Realizing Complete Solid-Solution Reaction in High Sodium Content P2-Type Cathode for High-Performance Sodium-Ion Batteries
Abstract
P2-type layered oxides suffer from an ordered Na+/vacancy arrangement and P2→O2/OP4 phase transitions, leading them to exhibit multiple voltage plateaus upon Na+ extraction/insertion. The deficient sodium in the P2-type cathode easily induces the bad structural stability at deep desodiation states and limited reversible capacity during Na+ de/insertion. These drawbacks cause poor rate capability and fast capacity decay in most P2-type layered oxides. In this work, to address these challenges, a novel high sodium content (0.85) and plateau-free P2-type cathode-Na0.85Li0.12Ni0.22Mn0.66O2 (P2-NLNMO) was developed. The complete solid-solution reaction over a wide voltage range ensures both fast Na+ mobility (10-11 to 10-10cm2s-1) and small volume variation (1.7%). Furthermore, the high sodium content P2-NLNMO exhibits a higher reversible capacity of 123.4 mAhg-1, superior rate capability of 79.3 mAhg-1 at 20 C, and 85.4% capacity retention after 500 cycles at 5 C. The sufficient Na and complete solid-solution reaction are critical to realizing high-performance P2-type cathodes for sodium-ion batteries.
- Authors:
-
[2]
- Nankai Univ. Tianjin (China) Key Lab. of Advanced Energy Materials Chemistry (Ministry of Education), Renewable Energy Conversion and Storage Center (ReCast); Univ. of Maryland, College Park, MD (United States)
- Univ. of Maryland, College Park, MD (United States)
- Brookhaven National Lab. (BNL), Upton, NY (United States)
- Nankai Univ. Tianjin (China) Key Lab. of Advanced Energy Materials Chemistry (Ministry of Education), Renewable Energy Conversion and Storage Center (ReCast)
- Publication Date:
- Research Org.:
- Brookhaven National Lab. (BNL), Upton, NY (United States)
- Sponsoring Org.:
- USDOE Office of Energy Efficiency and Renewable Energy (EERE), Vehicle Technologies Office (EE-3V); 111 Project; National Natural Science Foundation of China (NSFC); Ministry of Science and Technology of China
- OSTI Identifier:
- 1644017
- Report Number(s):
- BNL-216215-2020-JAAM
Journal ID: ISSN 0044-8249
- Grant/Contract Number:
- SC0012704; 1622102; 21421001; 2183500; B12015; 2017YFA0206702; 2016YFB090152; 18ZXJMTG00040; 19JCZDJC31800
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Angewandte Chemie
- Additional Journal Information:
- Journal Volume: 132; Journal Issue: 34; Journal ID: ISSN 0044-8249
- Publisher:
- German Chemical Society
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 25 ENERGY STORAGE; lithium sulfur batteries; lean electrolyte; chemical bonding; carbon; oxygen
Citation Formats
Jin, Ting, Wang, Peng‐Fei, Wang, Qin‐Chao, Zhu, Kunjie, Deng, Tao, Zhang, Jiaxun, Zhang, Wei, Yang, Xiao‐Qing, Jiao, Lifang, and Wang, Chunsheng. Realizing Complete Solid-Solution Reaction in High Sodium Content P2-Type Cathode for High-Performance Sodium-Ion Batteries. United States: N. p., 2020.
Web. doi:10.1002/ange.202003972.
Jin, Ting, Wang, Peng‐Fei, Wang, Qin‐Chao, Zhu, Kunjie, Deng, Tao, Zhang, Jiaxun, Zhang, Wei, Yang, Xiao‐Qing, Jiao, Lifang, & Wang, Chunsheng. Realizing Complete Solid-Solution Reaction in High Sodium Content P2-Type Cathode for High-Performance Sodium-Ion Batteries. United States. https://doi.org/10.1002/ange.202003972
Jin, Ting, Wang, Peng‐Fei, Wang, Qin‐Chao, Zhu, Kunjie, Deng, Tao, Zhang, Jiaxun, Zhang, Wei, Yang, Xiao‐Qing, Jiao, Lifang, and Wang, Chunsheng. Fri .
