The effect of wood composition and supercritical CO2 extraction on charcoal production in ferroalloy industries

Surup, Gerrit Ralf; Hunt, Andrew J.; Attard, Thomas; Budarin, Vitaliy L.; Forsberg, Fredrik; Arshadi, Mehrdad; Abdelsayed, Victor; Shekhawat, Dushyant; Trubetskaya, Anna

doi:10.1016/j.energy.2019.116696

Title: The effect of wood composition and supercritical CO₂ extraction on charcoal production in ferroalloy industries

Abstract

This work demonstrates that the integration of supercritical carbon dioxide extraction with slow pyrolysis is an effective method for the production of value-added chemicals and charcoal that is an attractive alternative to coke for industry. Integration of technologies is key for the development of holistic biorefineries that exploit all parts of the biomass feedstock and generate little or ideally no waste. In fact, the use of waste or low valued wood fractions is attractive due to their plentiful abundance and lack of exploitation. Supercritical carbon dioxide has been demonstrated to be effective at the removal of over half of extractives from low quality wood and forestry wastes, which can account for up to 11 wt %, of the dried biomass in waste needles. High extractive yields by supercritical carbon dioxide extraction illustrates the potential of utilizing low quality wood as an alternative feedstock for the sustainable production of value-added chemicals. We report high yields of steroids and derivatives, terpenes and other plant metabolites were obtained in the extracts of needles, branches and bark. Importantly, supercritical carbon dioxide extraction had little impact neither on the physical properties of original wood nor on the yield of solid charcoal. This indicates that extractionmore »« less

Authors:

Surup, Gerrit Ralf ^[1]; Hunt, Andrew J. ^[2]; Attard, Thomas ^[3]; Budarin, Vitaliy L. ^[3];

^[4]; Arshadi, Mehrdad ^[5]; Abdelsayed, Victor ^[6]; Shekhawat, Dushyant ^[7];

^[8]

Norwegian Univ. of Science and Technology, Trondheim (Norway)
Khon Kaen Univ. (Thailand)
Univ. of York (United Kingdom)
Luleå Univ. of Technology (Sweden)
Swedish Univ. of Agricultural Sciences (SLU), Umea (Sweden)
National Energy Technology Lab. (NETL), Morgantown, WV (United States); Leidos Research Support Team, Morgantown, WV (United States)
National Energy Technology Lab. (NETL), Morgantown, WV (United States)
Univ. of Limerick (Ireland)

Publication Date:: Mon Dec 16 00:00:00 EST 2019

Research Org.:: National Energy Technology Laboratory (NETL), Pittsburgh, PA, Morgantown, WV (United States)

Sponsoring Org.:: USDOE Office of Fossil Energy (FE); FORMAS; Kempe Foundation; Bjorn Wahlstroms; Jernkontoret Stiftelsen; Thailand Research Fund; Ministry of Higher Education, Science, Research and Innovation

OSTI Identifier:: 1635627

Resource Type:: Accepted Manuscript

Journal Name:: Energy

Additional Journal Information:: Journal Volume: 193; Journal ID: ISSN 0360-5442

Publisher:: Elsevier

Country of Publication:: United States

Language:: English

Subject:: 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; biorefinery; pyrolysis; supercritical; sterols; solid fuels

Citation Formats


                    Surup, Gerrit Ralf, Hunt, Andrew J., Attard, Thomas, Budarin, Vitaliy L., Forsberg, Fredrik, Arshadi, Mehrdad, Abdelsayed, Victor, Shekhawat, Dushyant, and Trubetskaya, Anna. The effect of wood composition and supercritical CO2 extraction on charcoal production in ferroalloy industries.  United States: N. p., 2019. 
Web.  doi:10.1016/j.energy.2019.116696.

Copy to clipboard


                    Surup, Gerrit Ralf, Hunt, Andrew J., Attard, Thomas, Budarin, Vitaliy L., Forsberg, Fredrik, Arshadi, Mehrdad, Abdelsayed, Victor, Shekhawat, Dushyant, & Trubetskaya, Anna. The effect of wood composition and supercritical CO2 extraction on charcoal production in ferroalloy industries.  United States.  https://doi.org/10.1016/j.energy.2019.116696

Copy to clipboard


                    Surup, Gerrit Ralf, Hunt, Andrew J., Attard, Thomas, Budarin, Vitaliy L., Forsberg, Fredrik, Arshadi, Mehrdad, Abdelsayed, Victor, Shekhawat, Dushyant, and Trubetskaya, Anna. Mon .  
"The effect of wood composition and supercritical CO2 extraction on charcoal production in ferroalloy industries".  United States.  https://doi.org/10.1016/j.energy.2019.116696.  https://www.osti.gov/servlets/purl/1635627.

Copy to clipboard


                    
@article{osti_1635627,

  title        = {The effect of wood composition and supercritical CO2 extraction on charcoal production in ferroalloy industries},

  author       = {Surup, Gerrit Ralf and Hunt, Andrew J. and Attard, Thomas and Budarin, Vitaliy L. and Forsberg, Fredrik and Arshadi, Mehrdad and Abdelsayed, Victor and Shekhawat, Dushyant and Trubetskaya, Anna},

  abstractNote = {This work demonstrates that the integration of supercritical carbon dioxide extraction with slow pyrolysis is an effective method for the production of value-added chemicals and charcoal that is an attractive alternative to coke for industry. Integration of technologies is key for the development of holistic biorefineries that exploit all parts of the biomass feedstock and generate little or ideally no waste. In fact, the use of waste or low valued wood fractions is attractive due to their plentiful abundance and lack of exploitation. Supercritical carbon dioxide has been demonstrated to be effective at the removal of over half of extractives from low quality wood and forestry wastes, which can account for up to 11 wt %, of the dried biomass in waste needles. High extractive yields by supercritical carbon dioxide extraction illustrates the potential of utilizing low quality wood as an alternative feedstock for the sustainable production of value-added chemicals. We report high yields of steroids and derivatives, terpenes and other plant metabolites were obtained in the extracts of needles, branches and bark. Importantly, supercritical carbon dioxide extraction had little impact neither on the physical properties of original wood nor on the yield of solid charcoal. This indicates that extraction by supercritical carbon dioxide can be used as a method for adding further value to the process by removal of bio-based chemicals, whilst still maintaining the yield of the solid fuel product. Moreover, the heat treatment temperature and supercritical carbon dioxide extraction had a significant impact on the tar yields during pyrolysis, leading to an increase in naphthalene, polycyclic aromatic hydrocarbons, aromatic and phenolic fractions with greater temperature. These results are promising as they show that the charcoal obtained from this renewable feedstock could be used as an alternative to fossil-based coke in applications including ferroalloy industries.},

  doi          = {10.1016/j.energy.2019.116696},

  journal      = {Energy},

  number       = ,

  volume       = 193,

  place        = {United States},

  year         = {Mon Dec 16 00:00:00 EST 2019},

  month        = {Mon Dec 16 00:00:00 EST 2019}

}

Copy to clipboard

Journal Article:

