Predicting secondary organic aerosol phase state and viscosity and its effect on multiphase chemistry in a regional-scale air quality model
Abstract
Atmospheric aerosols are a significant public health hazard and have substantial impacts on the climate. Secondary organic aerosols (SOAs) have been shown to phase separate into a highly viscous organic outer layer surrounding an aqueous core. This phase separation can decrease the partitioning of semi-volatile and low-volatile species to the organic phase and alter the extent of acid-catalyzed reactions in the aqueous core. A new algorithm that can determine SOA phase separation based on their glass transition temperature (Tg), oxygen to carbon (O:C) ratio and organic mass to sulfate ratio, and meteorological conditions was implemented into the Community Multiscale Air Quality Modeling (CMAQ) system version 5.2.1 and was used to simulate the conditions in the continental United States for the summer of 2013. SOA formed at the ground/surface level was predicted to be phase separated with core–shell morphology, i.e., aqueous inorganic core surrounded by organic coating 65.4 % of the time during the 2013 Southern Oxidant and Aerosol Study (SOAS) on average in the isoprene-rich southeastern United States. Our estimate is in proximity to the previously reported ~70 % in literature. The phase states of organic coatings switched between semi-solid and liquid states, depending on the environmental conditions. The semi-solid shellmore »
- Authors:
-
[2];
[3];
[4];
[5];
[1];
[7];
- Univ. of North Carolina, Chapel Hill, NC (United States)
- Univ. of North Carolina, Chapel Hill, NC (United States); Pacific Northwest National Lab. (PNNL), Richland, WA (United States)
- Univ. of North Carolina, Chapel Hill, NC (United States); Aerodyne Research, Inc., Billerica, MA (United States)
- Univ. of North Carolina, Chapel Hill, NC (United States); US Environmental Protection Agency (EPA), Research Triangle Park, NC (United States)
- Univ. of California, Riverside, CA (United States)
- Univ. of Washington, Seattle, WA (United States)
- Univ. of California, Berkeley, CA (United States)
- Publication Date:
- Research Org.:
- Pacific Northwest National Laboratory (PNNL), Richland, WA (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Biological and Environmental Research (BER); National Science Foundation (NSF); National Institutes of Health (NIH)
- OSTI Identifier:
- 1650723
- Report Number(s):
- PNNL-SA-153998
Journal ID: ISSN 1680-7324
- Grant/Contract Number:
- AC05-76RL01830; AGS-1524731; AGS-1250569; AGS-1644406; AGS-1703535; SC0018221
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Atmospheric Chemistry and Physics (Online)
- Additional Journal Information:
- Journal Name: Atmospheric Chemistry and Physics (Online); Journal Volume: 20; Journal Issue: 13; Journal ID: ISSN 1680-7324
- Publisher:
- European Geosciences Union
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; Aerosol dynamics; aerosol phase state and morphology; atmospheric modeling; tropospheric chemistry; reactive uptake
Citation Formats
Schmedding, Ryan, Rasool, Quazi Z., Zhang, Yue, Pye, Havala O. T., Zhang, Haofei, Chen, Yuzhi, Surratt, Jason D., Lopez-Hilfiker, Felipe D., Thornton, Joel A., Goldstein, Allen H., and Vizuete, William. Predicting secondary organic aerosol phase state and viscosity and its effect on multiphase chemistry in a regional-scale air quality model. United States: N. p., 2020.
Web. doi:10.5194/acp-20-8201-2020.
Schmedding, Ryan, Rasool, Quazi Z., Zhang, Yue, Pye, Havala O. T., Zhang, Haofei, Chen, Yuzhi, Surratt, Jason D., Lopez-Hilfiker, Felipe D., Thornton, Joel A., Goldstein, Allen H., & Vizuete, William. Predicting secondary organic aerosol phase state and viscosity and its effect on multiphase chemistry in a regional-scale air quality model. United States. https://doi.org/10.5194/acp-20-8201-2020
Schmedding, Ryan, Rasool, Quazi Z., Zhang, Yue, Pye, Havala O. T., Zhang, Haofei, Chen, Yuzhi, Surratt, Jason D., Lopez-Hilfiker, Felipe D., Thornton, Joel A., Goldstein, Allen H., and Vizuete, William. Thu .
"Predicting secondary organic aerosol phase state and viscosity and its effect on multiphase chemistry in a regional-scale air quality model". United States. https://doi.org/10.5194/acp-20-8201-2020. https://www.osti.gov/servlets/purl/1650723.