"Realizing Complete Solid-Solution Reaction in High Sodium Content P2-Type Cathode for High-Performance Sodium-Ion Batteries". United States. https://doi.org/10.1002/ange.202003972. https://www.osti.gov/servlets/purl/1644017.
@article{osti_1644017,
title = {Realizing Complete Solid-Solution Reaction in High Sodium Content P2-Type Cathode for High-Performance Sodium-Ion Batteries},
author = {Jin, Ting and Wang, Peng‐Fei and Wang, Qin‐Chao and Zhu, Kunjie and Deng, Tao and Zhang, Jiaxun and Zhang, Wei and Yang, Xiao‐Qing and Jiao, Lifang and Wang, Chunsheng},
abstractNote = {P2-type layered oxides suffer from an ordered Na+/vacancy arrangement and P2→O2/OP4 phase transitions, leading them to exhibit multiple voltage plateaus upon Na+ extraction/insertion. The deficient sodium in the P2-type cathode easily induces the bad structural stability at deep desodiation states and limited reversible capacity during Na+ de/insertion. These drawbacks cause poor rate capability and fast capacity decay in most P2-type layered oxides. In this work, to address these challenges, a novel high sodium content (0.85) and plateau-free P2-type cathode-Na0.85Li0.12Ni0.22Mn0.66O2 (P2-NLNMO) was developed. The complete solid-solution reaction over a wide voltage range ensures both fast Na+ mobility (10-11 to 10-10cm2s-1) and small volume variation (1.7%). Furthermore, the high sodium content P2-NLNMO exhibits a higher reversible capacity of 123.4 mAhg-1, superior rate capability of 79.3 mAhg-1 at 20 C, and 85.4% capacity retention after 500 cycles at 5 C. The sufficient Na and complete solid-solution reaction are critical to realizing high-performance P2-type cathodes for sodium-ion batteries.},
doi = {10.1002/ange.202003972},
journal = {Angewandte Chemie},
number = 34,
volume = 132,
place = {United States},
year = {Fri Jun 05 00:00:00 EDT 2020},
month = {Fri Jun 05 00:00:00 EDT 2020}
}
Free Publicly Available Full Text
Publisher's Version of Record
Other availability
Search WorldCat to find libraries that may hold this journal
Save to My Library
You must Sign In or Create an Account in order to save documents to your library.
Works referenced in this record:
Electrochemistry and Solid‐State Chemistry of NaMeO 2 (Me = 3d Transition Metals)
journal, June 2018
- Kubota, Kei; Kumakura, Shinichi; Yoda, Yusuke
- Advanced Energy Materials, Vol. 8, Issue 17
Review—Manganese-Based P2-Type Transition Metal Oxides as Sodium-Ion Battery Cathode Materials
journal, January 2015
- Clément, Raphaële J.; Bruce, Peter G.; Grey, Clare P.