Free Publicly Available Full Text

Accepted Manuscript (DOE)

Publisher's Version of Record

https://doi.org/10.1016/j.energy.2019.116696

Other availability

Search WorldCat to find libraries that may hold this journal

Citation Metrics:

Cited by: 13 works

Citation information provided by
Web of Science

Save / Share:

Export Metadata

Save to My Library

Works referenced in this record:

Impact of supercritical extraction on solid fuel wood pellet properties and off-gassing during storage
journal, January 2016

Attard, Thomas M.; Arshadi, Mehrdad; Nilsson, Calle
Green Chemistry, Vol. 18, Issue 9
DOI: 10.1039/C5GC02479J

Commercial uses of fatty acids
journal, November 1952

Ruston, N. A.
Journal of the American Oil Chemists Society, Vol. 29, Issue 11
DOI: 10.1007/BF02632638

Polyunsaturated fatty acids, part 1: Occurrence, biological activities and applications
journal, October 1997

Gill, I.; Valivety, R.
Trends in Biotechnology, Vol. 15, Issue 10
DOI: 10.1016/S0167-7799(97)01076-7

Production of biodiesel fuel from tall oil fatty acids via high temperature methanol reaction
journal, November 2011

White, Kristopher; Lorenz, Nikki; Potts, Tom
Fuel, Vol. 90, Issue 11
DOI: 10.1016/j.fuel.2011.06.017

Characterization and reactivity of charcoal from high temperature pyrolysis (800–1600 °C)
journal, January 2019

Surup, Gerrit Ralf; Nielsen, Henrik Kofoed; Heidelmann, Markus
Fuel, Vol. 235
DOI: 10.1016/j.fuel.2018.08.092

A study of densified biochar as carbon source in the silicon and ferrosilicon production
journal, August 2019

Riva, Lorenzo; Surup, Gerrit Ralf; Buø, Therese Videm
Energy, Vol. 181
DOI: 10.1016/j.energy.2019.06.013

Characterization of renewable reductants and charcoal-based pellets for the use in ferroalloy industries
journal, January 2019

Surup, Gerrit; Vehus, Tore; Eidem, Per-Anders
Energy, Vol. 167
DOI: 10.1016/j.energy.2018.10.193

The effect of feedstock origin and temperature on the structure and reactivity of char from pyrolysis at 1300–2800 °C
journal, January 2019

Surup, Gerrit Ralf; Foppe, Manuel; Schubert, Daniel
Fuel, Vol. 235
DOI: 10.1016/j.fuel.2018.07.093

Supercritical fluid extraction (SFE) as an effective tool in reducing auto-oxidation of dried pine sawdust for power generation
journal, January 2012

Arshadi, Mehrdad; Hunt, Andrew J.; Clark, James H.
RSC Advances, Vol. 2, Issue 5
DOI: 10.1039/c1ra00715g

Use of green chemical technologies in an integrated biorefinery
journal, January 2011

Budarin, Vitaly L.; Shuttleworth, Peter S.; Dodson, Jennifer R.
Energy Environ. Sci., Vol. 4, Issue 2
DOI: 10.1039/C0EE00184H

Economic analysis of rosemary, fennel and anise essential oils obtained by supercritical fluid extraction
journal, January 2007

Pereira, Camila G.; Meireles, M. Angela A.
Flavour and Fragrance Journal, Vol. 22, Issue 5
DOI: 10.1002/ffj.1813

Green Extraction of Natural Products: Concept and Principles
journal, July 2012

Chemat, Farid; Vian, Maryline Abert; Cravotto, Giancarlo
International Journal of Molecular Sciences, Vol. 13, Issue 7
DOI: 10.3390/ijms13078615

Hydrothermal processing, as an alternative for upgrading agriculture residues and marine biomass according to the biorefinery concept: A review
journal, May 2013

Ruiz, Héctor A.; Rodríguez-Jasso, Rosa M.; Fernandes, Bruno D.
Renewable and Sustainable Energy Reviews, Vol. 21
DOI: 10.1016/j.rser.2012.11.069

Generation, Capture, and Utilization of Industrial Carbon Dioxide
journal, January 2010

Hunt, Andrew J.; Sin, Emily H. K.; Marriott, Ray
ChemSusChem, Vol. 3, Issue 3
DOI: 10.1002/cssc.200900169

Identification, quantification and Chrastil modelling of wheat straw wax extraction using supercritical carbon dioxide
journal, March 2014

Sin, Emily H. K.; Marriott, Ray; Hunt, Andrew J.
Comptes Rendus Chimie, Vol. 17, Issue 3
DOI: 10.1016/j.crci.2013.12.001

Supercritical fluids: technology and application to food processing
journal, March 2005

Brunner, Gerd
Journal of Food Engineering, Vol. 67, Issue 1-2
DOI: 10.1016/j.jfoodeng.2004.05.060

Separation of Biomass Pyrolysis Oil by Supercritical CO2 Extraction
journal, January 2010

Wang, Jinghua; Cui, Hongyou; Wei, Shuqin
Smart Grid and Renewable Energy, Vol. 01, Issue 02
DOI: 10.4236/sgre.2010.12015

Novel Integrated Biorefinery for Olive Mill Waste Management: Utilization of Secondary Waste for Water Treatment
journal, November 2016