@article{osti_1650723,
title = {Predicting secondary organic aerosol phase state and viscosity and its effect on multiphase chemistry in a regional-scale air quality model},
author = {Schmedding, Ryan and Rasool, Quazi Z. and Zhang, Yue and Pye, Havala O. T. and Zhang, Haofei and Chen, Yuzhi and Surratt, Jason D. and Lopez-Hilfiker, Felipe D. and Thornton, Joel A. and Goldstein, Allen H. and Vizuete, William},
abstractNote = {Atmospheric aerosols are a significant public health hazard and have substantial impacts on the climate. Secondary organic aerosols (SOAs) have been shown to phase separate into a highly viscous organic outer layer surrounding an aqueous core. This phase separation can decrease the partitioning of semi-volatile and low-volatile species to the organic phase and alter the extent of acid-catalyzed reactions in the aqueous core. A new algorithm that can determine SOA phase separation based on their glass transition temperature (Tg), oxygen to carbon (O:C) ratio and organic mass to sulfate ratio, and meteorological conditions was implemented into the Community Multiscale Air Quality Modeling (CMAQ) system version 5.2.1 and was used to simulate the conditions in the continental United States for the summer of 2013. SOA formed at the ground/surface level was predicted to be phase separated with core–shell morphology, i.e., aqueous inorganic core surrounded by organic coating 65.4 % of the time during the 2013 Southern Oxidant and Aerosol Study (SOAS) on average in the isoprene-rich southeastern United States. Our estimate is in proximity to the previously reported ~70 % in literature. The phase states of organic coatings switched between semi-solid and liquid states, depending on the environmental conditions. The semi-solid shell occurring with lower aerosol liquid water content (western United States and at higher altitudes) has a viscosity that was predicted to be 102–1012 Pa s, which resulted in organic mass being decreased due to diffusion limitation. Organic aerosol was primarily liquid where aerosol liquid water was dominant (eastern United States and at the surface), with a viscosity <102 Pa s. Phase separation while in a liquid phase state, i.e., liquid–liquid phase separation (LLPS), also reduces reactive uptake rates relative to homogeneous internally mixed liquid morphology but was lower than aerosols with a thick viscous organic shell. The sensitivity cases performed with different phase-separation parameterization and dissolution rate of isoprene epoxydiol (IEPOX) into the particle phase in CMAQ can have varying impact on fine particulate matter (PM2.5) organic mass, in terms of bias and error compared to field data collected during the 2013 SOAS. This highlights the need to better constrain the parameters that govern phase state and morphology of SOA, as well as expand mechanistic representation of multiphase chemistry for non-IEPOX SOA formation in models aided by novel experimental insights.},
doi = {10.5194/acp-20-8201-2020},
journal = {Atmospheric Chemistry and Physics (Online)},
number = 13,
volume = 20,
place = {United States},
year = {Thu Jul 16 00:00:00 EDT 2020},
month = {Thu Jul 16 00:00:00 EDT 2020}
}
Free Publicly Available Full Text
Publisher's Version of Record
Other availability
Search WorldCat to find libraries that may hold this journal
Cited by: 28 works
Citation information provided by
Web of Science
Web of Science
Save to My Library
You must Sign In or Create an Account in order to save documents to your library.
Works referenced in this record:
Evidence for a kinetically controlled burying mechanism for growth of high viscosity secondary organic aerosol
journal, January 2020
- Vander Wall, Allison C.; Perraud, Véronique; Wingen, Lisa M.
- Environmental Science: Processes & Impacts, Vol. 22, Issue 1
Anthropogenic influences on the physical state of submicron particulate matter over a tropical forest
journal, January 2017
- Bateman, Adam P.; Gong, Zhaoheng; Harder, Tristan H.
- Atmospheric Chemistry and Physics, Vol. 17, Issue 3
Bouncier Particles at Night: Biogenic Secondary Organic Aerosol Chemistry and Sulfate Drive Diel Variations in the Aerosol Phase in a Mixed Forest
journal, April 2019
- Slade, Jonathan H.; Ault, Andrew P.; Bui, Alexander T.
- Environmental Science & Technology, Vol. 53, Issue 9
Effect of varying experimental conditions on the viscosity of α -pinene derived secondary organic material
journal, January 2016
- Grayson, James W.; Zhang, Yue; Mutzel, Anke
- Atmospheric Chemistry and Physics, Vol. 16, Issue 10
Effect of Acidity on Secondary Organic Aerosol Formation from Isoprene
journal, August 2007
- Surratt, Jason D.; Lewandowski, Michael; Offenberg, John H.
- Environmental Science & Technology, Vol. 41, Issue 15
Simulating Aqueous-Phase Isoprene-Epoxydiol (IEPOX) Secondary Organic Aerosol Production During the 2013 Southern Oxidant and Aerosol Study (SOAS)
journal, April 2017
- Budisulistiorini, Sri Hapsari; Nenes, Athanasios; Carlton, Annmarie G.
- Environmental Science & Technology, Vol. 51, Issue 9
Seasonal characterization of submicron aerosol chemical composition and organic aerosol sources in the southeastern United States: Atlanta, Georgia,and Look Rock, Tennessee
journal, January 2016
- Budisulistiorini, Sri Hapsari; Baumann, Karsten; Edgerton, Eric S.