- Journal of The Electrochemical Society, Vol. 162, Issue 14
Anionic Redox Reaction-Induced High-Capacity and Low-Strain Cathode with Suppressed Phase Transition
journal, February 2019
- Rong, Xiaohui; Hu, Enyuan; Lu, Yaxiang
- Joule, Vol. 3, Issue 2
Layered Oxide Cathodes for Sodium-Ion Batteries: Phase Transition, Air Stability, and Performance
journal, November 2017
- Wang, Peng-Fei; You, Ya; Yin, Ya-Xia
- Advanced Energy Materials, Vol. 8, Issue 8
High‐Entropy Layered Oxide Cathodes for Sodium‐Ion Batteries
journal, January 2020
- Zhao, Chenglong; Ding, Feixiang; Lu, Yaxiang
- Angewandte Chemie International Edition, Vol. 59, Issue 1
P2-Na0.6[Cr0.6Ti0.4]O2 cation-disordered electrode for high-rate symmetric rechargeable sodium-ion batteries
journal, April 2015
- Wang, Yuesheng; Xiao, Ruijuan; Hu, Yong-Sheng
- Nature Communications, Vol. 6, Issue 1
Natriumionenbatterien für die elektrochemische Energiespeicherung
journal, February 2015
- Kundu, Dipan; Talaie, Elahe; Duffort, Victor
- Angewandte Chemie, Vol. 127, Issue 11
An O3-type Oxide with Low Sodium Content as the Phase-Transition-Free Anode for Sodium-Ion Batteries
journal, May 2018
- Zhao, Chenglong; Avdeev, Maxim; Chen, Liquan
- Angewandte Chemie, Vol. 130, Issue 24
High Voltage Mg-Doped Na 0.67 Ni 0.3– x Mg x Mn 0.7 O 2 ( x = 0.05, 0.1) Na-Ion Cathodes with Enhanced Stability and Rate Capability
journal, July 2016
- Singh, Gurpreet; Tapia-Ruiz, Nuria; Lopez del Amo, Juan Miguel
- Chemistry of Materials, Vol. 28, Issue 14
In Situ X-Ray Diffraction Study of P2-Na[sub 2/3][Ni[sub 1/3]Mn[sub 2/3]]O[sub 2]
journal, January 2001
- Lu, Zhonghua; Dahn, J. R.
- Journal of The Electrochemical Society, Vol. 148, Issue 11
New O2/P2-type Li-Excess Layered Manganese Oxides as Promising Multi-Functional Electrode Materials for Rechargeable Li/Na Batteries
journal, May 2014
- Yabuuchi, Naoaki; Hara, Ryo; Kajiyama, Masataka
- Advanced Energy Materials, Vol. 4, Issue 13
Crystal Structures and Electrochemical Performance of Air-Stable Na 2/3 Ni 1/3– x Cu x Mn 2/3 O 2 in Sodium Cells
journal, February 2017
- Zheng, Lituo; Li, Jierui; Obrovac, M. N.
- Chemistry of Materials, Vol. 29, Issue 4
Cyclohexanehexone with Ultrahigh Capacity as Cathode Materials for Lithium‐Ion Batteries
journal, April 2019
- Lu, Yong; Hou, Xuesen; Miao, Licheng
- Angewandte Chemie, Vol. 131, Issue 21
Structure-Induced Reversible Anionic Redox Activity in Na Layered Oxide Cathode
journal, January 2018
- Rong, Xiaohui; Liu, Jue; Hu, Enyuan
- Joule, Vol. 2, Issue 1
Slope‐Dominated Carbon Anode with High Specific Capacity and Superior Rate Capability for High Safety Na‐Ion Batteries
journal, February 2019
- Qi, Yuruo; Lu, Yaxiang; Ding, Feixiang
- Angewandte Chemie, Vol. 131, Issue 13
An advanced cathode for Na-ion batteries with high rate and excellent structural stability
journal, January 2013
- Lee, Dae Hoe; Xu, Jing; Meng, Ying Shirley
- Physical Chemistry Chemical Physics, Vol. 15, Issue 9
Role of Crystal Symmetry in the Reversibility of Stacking-Sequence Changes in Layered Intercalation Electrodes
journal, November 2017
- Radin, Maxwell D.; Alvarado, Judith; Meng, Y. Shirley
- Nano Letters, Vol. 17, Issue 12
High‐Entropy Layered Oxide Cathodes for Sodium‐Ion Batteries
journal, January 2020
- Zhao, Chenglong; Ding, Feixiang; Lu, Yaxiang
- Angewandte Chemie, Vol. 132, Issue 1
Local Structure and Cation Ordering in O3 Lithium Nickel Manganese Oxides with Stoichiometry Li[Ni[sub x]Mn[sub (2−x)/3]Li[sub (1−2x)/3]]O[sub 2]
journal, January 2004
- Yoon, Won-Sub; Iannopollo, Steven; Grey, Clare P.