Goldfarb, Jillian L.; Buessing, Li; Gunn, Erica
ACS Sustainable Chemistry & Engineering, Vol. 5, Issue 1
DOI: 10.1021/acssuschemeng.6b02202

An integrated biorefinery concept for olive mill waste management: supercritical CO₂ extraction and energy recovery
journal, January 2015

Schievano, Andrea; Adani, Fabrizio; Buessing, Li
Green Chemistry, Vol. 17, Issue 5
DOI: 10.1039/C5GC00076A

Prediction ofPinus sylvestrisclear-wood properties using NIR spectroscopy and biorthogonal partial least squares regression
journal, July 2008

Lestander, Torbjörn A.; Lindeberg, Johan; Eriksson, Daniel
Canadian Journal of Forest Research, Vol. 38, Issue 7
DOI: 10.1139/X08-047

Chemical forms of ash-forming elements in woody biomass fuels
journal, February 2010

Werkelin, Johan; Skrifvars, Bengt-Johan; Zevenhoven, Maria
Fuel, Vol. 89, Issue 2
DOI: 10.1016/j.fuel.2009.09.005

Influence of Extractives on the Analysis of Herbaceous Biomass ^†
journal, February 1997

Thammasouk, Khamphet; Tandjo, Djuhartini; Penner, Michael H.
Journal of Agricultural and Food Chemistry, Vol. 45, Issue 2
DOI: 10.1021/jf960401r

Charcoal from agricultural residues as alternative reducing agent in metal recycling
journal, April 2012

Griessacher, Thomas; Antrekowitsch, Jürgen; Steinlechner, Stefan
Biomass and Bioenergy, Vol. 39
DOI: 10.1016/j.biombioe.2011.12.043

Analysis of optimal temperature, pressure and binder quantity for the production of biocarbon pellet to be used as a substitute for coke
journal, December 2019

Riva, Lorenzo; Nielsen, Henrik Kofoed; Skreiberg, Øyvind
Applied Energy, Vol. 256
DOI: 10.1016/j.apenergy.2019.113933

A 3D in-situ investigation of the deformation in compressive loading in the thickness direction of cellulose fiber mats
journal, August 2015

Joffre, Thomas; Girlanda, Orlando; Forsberg, Fredrik
Cellulose, Vol. 22, Issue 5
DOI: 10.1007/s10570-015-0727-7

3D micro-scale deformations of wood in bending: Synchrotron radiation μCT data analyzed with digital volume correlation
journal, December 2008

Forsberg, F.; Mooser, R.; Arnold, M.
Journal of Structural Biology, Vol. 164, Issue 3
DOI: 10.1016/j.jsb.2008.08.004

Full Three-Dimensional Strain Measurements on Wood Exposed to Three-Point Bending: Analysis by Use of Digital Volume Correlation Applied to Synchrotron Radiation Micro-Computed Tomography Image Data
journal, February 2010

Forsberg, F.; SjÃ¶dahl, M.; Mooser, R.
Strain, Vol. 46, Issue 1
DOI: 10.1111/j.1475-1305.2009.00687.x

Application of X-ray microtomography for the characterisation of hollow polymer-stabilised spray dried amorphous dispersion particles
journal, August 2016

Gamble, John F.; Terada, Masako; Holzner, Christian
International Journal of Pharmaceutics, Vol. 510, Issue 1
DOI: 10.1016/j.ijpharm.2016.05.051

A Threshold Selection Method from Gray-Level Histograms
journal, January 1979

Otsu, Nobuyuki
IEEE Transactions on Systems, Man, and Cybernetics, Vol. 9, Issue 1
DOI: 10.1109/TSMC.1979.4310076

Porosity and pore size distribution of different wood types as determined by mercury intrusion porosimetry
journal, November 2010

Plötze, Michael; Niemz, Peter
European Journal of Wood and Wood Products, Vol. 69, Issue 4
DOI: 10.1007/s00107-010-0504-0

Comparison of changes in micropores and mesopores in the wood cell walls of sapwood and heartwood
journal, June 2015

Yin, Jiangping; Song, Kunlin; Lu, Yun
Wood Science and Technology, Vol. 49, Issue 5
DOI: 10.1007/s00226-015-0741-9

Secondary comminution of wood pellets in power plant and laboratory-scale mills
journal, June 2017

Trubetskaya, Anna; Poyraz, Yunus; Weber, Roman
Fuel Processing Technology, Vol. 160
DOI: 10.1016/j.fuproc.2017.02.023

One way of representing the size and shape of biomass particles in combustion modeling
journal, October 2017

Trubetskaya, Anna; Beckmann, Gert; Wadenbäck, Johan
Fuel, Vol. 206
DOI: 10.1016/j.fuel.2017.06.052

Reduction of Tar and Soot Formation from Entrained-Flow Gasification of Woody Biomass by Alkali Impregnation
journal, April 2017

Umeki, Kentaro; Häggström, Gustav; Bach-Oller, Albert
Energy & Fuels, Vol. 31, Issue 5
DOI: 10.1021/acs.energyfuels.6b03480

Co-gasification of black liquor and pyrolysis oil at high temperature: Part 2. Fuel conversion
journal, June 2017

Bach-Oller, Albert; Kirtania, Kawnish; Furusjö, Erik
Fuel, Vol. 197
DOI: 10.1016/j.fuel.2017.01.108

Categorization of tars from fast pyrolysis of pure lignocellulosic compounds at high temperature
journal, October 2019

Trubetskaya, Anna; Souihi, Nabil; Umeki, Kentaro
Renewable Energy, Vol. 141
DOI: 10.1016/j.renene.2019.04.033

High-throughput characterization of sediment organic matter by pyrolysis–gas chromatography/mass spectrometry and multivariate curve resolution: A promising analytical tool in (paleo)limnology
journal, June 2015

Tolu, Julie; Gerber, Lorenz; Boily, Jean-François
Analytica Chimica Acta, Vol. 880
DOI: 10.1016/j.aca.2015.03.043

Multivariate curve resolution provides a high-throughput data processing pipeline for pyrolysis-gas chromatography/mass spectrometry
journal, May 2012