- Atmospheric Chemistry and Physics, Vol. 16, Issue 8
Formation of Low Volatility Organic Compounds and Secondary Organic Aerosol from Isoprene Hydroxyhydroperoxide Low-NO Oxidation
journal, July 2015
- Krechmer, Jordan E.; Coggon, Matthew M.; Massoli, Paola
- Environmental Science & Technology, Vol. 49, Issue 17
Evaluation of improved land use and canopy representation in BEIS v3.61 with biogenic VOC measurements in California
journal, January 2016
- Bash, Jesse O.; Baker, Kirk R.; Beaver, Melinda R.
- Geoscientific Model Development, Vol. 9, Issue 6
Amorphous phase state diagrams and viscosity of ternary aqueous organic/organic and inorganic/organic mixtures
journal, January 2018
- Marsh, Aleksandra; Petters, Sarah Suda; Rothfuss, Nicholas Ernest
- Physical Chemistry Chemical Physics, Vol. 20, Issue 22
Large contribution of natural aerosols to uncertainty in indirect forcing
journal, November 2013
- Carslaw, K. S.; Lee, L. A.; Reddington, C. L.
- Nature, Vol. 503, Issue 7474
Ideal copolymers and the second-order transitions of synthetic rubbers. i. non-crystalline copolymers
journal, September 1952
- Gordon, Manfred; Taylor, James S.
- Journal of Applied Chemistry, Vol. 2, Issue 9
Associations of particulate matter and its components with emergency room visits for cardiovascular and respiratory diseases
journal, August 2017
- Hwang, Sung-Hee; Lee, Jae Young; Yi, Seung-Muk
- PLOS ONE, Vol. 12, Issue 8
Relative humidity-dependent viscosity of secondary organic material from
toluene photo-oxidation and possible implications for organic particulate
matter over megacities
journal, January 2016
- Song, Mijung; Liu, Pengfei F.; Hanna, Sarah J.
- Atmospheric Chemistry and Physics, Vol. 16, Issue 14
Description and evaluation of the Community Multiscale Air Quality (CMAQ) modeling system version 5.1
journal, January 2017
- Appel, K. Wyat; Napelenok, Sergey L.; Foley, Kristen M.
- Geoscientific Model Development, Vol. 10, Issue 4
The viscosity of atmospherically relevant organic particles
journal, March 2018
- Reid, Jonathan P.; Bertram, Allan K.; Topping, David O.
- Nature Communications, Vol. 9, Issue 1
A simple lightning assimilation technique for improving retrospective WRF simulations
journal, November 2016
- Heath, Nicholas K.; Pleim, Jonathan C.; Gilliam, Robert
- Journal of Advances in Modeling Earth Systems
Relative importance of organic coatings for the heterogeneous hydrolysis of N 2 O 5 during summer in Europe
journal, January 2009
- Riemer, N.; Vogel, H.; Vogel, B.
- Journal of Geophysical Research, Vol. 114, Issue D17
Mixing of the Organic Aerosol Fractions: Liquids as the Thermodynamically Stable Phases
journal, March 2004
- Marcolli, Claudia; Luo, Beiping; Peter, Thomas
- The Journal of Physical Chemistry A, Vol. 108, Issue 12
The Effect of Fine and Coarse Particulate Air Pollution on Mortality: A National Analysis
journal, June 2009
- Zanobetti, Antonella; Schwartz, Joel
- Environmental Health Perspectives, Vol. 117, Issue 6
Phase separation in organic aerosol
journal, January 2017
- Freedman, Miriam Arak
- Chemical Society Reviews, Vol. 46, Issue 24
Increasing Isoprene Epoxydiol-to-Inorganic Sulfate Aerosol Ratio Results in Extensive Conversion of Inorganic Sulfate to Organosulfur Forms: Implications for Aerosol Physicochemical Properties
journal, June 2019
- Riva, Matthieu; Chen, Yuzhi; Zhang, Yue
- Environmental Science & Technology, Vol. 53, Issue 15
Predicting the relative humidities of liquid-liquid phase separation, efflorescence, and deliquescence of mixed particles of ammonium sulfate, organic material, and water using the organic-to-sulfate mass ratio of the particle and the oxygen-to-carbon elemental ratio of the organic component
journal, January 2011
- Bertram, A. K.; Martin, S. T.; Hanna, S. J.
- Atmospheric Chemistry and Physics, Vol. 11, Issue 21
Emulsified and Liquid–Liquid Phase-Separated States of α-Pinene Secondary Organic Aerosol Determined Using Aerosol Optical Tweezers
journal, October 2017
- Gorkowski, Kyle; Donahue, Neil M.; Sullivan, Ryan C.
- Environmental Science & Technology, Vol. 51, Issue 21
Epoxide Pathways Improve Model Predictions of Isoprene Markers and Reveal Key Role of Acidity in Aerosol Formation
journal, September 2013
- Pye, Havala O. T.; Pinder, Robert W.; Piletic, Ivan R.
