High-pressure synthesis, crystal structure, and magnetic properties of the Shastry-Sutherland-lattice oxides BaLn2ZnO5 (Ln = Pr, Sm, Eu)
Abstract
BaPr2ZnO5, BaSm2ZnO5, and BaEu2ZnO5 – a series of 4f magnetic insulators comprising the Shastry-Sutherland lattice – were synthesized via a solid-state reaction under high-pressure and high-temperature conditions. The magnetic behaviors are well characterized by the localized 4f electrons of each Ln3+ (= Pr, Sm, Eu) under the influence of the crystal-electric field of the surrounding ions. The magnetic susceptibility and heat capacity measurements of BaPr2ZnO5 (Pr3+; 4f2 3H4) indicate the splitting of the ground state J-multiplet due to the crystal-electric field. BaSm2ZnO5 (Sm3+; 4f5 6H5/2) is a strong Van Vleck paramagnet, while BaEu2ZnO5 is non-magnetic due to the 7F0 ground state (Eu3+; 4f6 7F0). The series of new oxides enriches a group of the Shastry-Sutherland lattice materials and helps to develop a range of two-dimensional quantum materials.
- Authors:
-
[3];
- Hokkaido Univ., Sapporo (Japan)
- National Institute for Materials Science, Tsukuba, Ibaraki (Japan). International Center for Materials Nanoarchitectonics (WPI-MANA); Hokkaido Univ., Sapporo (Japan)
- Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Materials Science & Technology Division
- Publication Date:
- Research Org.:
- Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES). Materials Sciences & Engineering Division; Japan Society for the Promotion of Science (JSPS)
- OSTI Identifier:
- 1649046
- Grant/Contract Number:
- AC05-00OR22725; JP19J14391
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Journal of Solid State Chemistry
- Additional Journal Information:
- Journal Volume: 289; Journal ID: ISSN 0022-4596
- Publisher:
- Elsevier
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 36 MATERIALS SCIENCE; BaPr2ZnO5; BaSm2ZnO5; BaEu2ZnO5; Shastry-sutherland lattice; High-pressure synthesis
Citation Formats
Ishii, Yuto, Chen, Jie, Yoshida, Hiroyuki K., Oda, Migaku, Christianson, Andrew D., and Yamaura, Kazunari. High-pressure synthesis, crystal structure, and magnetic properties of the Shastry-Sutherland-lattice oxides BaLn2ZnO5 (Ln = Pr, Sm, Eu). United States: N. p., 2020.
Web. doi:10.1016/j.jssc.2020.121489.
Ishii, Yuto, Chen, Jie, Yoshida, Hiroyuki K., Oda, Migaku, Christianson, Andrew D., & Yamaura, Kazunari. High-pressure synthesis, crystal structure, and magnetic properties of the Shastry-Sutherland-lattice oxides BaLn2ZnO5 (Ln = Pr, Sm, Eu). United States. https://doi.org/10.1016/j.jssc.2020.121489
Ishii, Yuto, Chen, Jie, Yoshida, Hiroyuki K., Oda, Migaku, Christianson, Andrew D., and Yamaura, Kazunari. Fri .
"High-pressure synthesis, crystal structure, and magnetic properties of the Shastry-Sutherland-lattice oxides BaLn2ZnO5 (Ln = Pr, Sm, Eu)". United States. https://doi.org/10.1016/j.jssc.2020.121489. https://www.osti.gov/servlets/purl/1649046.
@article{osti_1649046,
title = {High-pressure synthesis, crystal structure, and magnetic properties of the Shastry-Sutherland-lattice oxides BaLn2ZnO5 (Ln = Pr, Sm, Eu)},
author = {Ishii, Yuto and Chen, Jie and Yoshida, Hiroyuki K. and Oda, Migaku and Christianson, Andrew D. and Yamaura, Kazunari},
abstractNote = {BaPr2ZnO5, BaSm2ZnO5, and BaEu2ZnO5 – a series of 4f magnetic insulators comprising the Shastry-Sutherland lattice – were synthesized via a solid-state reaction under high-pressure and high-temperature conditions. The magnetic behaviors are well characterized by the localized 4f electrons of each Ln3+ (= Pr, Sm, Eu) under the influence of the crystal-electric field of the surrounding ions. The magnetic susceptibility and heat capacity measurements of BaPr2ZnO5 (Pr3+; 4f2 3H4) indicate the splitting of the ground state J-multiplet due to the crystal-electric field. BaSm2ZnO5 (Sm3+; 4f5 6H5/2) is a strong Van Vleck paramagnet, while BaEu2ZnO5 is non-magnetic due to the 7F0 ground state (Eu3+; 4f6 7F0). The series of new oxides enriches a group of the Shastry-Sutherland lattice materials and helps to develop a range of two-dimensional quantum materials.},
doi = {10.1016/j.jssc.2020.121489},
journal = {Journal of Solid State Chemistry},
number = ,
volume = 289,
place = {United States},
year = {Fri Jun 05 00:00:00 EDT 2020},
month = {Fri Jun 05 00:00:00 EDT 2020}
}
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Works referenced in this record:
Exact ground state of a quantum mechanical antiferromagnet
journal, August 1981
- Sriram Shastry, B.; Sutherland, Bill
- Physica B+C, Vol. 108, Issue 1-3
Crossbreeding between Experiment and Theory on Orthogonal Dimer Spin System
journal, January 2002
- Kageyama, Hiroshi; Ueda, Yutaka; Narumi, Yasuo
- Progress of Theoretical Physics Supplement, Vol. 145
Exact Dimer Ground State and Quantized Magnetization Plateaus in the Two-Dimensional Spin System
journal, April 1999
- Kageyama, H.; Yoshimura, K.; Stern, R.