Gerber, Lorenz; Eliasson, Mattias; Trygg, Johan
Journal of Analytical and Applied Pyrolysis, Vol. 95
DOI: 10.1016/j.jaap.2012.01.011

Effect of coal rank on structure and dielectric properties of chars
journal, August 2015

Liu, Haiyu; Xu, Liang; Jin, Yan
Fuel, Vol. 153
DOI: 10.1016/j.fuel.2015.03.008

Extraction of lignin from wood with supercritical alcohols
journal, December 1989

Reyes, Tom; Bandyopadhyay, S. S.; McCoy, B. J.
The Journal of Supercritical Fluids, Vol. 2, Issue 2-3
DOI: 10.1016/0896-8446(89)90014-4

The relationship between fiber-porosity and cellulose digestibility in steam-explodedPinus radiata
journal, April 1988

Wong, Ken K. Y.; Deverell, Kay F.; Mackie, Keith L.
Biotechnology and Bioengineering, Vol. 31, Issue 5
DOI: 10.1002/bit.260310509

X-ray computed microtomography and 2D image analysis for morphological characterization of short lignocellulosic fibers raw materials: A benchmark survey
journal, September 2015

Hamdi, Seif Eddine; Delisée, Christine; Malvestio, Jérome
Composites Part A: Applied Science and Manufacturing, Vol. 76
DOI: 10.1016/j.compositesa.2015.04.019

New approaches to measuring biochar density and porosity
journal, July 2014

Brewer, Catherine E.; Chuang, Victoria J.; Masiello, Caroline A.
Biomass and Bioenergy, Vol. 66
DOI: 10.1016/j.biombioe.2014.03.059

Mercury intrusion porosimetry in pulp and paper technology
journal, December 2005

Moura, M. J.; Ferreira, P. J.; Figueiredo, M. M.
Powder Technology, Vol. 160, Issue 2
DOI: 10.1016/j.powtec.2005.08.033

Investigations of the pore-size distribution of wood in the dry and wet state by means of mercury intrusion porosimetry
journal, September 2014

Zauer, Mario; Hempel, Simone; Pfriem, Alexander
Wood Science and Technology, Vol. 48, Issue 6
DOI: 10.1007/s00226-014-0671-y

Bestimmung der Porengrößenverteilung in Holz mit dem Quecksilber-Porosimeter
journal, June 1974

Schneider, Adolf; Wagner, Ludwig
Holz als Roh- und Werkstoff, Vol. 32, Issue 6
DOI: 10.1007/BF02607257

Beitrag zur Porositätsanalyse von Holz mit dem Quecksilber-Porosimeter
journal, August 1979

Schneider, A.
Holz als Roh- und Werkstoff, Vol. 37, Issue 8
DOI: 10.1007/BF02607491

Elektronenmikroskopische Untersuchungen über den Bau der Hoftüpfel
journal, May 1952

Liese, Walter; Fahnenbrock, Margarete
Holz als Roh- und Werkstoff, Vol. 10, Issue 5
DOI: 10.1007/BF02605534

Extractive profiles of different lodgepole pine (Pinus contorta) fractions grown under a direct seeding-based silvicultural regime
journal, July 2014

Backlund, Ingegerd; Arshadi, Mehrdad; Hunt, Andrew J.
Industrial Crops and Products, Vol. 58
DOI: 10.1016/j.indcrop.2014.04.027

Sterol composition and biosynthesis in sorghum: Importance to developmental regulation
journal, January 1986

Heupel, Rick C.; Sauvaire, Y.; Le, Phu H.
Lipids, Vol. 21, Issue 1
DOI: 10.1007/BF02534305

Free sterols, steryl esters, and lipid phosphorus in needles of scot's pine (Pinus sylvestris L.)
journal, November 1991

Fischer, Christine; Höll, Wolfgang
Lipids, Vol. 26, Issue 11
DOI: 10.1007/BF02535980

Concentration gradients of free sterols, steryl esters and lipid phosphorus in the trunkwood of Scot's pine (Pinus sylvestris L.)
journal, January 1987

H�ll, W.; Lipp, J.
Trees, Vol. 1, Issue 2
DOI: 10.1007/BF00203574

Industrial Uses of Wood Char
journal, August 1998

Kumar, M.; Gupta, R. C.
Energy Sources, Vol. 20, Issue 7
DOI: 10.1080/00908319808970079

Development of TG measurements of intrinsic char combustion reactivity for industrial and research purposes
journal, September 1998

Russell, N. V.; Beeley, T. J.; Man, C. -K.
Fuel Processing Technology, Vol. 57, Issue 2
DOI: 10.1016/S0378-3820(98)00077-0

Potassium and soot interaction in fast biomass pyrolysis at high temperatures
journal, August 2018

Trubetskaya, Anna; Larsen, Flemming Hofmann; Shchukarev, Andrey
Fuel, Vol. 225
DOI: 10.1016/j.fuel.2018.03.140

Complex permittivities and dielectric relaxation of granular activated carbons at microwave frequencies between 0.2 and 26 GHz
journal, January 2003

Atwater, James E.; Wheeler, Richard R.
Carbon, Vol. 41, Issue 9
DOI: 10.1016/S0008-6223(03)00150-7

Dielectric Properties of Biomass/Biochar Mixtures at Microwave Frequencies
journal, April 2017

Ellison, Candice; McKeown, Murat; Trabelsi, Samir
Energies, Vol. 10, Issue 4
DOI: 10.3390/en10040502

FT-i.r. analysis of coal
journal, July 1988

Solomon, Peter R.; Carangelo, Robert M.
Fuel, Vol. 67, Issue 7
DOI: 10.1016/0016-2361(88)90095-6

The relation between the adsorption characteristics of polar organic compounds (alcohols and acids) and their orientation polarization on activated carbon
journal, January 1981

Selim, M. M.; El-Nabarawy, Th. A.; Ghazy, T. M.
Carbon, Vol. 19, Issue 3
DOI: 10.1016/0008-6223(81)90038-5

Dielectric characterization of coals
journal, March 2003

Forniés-Marquina, J. M.; Martín, J. C.; Martínez, J. P.
Canadian Journal of Physics, Vol. 81, Issue 3
DOI: 10.1139/p02-125