- Environmental Science & Technology, Vol. 47, Issue 19
Observations and implications of liquid–liquid phase separation at high
relative humidities in secondary organic material produced by α -pinene ozonolysis without inorganic salts
journal, January 2016
- Renbaum-Wolff, Lindsay; Song, Mijung; Marcolli, Claudia
- Atmospheric Chemistry and Physics, Vol. 16, Issue 12
The effect of hydroxyl functional groups and molar mass on the viscosity of non-crystalline organic and organic–water particles
journal, January 2017
- Grayson, James W.; Evoy, Erin; Song, Mijung
- Atmospheric Chemistry and Physics, Vol. 17, Issue 13
Estimating the Viscosity Range of SOA Particles Based on Their Coalescence Time
journal, December 2013
- Pajunoja, Aki; Malila, Jussi; Hao, Liqing
- Aerosol Science and Technology, Vol. 48, Issue 2
Semivolatile POA and parameterized total combustion SOA in CMAQv5.2: impacts on source strength and partitioning
journal, January 2017
- Murphy, Benjamin N.; Woody, Matthew C.; Jimenez, Jose L.
- Atmospheric Chemistry and Physics, Vol. 17, Issue 18
Predicting the glass transition temperature and viscosity of secondary organic material using molecular composition
journal, January 2018
- DeRieux, Wing-Sy Wong; Li, Ying; Lin, Peng
- Atmospheric Chemistry and Physics, Vol. 18, Issue 9
A thermodynamic model of mixed organic-inorganic aerosols to predict activity coefficients
journal, January 2008
- Zuend, A.; Marcolli, C.; Luo, B. P.
- Atmospheric Chemistry and Physics, Vol. 8, Issue 16
Phase Transitions of Aqueous Atmospheric Particles
journal, September 2000
- Martin, Scot T.
- Chemical Reviews, Vol. 100, Issue 9
Molecular Composition and Volatility of Organic Aerosol in the Southeastern U.S.: Implications for IEPOX Derived SOA
journal, February 2016
- Lopez-Hilfiker, F. D.; Mohr, C.; D’Ambro, E. L.
- Environmental Science & Technology, Vol. 50, Issue 5
Images reveal that atmospheric particles can undergo liquid-liquid phase separations
journal, July 2012
- You, Y.; Renbaum-Wolff, L.; Carreras-Sospedra, M.
- Proceedings of the National Academy of Sciences, Vol. 109, Issue 33
The Molecular Identification of Organic Compounds in the Atmosphere: State of the Art and Challenges
journal, February 2015
- Nozière, Barbara; Kalberer, Markus; Claeys, Magda
- Chemical Reviews, Vol. 115, Issue 10
Gas Phase Production and Loss of Isoprene Epoxydiols
journal, February 2014
- Bates, Kelvin H.; Crounse, John D.; St. Clair, Jason M.
- The Journal of Physical Chemistry A, Vol. 118, Issue 7
Glass transition and phase state of organic compounds: dependency on molecular properties and implications for secondary organic aerosols in the atmosphere
journal, January 2011
- Koop, Thomas; Bookhold, Johannes; Shiraiwa, Manabu
- Physical Chemistry Chemical Physics, Vol. 13, Issue 43
Effective radiative forcing in the aerosol–climate model CAM5.3-MARC-ARG
journal, January 2018
- Grandey, Benjamin S.; Rothenberg, Daniel; Avramov, Alexander
- Atmospheric Chemistry and Physics, Vol. 18, Issue 21
Viscosities, diffusion coefficients, and mixing times of intrinsic fluorescent organic molecules in brown limonene secondary organic aerosol and tests of the Stokes–Einstein equation
journal, January 2019
- Ullmann, Dagny A.; Hinks, Mallory L.; Maclean, Adrian M.
- Atmospheric Chemistry and Physics, Vol. 19, Issue 3
Coupling of organic and inorganic aerosol systems and the effect on gas–particle partitioning in the southeastern US
journal, January 2018
- Pye, Havala O. T.; Zuend, Andreas; Fry, Juliane L.
- Atmospheric Chemistry and Physics, Vol. 18, Issue 1
Ubiquity and dominance of oxygenated species in organic aerosols in anthropogenically-influenced Northern Hemisphere midlatitudes: UBIQUITY AND DOMINANCE OF OXYGENATED OA
journal, July 2007
- Zhang, Q.; Jimenez, J. L.; Canagaratna, M. R.
- Geophysical Research Letters, Vol. 34, Issue 13
Sub-micrometre particulate matter is primarily in liquid form over Amazon rainforest
journal, December 2015
- Bateman, Adam P.; Gong, Zhaoheng; Liu, Pengfei
- Nature Geoscience, Vol. 9, Issue 1
Reactive intermediates revealed in secondary organic aerosol formation from isoprene
journal, December 2009
- Surratt, J. D.; Chan, A. W. H.; Eddingsaas, N. C.
- Proceedings of the National Academy of Sciences, Vol. 107, Issue 15
Photochemical Modeling of the Ozark Isoprene Volcano: MEGAN, BEIS, and Their Impacts on Air Quality Predictions
journal, May 2011
- Carlton, Annmarie G.; Baker, Kirk R.