- Physical Review Letters, Vol. 82, Issue 15
Magnetization of in Ultrahigh Magnetic Fields up to 118 T
journal, September 2013
- Matsuda, Y. H.; Abe, N.; Takeyama, S.
- Physical Review Letters, Vol. 111, Issue 13
Crystallization of spin superlattices with pressure and field in the layered magnet SrCu2(BO3)2
journal, June 2016
- Haravifard, S.; Graf, D.; Feiguin, A. E.
- Nature Communications, Vol. 7, Issue 1
Note on the Interactions between the Spins of Magnetic Ions or Nuclei in Metals
journal, October 1962
- Van Vleck, J. H.
- Reviews of Modern Physics, Vol. 34, Issue 4
Magnetisation process in the rare earth tetraborides, NdB4 and HoB4
journal, January 2018
- Brunt, D.; Balakrishnan, G.; Mayoh, D. A.
- Scientific Reports, Vol. 8, Issue 1
Electronic transport on the Shastry-Sutherland lattice in Ising-type rare-earth tetraborides
journal, May 2017
- Ye, Linda; Suzuki, Takehito; Checkelsky, Joseph G.
- Physical Review B, Vol. 95, Issue 17
Phase diagram of the Shastry-Sutherland antiferromagnet
journal, November 2001
- Zheng, Weihong; Oitmaa, J.; Hamer, C. J.
- Physical Review B, Vol. 65, Issue 1
Phase diagram of the quadrumerized Shastry-Sutherland model
journal, June 2002
- Läuchli, Andreas; Wessel, Stefan; Sigrist, Manfred
- Physical Review B, Vol. 66, Issue 1
Phase transitions in the Shastry-Sutherland lattice
journal, September 2005
- Al Hajj, Mohamad; Malrieu, Jean-Paul
- Physical Review B, Vol. 72, Issue 9
Coupled cluster treatment of the Shastry-Sutherland antiferromagnet
journal, September 2005
- Darradi, R.; Richter, J.; Farnell, D. J. J.
- Physical Review B, Vol. 72, Issue 10
Variational treatment of the Shastry-Sutherland antiferromagnet using projected entangled pair states
journal, August 2006
- Isacsson, A.; Syljuåsen, Olav F.
- Physical Review E, Vol. 74, Issue 2
Plaquette ground state of the Shastry-Sutherland model: Density-matrix renormalization-group calculations
journal, October 2008
- Moukouri, S.
- Physical Review B, Vol. 78, Issue 13
Tensor network study of the Shastry-Sutherland model in zero magnetic field
journal, March 2013
- Corboz, Philippe; Mila, Frédéric
- Physical Review B, Vol. 87, Issue 11
Identifying topological order in the Shastry-Sutherland model via entanglement entropy
journal, November 2014
- Ronquillo, David C.; Peterson, Michael R.
- Physical Review B, Vol. 90, Issue 20
Magnetization and specific heat measurement of the Shastry–Sutherland lattice compounds: Ln2BaPdO5 (Ln=La, Pr, Nd, Sm, Eu, Gd, Dy, Ho)
journal, January 2008
- Ozawa, T. C.; Taniguchi, T.; Kawaji, Y.
- Journal of Alloys and Compounds, Vol. 448, Issue 1-2
Ln2BaZnO5 and Ln2BaZn1−xCuxO5: A series of zinc oxides with zinc in a pyramidal coordination
journal, September 1983
- Michel, C.; Raveau, B.
- Journal of Solid State Chemistry, Vol. 49, Issue 2
Crystal structures and reference powder patterns of BaR2ZnO5 (R = La, Nd, Sm, Eu, Gd, Dy, Ho, Y, Er, and Tm)
journal, March 1999
- Kaduk, J. A.; Wong-Ng, W.; Greenwood, G.