Effect of maleic anhydride on dielectric properties of natural fiber composite
journal, April 2014

Ben Amor, I.; Arous, M.; Kallel, A.
Journal of Electrostatics, Vol. 72, Issue 2
DOI: 10.1016/j.elstat.2013.12.006

Oil palm fiber (OPF) and its composites: A review
journal, January 2011

Shinoj, S.; Visvanathan, R.; Panigrahi, S.
Industrial Crops and Products, Vol. 33, Issue 1
DOI: 10.1016/j.indcrop.2010.09.009

Dielectric Properties of Typical Australian Wood-Based Biomass Materials at Microwave Frequency
journal, July 2010

Ramasamy, Shanmuganathan; Moghtaderi, Behdad
Energy & Fuels, Vol. 24, Issue 8
DOI: 10.1021/ef100623e

Microwave and slow pyrolysis biochar—Comparison of physical and functional properties
journal, March 2013

Mašek, Ondřej; Budarin, Vitaly; Gronnow, Mark
Journal of Analytical and Applied Pyrolysis, Vol. 100
DOI: 10.1016/j.jaap.2012.11.015

Hydrothermal carbonization of anaerobically digested maize silage
journal, October 2011

Mumme, Jan; Eckervogt, Lion; Pielert, Judith
Bioresource Technology, Vol. 102, Issue 19
DOI: 10.1016/j.biortech.2011.06.099

From olive waste to solid biofuel through hydrothermal carbonisation: The role of temperature and solid load on secondary char formation and hydrochar energy properties
journal, March 2017

Volpe, Maurizio; Fiori, Luca
Journal of Analytical and Applied Pyrolysis, Vol. 124
DOI: 10.1016/j.jaap.2017.02.022

Rapid estimation of the manufacturing cost of extracts obtained by supercritical fluid extraction
journal, March 2005

Rosa, Paulo T. V.; Meireles, M. Angela A.
Journal of Food Engineering, Vol. 67, Issue 1-2
DOI: 10.1016/j.jfoodeng.2004.05.064

Supercritical fluid extraction of vegetable matrices: Applications, trends and future perspectives of a convincing green technology
journal, August 2014

de Melo, M. M. R.; Silvestre, A. J. D.; Silva, C. M.
The Journal of Supercritical Fluids, Vol. 92
DOI: 10.1016/j.supflu.2014.04.007

Economic Assessment of Supercritical CO2 Extraction of Waxes as Part of a Maize Stover Biorefinery
journal, July 2015

Attard, Thomas; McElroy, Con; Hunt, Andrew
International Journal of Molecular Sciences, Vol. 16, Issue 8
DOI: 10.3390/ijms160817546

Toward an integrated straw-based biorefinery
journal, January 2007

Deswarte, Fabien E. I.; Clark, James H.; Wilson, Ashley J.
Biofuels, Bioproducts and Biorefining, Vol. 1, Issue 4
DOI: 10.1002/bbb.32

Valorization of spruce needle waste via supercritical extraction of waxes and facile isolation of nonacosan-10-ol
journal, January 2018

McElroy, Con R.; Attard, Thomas M.; Farmer, Thomas J.
Journal of Cleaner Production, Vol. 171
DOI: 10.1016/j.jclepro.2017.10.002

Antimicrobial and Antioxidant Compounds in the Nonvolatile Fraction of Expressed Orange Essential Oil
journal, August 1999

Vargas, Irasema; Sanz, Isidora; Moya, Pilar
Journal of Food Protection, Vol. 62, Issue 8
DOI: 10.4315/0362-028X-62.8.929

Isopimaric acid fromPinus nigra shows activity against multidrug-resistant and EMRSA strains ofStaphylococcus aureus
journal, January 2005

Smith, Eileen; Williamson, Elizabeth; Zloh, Mire
Phytotherapy Research, Vol. 19, Issue 6
DOI: 10.1002/ptr.1711

Anti-inflammatory activity of abietic acid, a diterpene isolated from Pimenta racemosa var. grissea
journal, February 2010

Fernández, M. A.; Tornos, M. P.; García, M. D.
Journal of Pharmacy and Pharmacology, Vol. 53, Issue 6
DOI: 10.1211/0022357011776027

Study of diabietic acid as matrix forming material
journal, June 1996

Ramani, C. C.; Puranik, P. K.; Dorle, A. K.
International Journal of Pharmaceutics, Vol. 137, Issue 1
DOI: 10.1016/0378-5173(95)04268-7

Study of the biodegradation and in vivo biocompatibility of novel biomaterials
journal, September 2003

Fulzele, S. V.; Satturwar, P. M.; Dorle, A. K.
European Journal of Pharmaceutical Sciences, Vol. 20, Issue 1
DOI: 10.1016/S0928-0987(03)00168-4

Phytosterols as anticancer compounds
journal, February 2007

Bradford, Peter G.; Awad, Atif B.
Molecular Nutrition & Food Research, Vol. 51, Issue 2
DOI: 10.1002/mnfr.200600164

Works referencing / citing this record:

Charcoal as an Alternative Reductant in Ferroalloy Production: A Review
journal, November 2020

Surup, Gerrit Ralf; Trubetskaya, Anna; Tangstad, Merete
Processes, Vol. 8, Issue 11
DOI: 10.3390/pr8111432

Similar Records in DOE PAGES and OSTI.GOV collections:

YEAR 2 BIOMASS UTILIZATION

Technical Report Zygarlicke, Christopher J

This Energy & Environmental Research Center (EERC) Year 2 Biomass Utilization Final Technical Report summarizes multiple projects in biopower or bioenergy, transportation biofuels, and bioproducts. A prototype of a novel advanced power system, termed the high-temperature air furnace (HITAF), was tested for performance while converting biomass and coal blends to energy. Three biomass fuels--wood residue or hog fuel, corn stover, and switchgrass--and Wyoming subbituminous coal were acquired for combustion tests in the 3-million-Btu/hr system. Blend levels were 20% biomass--80% coal on a heat basis. Hog fuel was prepared for the upcoming combustion test by air-drying and processing through a hammermore »« less
https://doi.org/10.2172/876436

Full Text Available
Commercial charcoal manufacture in Brazil

Conference Rezende, M E ; Lessa, A ; Pasa, V ; ...