- Environmental Science & Technology, Vol. 45, Issue 10
On the implications of aerosol liquid water and phase separation for organic aerosol mass
journal, January 2017
- Pye, Havala O. T.; Murphy, Benjamin N.; Xu, Lu
- Atmospheric Chemistry and Physics, Vol. 17, Issue 1
Liquid–liquid phase separation in organic particles containing one and two organic species: importance of the average O : C
journal, January 2018
- Song, Mijung; Ham, Suhan; Andrews, Ryan J.
- Atmospheric Chemistry and Physics, Vol. 18, Issue 16
Water diffusion in atmospherically relevant α-pinene secondary organic material
journal, January 2015
- Price, Hannah C.; Mattsson, Johan; Zhang, Yue
- Chemical Science, Vol. 6, Issue 8
Experimental and model estimates of the contributions from biogenic monoterpenes and sesquiterpenes to secondary organic aerosol in the southeastern United States
journal, January 2018
- Xu, Lu; Pye, Havala O. T.; He, Jia
- Atmospheric Chemistry and Physics, Vol. 18, Issue 17
Liquid–liquid phase separation in atmospherically relevant particles consisting of organic species and inorganic salts
journal, January 2014
- You, Yuan; Smith, Mackenzie L.; Song, Mijung
- International Reviews in Physical Chemistry, Vol. 33, Issue 1
Relative humidity-dependent viscosities of isoprene-derived secondary organic material and atmospheric implications for isoprene-dominant forests
journal, January 2015
- Song, M.; Liu, P. F.; Hanna, S. J.
- Atmospheric Chemistry and Physics, Vol. 15, Issue 9
On the relationship between aerosol model uncertainty and radiative forcing uncertainty
journal, February 2016
- Lee, Lindsay A.; Reddington, Carly L.; Carslaw, Kenneth S.
- Proceedings of the National Academy of Sciences, Vol. 113, Issue 21
Spatial/Temporal Variations and Source Apportionment of VOCs Monitored at Community Scale in an Urban Area
journal, April 2014
- Yu, Chang Ho; Zhu, Xianlei; Fan, Zhi-hua
- PLoS ONE, Vol. 9, Issue 4
Analysis of Recent Measurements of the Viscosity of Glasses
journal, June 1925
- Fulcher, Gordon S.
- Journal of the American Ceramic Society, Vol. 8, Issue 6
Mixing times of organic molecules within secondary organic aerosol particles: a global planetary boundary layer perspective
journal, January 2017
- Maclean, Adrian M.; Butenhoff, Christopher L.; Grayson, James W.
- Atmospheric Chemistry and Physics, Vol. 17, Issue 21
Effect of relative humidity on SOA formation from isoprene/NO photooxidation: enhancement of 2-methylglyceric acid and its corresponding oligoesters under dry conditions
journal, January 2011
- Zhang, H.; Surratt, J. D.; Lin, Y. H.
- Atmospheric Chemistry and Physics, Vol. 11, Issue 13
Changing shapes and implied viscosities of suspended submicron particles
journal, January 2015
- Zhang, Y.; Sanchez, M. S.; Douet, C.
- Atmospheric Chemistry and Physics, Vol. 15, Issue 14
Hygroscopic Influence on the Semisolid-to-Liquid Transition of Secondary Organic Materials
journal, November 2014
- Bateman, Adam P.; Bertram, Allan K.; Martin, Scot T.
- The Journal of Physical Chemistry A, Vol. 119, Issue 19
α-Pinene-Derived organic coatings on acidic sulfate aerosol impacts secondary organic aerosol formation from isoprene in a box model
journal, September 2019
- Schmedding, Ryan; Ma, Mutian; Zhang, Yue
- Atmospheric Environment, Vol. 213
Constraining condensed-phase formation kinetics of secondary organic aerosol components from isoprene epoxydiols
journal, January 2016
- Riedel, T. P.; Lin, Y. -H.; Zhang, Z.
- Atmospheric Chemistry and Physics, Vol. 16, Issue 3
Modeling the gas-particle partitioning of secondary organic aerosol: the importance of liquid-liquid phase separation
journal, January 2012
- Zuend, A.; Seinfeld, J. H.
- Atmospheric Chemistry and Physics, Vol. 12, Issue 9
Apportionment of Primary and Secondary Organic Aerosols in Southern California during the 2005 Study of Organic Aerosols in Riverside (SOAR-1)
journal, October 2008
- Docherty, Kenneth S.; Stone, Elizabeth A.; Ulbrich, Ingrid M.