- Electrochemical and Solid-State Letters, Vol. 7, Issue 7
Origin of Enhanced Capacity Retention of P2-Type Na 2/3 Ni 1/3- x Mn 2/3 Cu x O 2 for Na-Ion Batteries
journal, January 2017
- Kubota, Kei; Yoda, Yusuke; Komaba, Shinichi
- Journal of The Electrochemical Society, Vol. 164, Issue 12
Research Development on Sodium-Ion Batteries
journal, October 2014
- Yabuuchi, Naoaki; Kubota, Kei; Dahbi, Mouad
- Chemical Reviews, Vol. 114, Issue 23
An O3-type Oxide with Low Sodium Content as the Phase-Transition-Free Anode for Sodium-Ion Batteries
journal, May 2018
- Zhao, Chenglong; Avdeev, Maxim; Chen, Liquan
- Angewandte Chemie International Edition, Vol. 57, Issue 24
Review—Practical Issues and Future Perspective for Na-Ion Batteries
journal, January 2015
- Kubota, Kei; Komaba, Shinichi
- Journal of The Electrochemical Society, Vol. 162, Issue 14
The Emerging Chemistry of Sodium Ion Batteries for Electrochemical Energy Storage
journal, February 2015
- Kundu, Dipan; Talaie, Elahe; Duffort, Victor
- Angewandte Chemie International Edition, Vol. 54, Issue 11
Suppressing the P2-O2 Phase Transition of Na 0.67 Mn 0.67 Ni 0.33 O 2 by Magnesium Substitution for Improved Sodium-Ion Batteries
journal, May 2016
- Wang, Peng-Fei; You, Ya; Yin, Ya-Xia
- Angewandte Chemie International Edition, Vol. 55, Issue 26
Cyclohexanehexone with Ultrahigh Capacity as Cathode Materials for Lithium‐Ion Batteries
journal, May 2019
- Lu, Yong; Hou, Xuesen; Miao, Licheng
- Angewandte Chemie International Edition, Vol. 58, Issue 21
Crystallographic Evolution of P2 Na 2/3 Fe 0.4 Mn 0.6 O 2 Electrodes during Electrochemical Cycling
journal, August 2016
- Dose, Wesley M.; Sharma, Neeraj; Pramudita, James C.
- Chemistry of Materials, Vol. 28, Issue 17
Slope-Dominated Carbon Anode with High Specific Capacity and Superior Rate Capability for High Safety Na-Ion Batteries
journal, February 2019
- Qi, Yuruo; Lu, Yaxiang; Ding, Feixiang
- Angewandte Chemie International Edition, Vol. 58, Issue 13
Von Lithium- zu Natriumionenbatterien: Vorteile, Herausforderungen und Überraschendes
journal, November 2017
- Nayak, Prasant Kumar; Yang, Liangtao; Brehm, Wolfgang
- Angewandte Chemie, Vol. 130, Issue 1
A Hydrostable Cathode Material Based on the Layered P2@P3 Composite that Shows Redox Behavior for Copper in High-Rate and Long-Cycling Sodium-Ion Batteries
journal, January 2019
- Yan, Zichao; Tang, Liang; Huang, Yangyang
- Angewandte Chemie, Vol. 131, Issue 5
P2-type Na 2/3 Ni 1/3 Mn 2/3−x Ti x O 2 as a new positive electrode for higher energy Na-ion batteries
journal, January 2014
- Yoshida, Hiroaki; Yabuuchi, Naoaki; Kubota, Kei
- Chem. Commun., Vol. 50, Issue 28
Lithium-Doping Stabilized High-Performance P2–Na 0.66 Li 0.18 Fe 0.12 Mn 0.7 O 2 Cathode for Sodium Ion Batteries
journal, April 2019
- Yang, Lufeng; Li, Xiang; Liu, Jue
- Journal of the American Chemical Society, Vol. 141, Issue 16
Superstructure control of first-cycle voltage hysteresis in oxygen-redox cathodes
journal, December 2019
- House, Robert A.; Maitra, Urmimala; Pérez-Osorio, Miguel A.