Brazil is the only country where charcoal has a major industrial us. Almost 40% of the pig iron and all the ferroalloys produced in the country are based on it and were established near Minas Gerais iron ore deposits using non-sustainable farm charcoal. Since the 1980s charcoal production from large eucalyptus forests is gradually increasing, accounting for 40% of the 8 million tonnes produced in 1991. Farm charcoal is produced when native forests are slashed to give way to farm land. Adequate techniques, labor rights or environmental concerns are not common in this scenario. In large eucalyptus forests charcoal productionmore »« less
Multiscale Catalytic Fast Pyrolysis of Grindelia Reveals Opportunities for Generating Low Oxygen Content Bio-Oils from Drought Tolerant Biomass

Journal Article Cross, Phillip ; Iisa, Kristiina ; To, Anh ; ... - Energy and Fuels

Grindelia squarrosa (curlycup gumweed) biomass possesses unique biochemistry, cell wall composition, and leaf architecture tailored for prolific growth in arid and semiarid climates. Most notably, this plant has developed high levels of extractable resins that have high effective H/C_eff ratios ((mol H - 2 x mol O)/mol C), which is hypothesized to lead to low coke formation during catalytic fast pyrolysis (CFP) over the ZSM-5 catalyst. In microscale experiments with high ZSM-5 loadings (biomass-to-catalyst mass ratio (B/C) ~ 0.1), in situ CFP generated high yields of aromatic hydrocarbons (30% carbon yield) while ex situ CFP favored aliphatic hydrocarbons (25% carbonmore »« less
https://doi.org/10.1021/acs.energyfuels.1c02403

Full Text Available
An Assessment of the Conversion of Biomass and Industrial Waste Products to Activated Carbon

Journal Article Coker, Eric N. ; Lujan-Flores, Xavier ; Donaldson, Arlie Burl ; ... - Energies

The production of biochar from biomass and industrial wastes provides both environmental and economic sustainability. An effective way to ensure the sustainability of biochar is to produce high value-added activated carbon. The desirable characteristic of activated carbon is its high surface area for efficient adsorption of contaminants. Feedstocks can include a number of locally available materials with little or negative value, such as orchard slash and crop residue. In this context, it is necessary to determine and know the conversion effects of the feedstocks to be used in the production of activated carbon. In the study conducted for this purpose;more »« less
https://doi.org/10.3390/en16041606

Full Text Available
Understanding Biomass and Polymer Feedstock Variability Through Analytical Pyrolysis and Two Dimensional Gas Chromatography and Mass Spectrometry

S&T Accomplishment Report Hodges, Brittany D ; Zarzana, Christopher A ; Castle, Grace A.

Moving toward a circular carbon economy requires enabling reuse of carbon-based macromolecules like those in biomass and polymers. Meeting this goal requires increased upcycling of waste products into higher value products. For biomass waste such as corn stover, pine needles, or bark, one approach is using pyrolysis to convert these feedstocks into bio-oil that can be used for liquid fuel or transformed into other hydrocarbon based products, like bio-polymers. Waste plastics can be upcycled or recycled into new products, or alternatively converted into bio-oil by pyrolysis. Macromolecules from biomass and polymers are challenging to convert into liquid fuel or chemicalmore »« less
Full Text Available

Similar Records

Title: The effect of wood composition and supercritical CO2 extraction on charcoal production in ferroalloy industries

Abstract

Citation Formats

Impact of supercritical extraction on solid fuel wood pellet properties and off-gassing during storage journal, January 2016

Commercial uses of fatty acids journal, November 1952

Polyunsaturated fatty acids, part 1: Occurrence, biological activities and applications journal, October 1997

Production of biodiesel fuel from tall oil fatty acids via high temperature methanol reaction journal, November 2011

Characterization and reactivity of charcoal from high temperature pyrolysis (800–1600 °C) journal, January 2019

A study of densified biochar as carbon source in the silicon and ferrosilicon production journal, August 2019

Characterization of renewable reductants and charcoal-based pellets for the use in ferroalloy industries journal, January 2019

The effect of feedstock origin and temperature on the structure and reactivity of char from pyrolysis at 1300–2800 °C journal, January 2019

Supercritical fluid extraction (SFE) as an effective tool in reducing auto-oxidation of dried pine sawdust for power generation journal, January 2012

Use of green chemical technologies in an integrated biorefinery journal, January 2011

Economic analysis of rosemary, fennel and anise essential oils obtained by supercritical fluid extraction journal, January 2007

Green Extraction of Natural Products: Concept and Principles journal, July 2012

Hydrothermal processing, as an alternative for upgrading agriculture residues and marine biomass according to the biorefinery concept: A review journal, May 2013

Generation, Capture, and Utilization of Industrial Carbon Dioxide journal, January 2010

Identification, quantification and Chrastil modelling of wheat straw wax extraction using supercritical carbon dioxide journal, March 2014

Supercritical fluids: technology and application to food processing journal, March 2005

Separation of Biomass Pyrolysis Oil by Supercritical CO2 Extraction journal, January 2010

Novel Integrated Biorefinery for Olive Mill Waste Management: Utilization of Secondary Waste for Water Treatment journal, November 2016

An integrated biorefinery concept for olive mill waste management: supercritical CO2 extraction and energy recovery journal, January 2015

Prediction ofPinus sylvestrisclear-wood properties using NIR spectroscopy and biorthogonal partial least squares regression journal, July 2008

Chemical forms of ash-forming elements in woody biomass fuels journal, February 2010

Influence of Extractives on the Analysis of Herbaceous Biomass † journal, February 1997

Charcoal from agricultural residues as alternative reducing agent in metal recycling journal, April 2012

Analysis of optimal temperature, pressure and binder quantity for the production of biocarbon pellet to be used as a substitute for coke journal, December 2019

A 3D in-situ investigation of the deformation in compressive loading in the thickness direction of cellulose fiber mats journal, August 2015

3D micro-scale deformations of wood in bending: Synchrotron radiation μCT data analyzed with digital volume correlation journal, December 2008