- Environmental Science & Technology, Vol. 42, Issue 20
Reactive Uptake of an Isoprene-Derived Epoxydiol to Submicron Aerosol Particles
journal, September 2014
- Gaston, Cassandra J.; Riedel, Theran P.; Zhang, Zhenfa
- Environmental Science & Technology, Vol. 48, Issue 19
Liquid–liquid phase separation in secondary organic aerosol particles produced from α -pinene ozonolysis and α -pinene photooxidation with/without ammonia
journal, January 2019
- Ham, Suhan; Babar, Zaeem Bin; Lee, Jae Bong
- Atmospheric Chemistry and Physics, Vol. 19, Issue 14
Airborne measurements of organosulfates over the continental U.S.: organosulfates over the continental US
journal, April 2015
- Liao, Jin; Froyd, Karl D.; Murphy, Daniel M.
- Journal of Geophysical Research: Atmospheres, Vol. 120, Issue 7
An amorphous solid state of biogenic secondary organic aerosol particles
journal, October 2010
- Virtanen, Annele; Joutsensaari, Jorma; Koop, Thomas
- Nature, Vol. 467, Issue 7317
Effect of the Aerosol-Phase State on Secondary Organic Aerosol Formation from the Reactive Uptake of Isoprene-Derived Epoxydiols (IEPOX)
journal, February 2018
- Zhang, Yue; Chen, Yuzhi; Lambe, Andrew T.
- Environmental Science & Technology Letters, Vol. 5, Issue 3
Viscous organic aerosol particles in the upper troposphere: diffusivity-controlled water uptake and ice nucleation?
journal, January 2015
- Lienhard, D. M.; Huisman, A. J.; Krieger, U. K.
- Atmospheric Chemistry and Physics, Vol. 15, Issue 23
Chemical Composition of Secondary Organic Aerosol Formed from the Photooxidation of Isoprene
journal, August 2006
- Surratt, Jason D.; Murphy, Shane M.; Kroll, Jesse H.
- The Journal of Physical Chemistry A, Vol. 110, Issue 31
Kinetics of the reactions of isoprene-derived hydroxynitrates: gas phase epoxide formation and solution phase hydrolysis
journal, January 2014
- Jacobs, M. I.; Burke, W. J.; Elrod, M. J.
- Atmospheric Chemistry and Physics, Vol. 14, Issue 17
Highly functionalized organic nitrates in the southeast United States: Contribution to secondary organic aerosol and reactive nitrogen budgets
journal, January 2016
- Lee, Ben H.; Mohr, Claudia; Lopez-Hilfiker, Felipe D.
- Proceedings of the National Academy of Sciences, Vol. 113, Issue 6
α -Pinene secondary organic aerosol at low temperature: chemical composition and implications for particle viscosity
journal, January 2018
- Huang, Wei; Saathoff, Harald; Pajunoja, Aki
- Atmospheric Chemistry and Physics, Vol. 18, Issue 4
Predictions of diffusion rates of large organic molecules in secondary organic aerosols using the Stokes–Einstein and fractional Stokes–Einstein relations
journal, January 2019
- Evoy, Erin; Maclean, Adrian M.; Rovelli, Grazia
- Atmospheric Chemistry and Physics, Vol. 19, Issue 15
Aerosol characterization over the southeastern United States using high-resolution aerosol mass spectrometry: spatial and seasonal variation of aerosol composition and sources with a focus on organic nitrates
journal, January 2015
- Xu, L.; Suresh, S.; Guo, H.
- Atmospheric Chemistry and Physics, Vol. 15, Issue 13
Monoterpenes are the largest source of summertime organic aerosol in the southeastern United States
journal, February 2018
- Zhang, Haofei; Yee, Lindsay D.; Lee, Ben H.
- Proceedings of the National Academy of Sciences, Vol. 115, Issue 9
On the Reactive Uptake of Gaseous Compounds by Organic-Coated Aqueous Aerosols: Theoretical Analysis and Application to the Heterogeneous Hydrolysis of N 2 O 5
journal, September 2006
- Anttila, Tatu; Kiendler-Scharr, Astrid; Tillmann, Ralf
- The Journal of Physical Chemistry A, Vol. 110, Issue 35
Die Abhängigkeit der Viscosität von der Temperatur bie unterkühlten Flüssigkeiten
journal, October 1926
- Tammann, G.; Hesse, W.
- Zeitschrift für anorganische und allgemeine Chemie, Vol. 156, Issue 1
The Climatic Importance of Uncertainties in Regional Aerosol–Cloud Radiative Forcings over Recent Decades
journal, September 2015
- Regayre, Leighton A.; Pringle, Kirsty J.; Lee, Lindsay A.
- Journal of Climate, Vol. 28, Issue 17
Liquid–Liquid Phase Separation in Aerosol Particles: Imaging at the Nanometer Scale
journal, April 2015
- O’Brien, Rachel E.; Wang, Bingbing; Kelly, Stephen T.