- Journal of Research of the National Institute of Standards and Technology, Vol. 104, Issue 2
Crystal structure and electrical conductivity of BaR2ZnO5 (R = Sm, Gd, Dy, Ho, and Er)—a new structure family of oxide-ion conductors
journal, January 2018
- Nakamura, Keigo; Fujii, Kotaro; Niwa, Eiki
- Journal of the Ceramic Society of Japan, Vol. 126, Issue 5
A new large radius imaging plate camera for high-resolution and high-throughput synchrotron x-ray powder diffraction by multiexposure method
journal, July 2008
- Tanaka, Masahiko; Katsuya, Yoshio; Yamamoto, Akiji
- Review of Scientific Instruments, Vol. 79, Issue 7
Development of a synchrotron powder diffractometer with a one-dimensional X-ray detector for analysis of advanced materials
journal, January 2013
- Tanaka, Masahiko; Katsuya, Yoshio; Matsushita, Yoshitaka
- Journal of the Ceramic Society of Japan, Vol. 121, Issue 1411
Three-Dimensional Visualization in Powder Diffraction
journal, December 2007
- Izumi, Fujio; Momma, Koichi
- Solid State Phenomena, Vol. 130
VESTA 3 for three-dimensional visualization of crystal, volumetric and morphology data
journal, October 2011
- Momma, Koichi; Izumi, Fujio
- Journal of Applied Crystallography, Vol. 44, Issue 6
Structure cristalline de l'oxyde Nd2BaZnO5
journal, June 1990
- Taibi, M.; Aride, J.; Darriet, J.
- Journal of Solid State Chemistry, Vol. 86, Issue 2
Magnetic properties of Pnma - oxides (R = Sm, Eu, Dy and Ho)
journal, October 1996
- Goya, G. F.; Mercader, R. C.; Causa, M. T.
- Journal of Physics: Condensed Matter, Vol. 8, Issue 44
Synthesis, structure, and properties of the orthoborate SrCu2(BO3)2
journal, August 1991
- Smith, Robert W.; Keszler, Douglas A.
- Journal of Solid State Chemistry, Vol. 93, Issue 2
Treating crystal field parameters in lower than cubic symmetries
journal, January 1984
- Walter, U.
- Journal of Physics and Chemistry of Solids, Vol. 45, Issue 4
Structure and luminescence of some rare earth halotungstates of the type Ln3WO6Cl3
journal, August 1982
- Brixner, L. H.; Chen, H. Y.; Foris, C. M.
- Journal of Solid State Chemistry, Vol. 44, Issue 1
Synthesis and characterization of the wide band-gap compound Pr2Te4O11
journal, May 2003
- Ijjaali, Ismail; Flaschenriem, Christine; Ibers, James A.
- Journal of Alloys and Compounds, Vol. 354, Issue 1-2
Crystal-Field Effect on the Magnetic Susceptibility of Rare-Earth (Pr, Nd, Eu) Mixed Oxides
journal, January 1995
- Cascales, C.; Sáez-Puche, R.; Porcher, P.
- Journal of Solid State Chemistry, Vol. 114, Issue 1
Schottky contribution to the heat capacity of monazite type (La, Pr)PO4 from low temperature calorimetry and fluorescence measurements
journal, June 2016
- Bauer, J. D.; Hirsch, A.; Bayarjargal, L.
- Chemical Physics Letters, Vol. 654
Synthesis, crystal structure, and magnetic properties of novel 2D kagome materials RE 3 Sb 3 Mg 2 O 14 (RE = La, Pr, Sm, Eu, Tb, Ho): Comparison to RE 3 Sb 3 Zn 2 O 14 family : Properties of novel 2D kagome materials RE
journal, August 2016
- Sanders, M. B.; Baroudi, K. M.; Krizan, J. W.
- physica status solidi (b), Vol. 253, Issue 10
Magnetism in the KBaRE(BO 3 ) 2 (RE = Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu) series: materials with a triangular rare earth lattice
journal, March 2017
- Sanders, M. B.; Cevallos, F. A.; Cava, R. J.
- Materials Research Express, Vol. 4, Issue 3
Manifestation of geometric frustration on magnetic and thermodynamic properties of the pyrochlores
journal, February 2008
- Singh, Surjeet; Saha, Surajit; Dhar, S. K.
- Physical Review B, Vol. 77, Issue 5
Paramagnetic Anisotropy and Crystal-Field Splittings in EuAl
journal, February 1969
- Holmes, L.; Sherwood, R.; Van Uitert, L. G.
- Physical Review, Vol. 178, Issue 2
: An anisotropic Van Vleck paramagnet
journal, February 1989
- Tovar, M.; Rao, D.; Barnett, J.
- Physical Review B, Vol. 39, Issue 4