Full Three-Dimensional Strain Measurements on Wood Exposed to Three-Point Bending: Analysis by Use of Digital Volume Correlation Applied to Synchrotron Radiation Micro-Computed Tomography Image Data journal, February 2010

Application of X-ray microtomography for the characterisation of hollow polymer-stabilised spray dried amorphous dispersion particles journal, August 2016

A Threshold Selection Method from Gray-Level Histograms journal, January 1979

Porosity and pore size distribution of different wood types as determined by mercury intrusion porosimetry journal, November 2010

Comparison of changes in micropores and mesopores in the wood cell walls of sapwood and heartwood journal, June 2015

Secondary comminution of wood pellets in power plant and laboratory-scale mills journal, June 2017

One way of representing the size and shape of biomass particles in combustion modeling journal, October 2017

Reduction of Tar and Soot Formation from Entrained-Flow Gasification of Woody Biomass by Alkali Impregnation journal, April 2017

Co-gasification of black liquor and pyrolysis oil at high temperature: Part 2. Fuel conversion journal, June 2017

Categorization of tars from fast pyrolysis of pure lignocellulosic compounds at high temperature journal, October 2019

High-throughput characterization of sediment organic matter by pyrolysis–gas chromatography/mass spectrometry and multivariate curve resolution: A promising analytical tool in (paleo)limnology journal, June 2015

Multivariate curve resolution provides a high-throughput data processing pipeline for pyrolysis-gas chromatography/mass spectrometry journal, May 2012

Effect of coal rank on structure and dielectric properties of chars journal, August 2015

Extraction of lignin from wood with supercritical alcohols journal, December 1989

The relationship between fiber-porosity and cellulose digestibility in steam-explodedPinus radiata journal, April 1988

X-ray computed microtomography and 2D image analysis for morphological characterization of short lignocellulosic fibers raw materials: A benchmark survey journal, September 2015

New approaches to measuring biochar density and porosity journal, July 2014

Mercury intrusion porosimetry in pulp and paper technology journal, December 2005

Investigations of the pore-size distribution of wood in the dry and wet state by means of mercury intrusion porosimetry journal, September 2014

Bestimmung der Porengrößenverteilung in Holz mit dem Quecksilber-Porosimeter journal, June 1974

Beitrag zur Porositätsanalyse von Holz mit dem Quecksilber-Porosimeter journal, August 1979

Elektronenmikroskopische Untersuchungen über den Bau der Hoftüpfel journal, May 1952

Extractive profiles of different lodgepole pine (Pinus contorta) fractions grown under a direct seeding-based silvicultural regime journal, July 2014

Sterol composition and biosynthesis in sorghum: Importance to developmental regulation journal, January 1986

Free sterols, steryl esters, and lipid phosphorus in needles of scot's pine (Pinus sylvestris L.) journal, November 1991

Concentration gradients of free sterols, steryl esters and lipid phosphorus in the trunkwood of Scot's pine (Pinus sylvestris L.) journal, January 1987

Industrial Uses of Wood Char journal, August 1998

Development of TG measurements of intrinsic char combustion reactivity for industrial and research purposes journal, September 1998

Potassium and soot interaction in fast biomass pyrolysis at high temperatures journal, August 2018

Complex permittivities and dielectric relaxation of granular activated carbons at microwave frequencies between 0.2 and 26 GHz journal, January 2003

Dielectric Properties of Biomass/Biochar Mixtures at Microwave Frequencies journal, April 2017

FT-i.r. analysis of coal journal, July 1988

The relation between the adsorption characteristics of polar organic compounds (alcohols and acids) and their orientation polarization on activated carbon journal, January 1981

Dielectric characterization of coals journal, March 2003

Effect of maleic anhydride on dielectric properties of natural fiber composite journal, April 2014

Oil palm fiber (OPF) and its composites: A review journal, January 2011

Dielectric Properties of Typical Australian Wood-Based Biomass Materials at Microwave Frequency journal, July 2010

Microwave and slow pyrolysis biochar—Comparison of physical and functional properties journal, March 2013

Hydrothermal carbonization of anaerobically digested maize silage journal, October 2011

From olive waste to solid biofuel through hydrothermal carbonisation: The role of temperature and solid load on secondary char formation and hydrochar energy properties journal, March 2017

Rapid estimation of the manufacturing cost of extracts obtained by supercritical fluid extraction journal, March 2005

Supercritical fluid extraction of vegetable matrices: Applications, trends and future perspectives of a convincing green technology journal, August 2014

Economic Assessment of Supercritical CO2 Extraction of Waxes as Part of a Maize Stover Biorefinery journal, July 2015

Toward an integrated straw-based biorefinery journal, January 2007

Valorization of spruce needle waste via supercritical extraction of waxes and facile isolation of nonacosan-10-ol journal, January 2018

Antimicrobial and Antioxidant Compounds in the Nonvolatile Fraction of Expressed Orange Essential Oil journal, August 1999

Isopimaric acid fromPinus nigra shows activity against multidrug-resistant and EMRSA strains ofStaphylococcus aureus journal, January 2005

Anti-inflammatory activity of abietic acid, a diterpene isolated from Pimenta racemosa var. grissea journal, February 2010

Study of diabietic acid as matrix forming material journal, June 1996

Study of the biodegradation and in vivo biocompatibility of novel biomaterials journal, September 2003

Phytosterols as anticancer compounds journal, February 2007

Title: The effect of wood composition and supercritical CO₂ extraction on charcoal production in ferroalloy industries

Impact of supercritical extraction on solid fuel wood pellet properties and off-gassing during storage
journal, January 2016

Commercial uses of fatty acids
journal, November 1952

Polyunsaturated fatty acids, part 1: Occurrence, biological activities and applications
journal, October 1997

Production of biodiesel fuel from tall oil fatty acids via high temperature methanol reaction
journal, November 2011

Characterization and reactivity of charcoal from high temperature pyrolysis (800–1600 °C)
journal, January 2019

A study of densified biochar as carbon source in the silicon and ferrosilicon production
journal, August 2019

Characterization of renewable reductants and charcoal-based pellets for the use in ferroalloy industries
journal, January 2019

The effect of feedstock origin and temperature on the structure and reactivity of char from pyrolysis at 1300–2800 °C
journal, January 2019