- Nature, Vol. 577, Issue 7791
Deciphering an Abnormal Layered‐Tunnel Heterostructure Induced by Chemical Substitution for the Sodium Oxide Cathode
journal, December 2019
- Xiao, Yao; Zhu, Yan‐Fang; Xiang, Wei
- Angewandte Chemie, Vol. 132, Issue 4
P2-type Na 0.66 Ni 0.33–x Zn x Mn 0.67 O 2 as new high-voltage cathode materials for sodium-ion batteries
journal, May 2015
- Wu, Xuehang; Guo, Jianghuai; Wang, Dawei
- Journal of Power Sources, Vol. 281
1D Nanomaterials: Design, Synthesis, and Applications in Sodium-Ion Batteries
journal, December 2017
- Jin, Ting; Han, Qingqing; Wang, Yijing
- Small, Vol. 14, Issue 2
Binder‐Free Electrodes for Advanced Sodium‐Ion Batteries
journal, February 2019
- Jin, Ting; Han, Qingqing; Jiao, Lifang
- Advanced Materials, Vol. 32, Issue 3
Building better batteries
journal, February 2008
- Armand, M.; Tarascon, J.-M.
- Nature, Vol. 451, Issue 7179, p. 652-657
Dynamic Aspects of Solid Solution Cathodes for Electrochemical Power Sources
journal, January 1979
- Atlung, S.
- Journal of The Electrochemical Society, Vol. 126, Issue 8
Enabling Sodium Batteries Using Lithium-Substituted Sodium Layered Transition Metal Oxide Cathodes
journal, February 2011
- Kim, Donghan; Kang, Sun-Ho; Slater, Michael
- Advanced Energy Materials, Vol. 1, Issue 3, p. 333-336
Recent Advances and Prospects of Cathode Materials for Sodium-Ion Batteries
journal, August 2015
- Xiang, Xingde; Zhang, Kai; Chen, Jun
- Advanced Materials, Vol. 27, Issue 36
Suppressing the P2-O2 Phase Transition of Na 0.67 Mn 0.67 Ni 0.33 O 2 by Magnesium Substitution for Improved Sodium-Ion Batteries
journal, May 2016
- Wang, Peng-Fei; You, Ya; Yin, Ya-Xia
- Angewandte Chemie, Vol. 128, Issue 26
Ni-based cathode materials for Na-ion batteries
journal, June 2019
- Zhao, Chenglong; Lu, Yaxiang; Chen, Liquan
- Nano Research, Vol. 12, Issue 9
Na + /vacancy disordering promises high-rate Na-ion batteries
journal, March 2018
- Wang, Peng-Fei; Yao, Hu-Rong; Liu, Xin-Yu
- Science Advances, Vol. 4, Issue 3
From Lithium-Ion to Sodium-Ion Batteries: Advantages, Challenges, and Surprises
journal, November 2017
- Nayak, Prasant Kumar; Yang, Liangtao; Brehm, Wolfgang
- Angewandte Chemie International Edition, Vol. 57, Issue 1
A Hydrostable Cathode Material Based on the Layered P2@P3 Composite that Shows Redox Behavior for Copper in High-Rate and Long-Cycling Sodium-Ion Batteries
journal, January 2019
- Yan, Zichao; Tang, Liang; Huang, Yangyang
- Angewandte Chemie International Edition, Vol. 58, Issue 5
Identifying the Critical Role of Li Substitution in P2–Na x [Li y Ni z Mn 1– y – z ]O 2 (0 < x , y , z < 1) Intercalation Cathode Materials for High-Energy Na-Ion Batteries
journal, December 2013
- Xu, Jing; Lee, Dae Hoe; Clément, Raphaële J.
- Chemistry of Materials, Vol. 26, Issue 2
Simulating Charge, Spin, and Orbital Ordering: Application to Jahn–Teller Distortions in Layered Transition-Metal Oxides
journal, January 2018
- Radin, Maxwell D.; Van der Ven, Anton
- Chemistry of Materials, Vol. 30, Issue 3
Deciphering an Abnormal Layered‐Tunnel Heterostructure Induced by Chemical Substitution for the Sodium Oxide Cathode
journal, January 2020
- Xiao, Yao; Zhu, Yan‐Fang; Xiang, Wei
- Angewandte Chemie International Edition, Vol. 59, Issue 4