- Environmental Science & Technology, Vol. 49, Issue 8
Particle-Phase Diffusion Modulates Partitioning of Semivolatile Organic Compounds to Aged Secondary Organic Aerosol
journal, January 2020
- Zaveri, Rahul A.; Shilling, John E.; Zelenyuk, Alla
- Environmental Science & Technology, Vol. 54, Issue 5
Aerosol Phase State and Its Link to Chemical Composition and Liquid Water Content in a Subtropical Coastal Megacity
journal, April 2019
- Liu, Yuechen; Wu, Zhijun; Huang, Xiaofeng
- Environmental Science & Technology, Vol. 53, Issue 9
Aqueous-phase mechanism for secondary organic aerosol formation from isoprene: application to the southeast United States and co-benefit of SO 2 emission controls
journal, January 2016
- Marais, E. A.; Jacob, D. J.; Jimenez, J. L.
- Atmospheric Chemistry and Physics, Vol. 16, Issue 3
Development of a hydrophilic interaction liquid chromatography (HILIC) method for the chemical characterization of water-soluble isoprene epoxydiol (IEPOX)-derived secondary organic aerosol
journal, January 2018
- Cui, Tianqu; Zeng, Zhexi; dos Santos, Erickson O.
- Environmental Science: Processes & Impacts, Vol. 20, Issue 11
Joint Impacts of Acidity and Viscosity on the Formation of Secondary Organic Aerosol from Isoprene Epoxydiols (IEPOX) in Phase Separated Particles
journal, October 2019
- Zhang, Yue; Chen, Yuzhi; Lei, Ziying
- ACS Earth and Space Chemistry, Vol. 3, Issue 12
Ambient Measurements of Highly Oxidized Gas-Phase Molecules during the Southern Oxidant and Aerosol Study (SOAS) 2013
journal, May 2018
- Massoli, Paola; Stark, Harald; Canagaratna, Manjula R.
- ACS Earth and Space Chemistry, Vol. 2, Issue 7
The Southeastern Aerosol Research and Characterization Study: Part 1—Overview
journal, December 2003
- Hansen, D. Alan; Edgerton, Eric S.; Hartsell, Benjamin E.
- Journal of the Air & Waste Management Association, Vol. 53, Issue 12
Transition from high- to low-NOx control of night-time oxidation in the southeastern US
journal, June 2017
- Edwards, P. M.; Aikin, K. C.; Dube, W. P.
- Nature Geoscience, Vol. 10, Issue 7
On the Role of Particle Inorganic Mixing State in the Reactive Uptake of N 2 O 5 to Ambient Aerosol Particles
journal, January 2014
- Ryder, Olivia S.; Ault, Andrew P.; Cahill, John F.
- Environmental Science & Technology, Vol. 48, Issue 3
Fine-particle water and pH in the southeastern United States
journal, January 2015
- Guo, H.; Xu, L.; Bougiatioti, A.
- Atmospheric Chemistry and Physics, Vol. 15, Issue 9
Viscosity of -pinene secondary organic material and implications for particle growth and reactivity
journal, April 2013
- Renbaum-Wolff, L.; Grayson, J. W.; Bateman, A. P.
- Proceedings of the National Academy of Sciences, Vol. 110, Issue 20
Isoprene-Derived Organosulfates: Vibrational Mode Analysis by Raman Spectroscopy, Acidity-Dependent Spectral Modes, and Observation in Individual Atmospheric Particles
journal, December 2017
- Bondy, Amy L.; Craig, Rebecca L.; Zhang, Zhenfa
- The Journal of Physical Chemistry A, Vol. 122, Issue 1
Enhanced formation of isoprene-derived organic aerosol in sulfur-rich power plant plumes during Southeast Nexus: SULFATE AFFECTS ISOPRENE SOA FORMATION
journal, September 2016
- Xu, Lu; Middlebrook, Ann M.; Liao, Jin
- Journal of Geophysical Research: Atmospheres, Vol. 121, Issue 18
Estimates of global terrestrial isoprene emissions using MEGAN (Model of Emissions of Gases and Aerosols from Nature)
journal, January 2006
- Guenther, A.; Karl, T.; Harley, P.
- Atmospheric Chemistry and Physics, Vol. 6, Issue 11
Kinetics and Products of the Acid-Catalyzed Ring-Opening of Atmospherically Relevant Butyl Epoxy Alcohols
journal, August 2010
- Eddingsaas, Nathan C.; VanderVelde, David G.; Wennberg, Paul O.
- The Journal of Physical Chemistry A, Vol. 114, Issue 31
Unexpected Epoxide Formation in the Gas-Phase Photooxidation of Isoprene
journal, August 2009
- Paulot, F.; Crounse, J. D.; Kjaergaard, H. G.
- Science, Vol. 325, Issue 5941
The Molecular Identification of Organic Compounds in the Atmosphere: State of the Art and Challenges
journal, February 2015
- Nozière, Barbara; Kalberer, Markus; Claeys, Magda
- Chemical Reviews, Vol. 115, Issue 10
Chemical Composition of Secondary Organic Aerosol Formed from the Photooxidation of Isoprene
journal, August 2006
- Surratt, Jason D.; Murphy, Shane M.; Kroll, Jesse H.
