issue 4
X-ray single-crystal and Raman study of (Na0.86Mg0.14)(Mg0.57Ti0.43)Si2O6, a new pyroxene synthesized at 7 GPa and 1700 °C
journal, July 2016
- Sirotkina, Ekaterina A.; Bobrov, Andrey V.; Spivak, Anna V.
- Physics and Chemistry of Minerals, Vol. 43, Issue 10
Akaogiite: An ultra-dense polymorph of TiO2 with the baddeleyite-type structure, in shocked garnet gneiss from the Ries Crater, Germany
journal, May 2010
- El Goresy, A.; Dubrovinsky, L.; Gillet, P.
- American Mineralogist, Vol. 95, Issue 5-6
A high-precision 40Ar/39Ar age for the Nördlinger Ries impact crater, Germany, and implications for the accurate dating of terrestrial impact events
journal, January 2018
- Schmieder, Martin; Kennedy, Trudi; Jourdan, Fred
- Geochimica et Cosmochimica Acta, Vol. 220
High-pressure transformations in silicates, germanates, and titanates with ABO3 stoichiometry
journal, January 1979
- Ito, Eiji; Matsui, Yoshito
- Physics and Chemistry of Minerals, Vol. 4, Issue 3
High-pressure and high-temperature phase transitions in FeTiO3 and a new dense FeTi3O7 structure
journal, March 2012
- Nishio-Hamane, D.; Zhang, M.; Yagi, T.
- American Mineralogist, Vol. 97, Issue 4
Majoritic garnet grains within shock-induced melt veins in amphibolites from the Ries impact crater suggest ultrahigh crystallization pressures between 18 and 9 GPa
journal, October 2017
- Stähle, Volker; Altherr, Rainer; Nasdala, Lutz
- Contributions to Mineralogy and Petrology, Vol. 172, Issue 10
Empirical constrains on volume changes in pressure-induced solid state transformations
journal, September 2020
- Tschauner, Oliver
- High Pressure Research, Vol. 40, Issue 4
Fully automated microcomputer calculation of vibrational spectra
journal, January 1987
- Dowty, Eric
- Physics and Chemistry of Minerals, Vol. 14, Issue 1
DIOPTAS : a program for reduction of two-dimensional X-ray diffraction data and data exploration
journal, May 2015
- Prescher, Clemens; Prakapenka, Vitali B.
- High Pressure Research, Vol. 35, Issue 3
Combined method for ab initio structure solution from powder diffraction data
journal, October 1999
- Putz, H.; Schön, J. C.; Jansen, M.
- Journal of Applied Crystallography, Vol. 32, Issue 5
High-pressure high-temperature phase relations in FeTiO3 up to 35 GPa and 1600 °C
journal, August 2016
- Akaogi, M.; Abe, K.; Yusa, H.
- Physics and Chemistry of Minerals, Vol. 44, Issue 1
High-pressure phase transformations and compressions of ilmenite and rutile, I. Experimental results
journal, June 1975
- Liu, Lin-Gun
- Physics of the Earth and Planetary Interiors, Vol. 10, Issue 2
Riesite, a New High Pressure Polymorph of TiO2 from the Ries Impact Structure
journal, January 2020
- Tschauner, Oliver; Ma, Chi; Lanzirotti, Antonio
- Minerals, Vol. 10, Issue 1
POWDER CELL – a program for the representation and manipulation of crystal structures and calculation of the resulting X-ray powder patterns
journal, June 1996
- Kraus, W.; Nolze, G.
- Journal of Applied Crystallography, Vol. 29, Issue 3, p. 301-303
Shock compression of ilmenite
journal, February 1976
- King, David A.; Ahrens, Thomas J.
- Journal of Geophysical Research, Vol. 81, Issue 5
In situ X-ray diffraction study of phase transitions of FeTiO 3 at high pressures and temperatures using a large-volume press and synchrotron radiation
journal, January 2006
- Ming, Li Chung; Kim, Young-Ho; Uchida, T.
- American Mineralogist, Vol. 91, Issue 1
Ca-rich majorite derived from high-temperature melt and thermally stressed hornblende in shock veins of crustal rocks from the Ries impact crater (Germany)
journal, May 2010
- Stähle, Volker; Altherr, Rainer; Nasdala, Lutz
- Contributions to Mineralogy and Petrology, Vol. 161, Issue 2
High-pressure minerals
journal, December 2019
- Tschauner, Oliver
- American Mineralogist, Vol. 104, Issue 12
Wangdaodeite, the LiNbO 3 ‐structured high‐pressure polymorph of ilmenite, a new mineral from the Suizhou L6 chondrite
journal, December 2019
- Xie, Xiande; Gu, Xiangping; Yang, Hexiong
- Meteoritics & Planetary Science, Vol. 55, Issue 1
Bilbao Crystallographic Server : Useful Databases and Tools for Phase-Transition Studies
journal, January 2003
- Kroumova, E.; Aroyo, M. I.; Perez-Mato, J. M.
- Phase Transitions, Vol. 76, Issue 1-2