- The Journal of Physical Chemistry A, Vol. 110, Issue 31
Kinetics and Products of the Acid-Catalyzed Ring-Opening of Atmospherically Relevant Butyl Epoxy Alcohols
journal, August 2010
- Eddingsaas, Nathan C.; VanderVelde, David G.; Wennberg, Paul O.
- The Journal of Physical Chemistry A, Vol. 114, Issue 31
Gas Phase Production and Loss of Isoprene Epoxydiols
journal, February 2014
- Bates, Kelvin H.; Crounse, John D.; St. Clair, Jason M.
- The Journal of Physical Chemistry A, Vol. 118, Issue 7
An amorphous solid state of biogenic secondary organic aerosol particles
journal, October 2010
- Virtanen, Annele; Joutsensaari, Jorma; Koop, Thomas
- Nature, Vol. 467, Issue 7317
Global distribution of particle phase state in atmospheric secondary organic aerosols
journal, April 2017
- Shiraiwa, Manabu; Li, Ying; Tsimpidi, Alexandra P.
- Nature Communications, Vol. 8, Issue 1
Images reveal that atmospheric particles can undergo liquid-liquid phase separations
journal, July 2012
- You, Y.; Renbaum-Wolff, L.; Carreras-Sospedra, M.
- Proceedings of the National Academy of Sciences, Vol. 109, Issue 33
Viscosity of -pinene secondary organic material and implications for particle growth and reactivity
journal, April 2013
- Renbaum-Wolff, L.; Grayson, J. W.; Bateman, A. P.
- Proceedings of the National Academy of Sciences, Vol. 110, Issue 20
On the relationship between aerosol model uncertainty and radiative forcing uncertainty
journal, February 2016
- Lee, Lindsay A.; Reddington, Carly L.; Carslaw, Kenneth S.
- Proceedings of the National Academy of Sciences, Vol. 113, Issue 21
Estimating the Viscosity Range of SOA Particles Based on Their Coalescence Time
journal, December 2013
- Pajunoja, Aki; Malila, Jussi; Hao, Liqing
- Aerosol Science and Technology, Vol. 48, Issue 2
Unexpected Epoxide Formation in the Gas-Phase Photooxidation of Isoprene
journal, August 2009
- Paulot, F.; Crounse, J. D.; Kjaergaard, H. G.
- Science, Vol. 325, Issue 5941
Diagnosis of venous disease and use of Doppler assessment
journal, April 2013
- Yarwood-Ross, Lee
- Independent Nurse, Vol. 2013, Issue 4
Are diffusion coefficients calculated using the Stokes-Einstein equation combined with viscosities consistent with measured diffusion coefficients of tracer organics within organics-water mediums?
text, January 2015
- Chenyakin, Yuri
- University of British Columbia
Effect of relative humidity on SOA formation from isoprene/NO photooxidation: enhancement of 2-methylglyceric acid and its corresponding oligoesters under dry conditions
text, January 2011
- J., Bapat,; D., Surratt, J.; M., Kamens, R.
- The University of North Carolina at Chapel Hill University Libraries
Effective radiative forcing in the aerosol-climate model CAM5.3-MARC-ARG
text, January 2018
- Grandey, Benjamin S.; Rothenberg, Daniel; Avramov, Alexander
- arXiv
Experimental and model estimates of the contributions from biogenic monoterpenes and sesquiterpenes to secondary organic aerosol in the southeastern United States
journal, January 2018
- Xu, Lu; Pye, Havala O. T.; He, Jia
- Atmospheric Chemistry and Physics, Vol. 18, Issue 17
Coupling of organic and inorganic aerosol systems and the effect on gas–particle partitioning in the southeastern US
journal, January 2018
- Pye, Havala O. T.; Zuend, Andreas; Fry, Juliane L.
- Atmospheric Chemistry and Physics, Vol. 18, Issue 1
Predictions of diffusion rates of large organic molecules in secondary organic aerosols using the Stokes–Einstein and fractional Stokes–Einstein relations
journal, January 2019
- Evoy, Erin; Maclean, Adrian M.; Rovelli, Grazia
- Atmospheric Chemistry and Physics, Vol. 19, Issue 15
Viscosities, diffusion coefficients, and mixing times of intrinsic fluorescent organic molecules in brown limonene secondary organic aerosol and tests of the Stokes–Einstein equation
journal, January 2019
- Ullmann, Dagny A.; Hinks, Mallory L.; Maclean, Adrian M.
- Atmospheric Chemistry and Physics, Vol. 19, Issue 3
Estimates of global terrestrial isoprene emissions using MEGAN (Model of Emissions of Gases and Aerosols from Nature)
journal, January 2006
- Guenther, A.; Karl, T.; Harley, P.
- Atmospheric Chemistry and Physics, Vol. 6, Issue 11
Description and evaluation of the Community Multiscale Air Quality (CMAQ) modeling system version 5.1
journal, January 2017
- Appel, K. Wyat; Napelenok, Sergey L.; Foley, Kristen M.
- Geoscientific Model Development, Vol. 10, Issue 4