Supercritical fluid extraction (SFE) as an effective tool in reducing auto-oxidation of dried pine sawdust for power generation
journal, January 2012

Use of green chemical technologies in an integrated biorefinery
journal, January 2011

Economic analysis of rosemary, fennel and anise essential oils obtained by supercritical fluid extraction
journal, January 2007

Green Extraction of Natural Products: Concept and Principles
journal, July 2012

Hydrothermal processing, as an alternative for upgrading agriculture residues and marine biomass according to the biorefinery concept: A review
journal, May 2013

Generation, Capture, and Utilization of Industrial Carbon Dioxide
journal, January 2010

Identification, quantification and Chrastil modelling of wheat straw wax extraction using supercritical carbon dioxide
journal, March 2014

Supercritical fluids: technology and application to food processing
journal, March 2005

Separation of Biomass Pyrolysis Oil by Supercritical CO2 Extraction
journal, January 2010

Novel Integrated Biorefinery for Olive Mill Waste Management: Utilization of Secondary Waste for Water Treatment
journal, November 2016

An integrated biorefinery concept for olive mill waste management: supercritical CO₂ extraction and energy recovery
journal, January 2015

Prediction ofPinus sylvestrisclear-wood properties using NIR spectroscopy and biorthogonal partial least squares regression
journal, July 2008

Chemical forms of ash-forming elements in woody biomass fuels
journal, February 2010

Influence of Extractives on the Analysis of Herbaceous Biomass ^†
journal, February 1997

Charcoal from agricultural residues as alternative reducing agent in metal recycling
journal, April 2012

Analysis of optimal temperature, pressure and binder quantity for the production of biocarbon pellet to be used as a substitute for coke
journal, December 2019

A 3D in-situ investigation of the deformation in compressive loading in the thickness direction of cellulose fiber mats
journal, August 2015

3D micro-scale deformations of wood in bending: Synchrotron radiation μCT data analyzed with digital volume correlation
journal, December 2008

Full Three-Dimensional Strain Measurements on Wood Exposed to Three-Point Bending: Analysis by Use of Digital Volume Correlation Applied to Synchrotron Radiation Micro-Computed Tomography Image Data
journal, February 2010

Application of X-ray microtomography for the characterisation of hollow polymer-stabilised spray dried amorphous dispersion particles
journal, August 2016

A Threshold Selection Method from Gray-Level Histograms
journal, January 1979

Porosity and pore size distribution of different wood types as determined by mercury intrusion porosimetry
journal, November 2010

Comparison of changes in micropores and mesopores in the wood cell walls of sapwood and heartwood
journal, June 2015

Secondary comminution of wood pellets in power plant and laboratory-scale mills
journal, June 2017

One way of representing the size and shape of biomass particles in combustion modeling
journal, October 2017

Reduction of Tar and Soot Formation from Entrained-Flow Gasification of Woody Biomass by Alkali Impregnation
journal, April 2017

Co-gasification of black liquor and pyrolysis oil at high temperature: Part 2. Fuel conversion
journal, June 2017

Categorization of tars from fast pyrolysis of pure lignocellulosic compounds at high temperature
journal, October 2019

High-throughput characterization of sediment organic matter by pyrolysis–gas chromatography/mass spectrometry and multivariate curve resolution: A promising analytical tool in (paleo)limnology
journal, June 2015

Multivariate curve resolution provides a high-throughput data processing pipeline for pyrolysis-gas chromatography/mass spectrometry
journal, May 2012

Effect of coal rank on structure and dielectric properties of chars
journal, August 2015

Extraction of lignin from wood with supercritical alcohols
journal, December 1989

The relationship between fiber-porosity and cellulose digestibility in steam-explodedPinus radiata
journal, April 1988

X-ray computed microtomography and 2D image analysis for morphological characterization of short lignocellulosic fibers raw materials: A benchmark survey
journal, September 2015

New approaches to measuring biochar density and porosity
journal, July 2014

Mercury intrusion porosimetry in pulp and paper technology
journal, December 2005

Investigations of the pore-size distribution of wood in the dry and wet state by means of mercury intrusion porosimetry
journal, September 2014

Bestimmung der Porengrößenverteilung in Holz mit dem Quecksilber-Porosimeter
journal, June 1974

Beitrag zur Porositätsanalyse von Holz mit dem Quecksilber-Porosimeter
journal, August 1979

Elektronenmikroskopische Untersuchungen über den Bau der Hoftüpfel
journal, May 1952

Extractive profiles of different lodgepole pine (Pinus contorta) fractions grown under a direct seeding-based silvicultural regime
journal, July 2014

Sterol composition and biosynthesis in sorghum: Importance to developmental regulation
journal, January 1986

Free sterols, steryl esters, and lipid phosphorus in needles of scot's pine (Pinus sylvestris L.)
journal, November 1991

Concentration gradients of free sterols, steryl esters and lipid phosphorus in the trunkwood of Scot's pine (Pinus sylvestris L.)
journal, January 1987

Industrial Uses of Wood Char
journal, August 1998

Development of TG measurements of intrinsic char combustion reactivity for industrial and research purposes
journal, September 1998

Potassium and soot interaction in fast biomass pyrolysis at high temperatures
journal, August 2018

Complex permittivities and dielectric relaxation of granular activated carbons at microwave frequencies between 0.2 and 26 GHz
journal, January 2003

Dielectric Properties of Biomass/Biochar Mixtures at Microwave Frequencies
journal, April 2017

FT-i.r. analysis of coal
journal, July 1988

The relation between the adsorption characteristics of polar organic compounds (alcohols and acids) and their orientation polarization on activated carbon
journal, January 1981

Dielectric characterization of coals
journal, March 2003

Effect of maleic anhydride on dielectric properties of natural fiber composite
journal, April 2014

Oil palm fiber (OPF) and its composites: A review
journal, January 2011

Dielectric Properties of Typical Australian Wood-Based Biomass Materials at Microwave Frequency
journal, July 2010

Microwave and slow pyrolysis biochar—Comparison of physical and functional properties
journal, March 2013

Hydrothermal carbonization of anaerobically digested maize silage
journal, October 2011

From olive waste to solid biofuel through hydrothermal carbonisation: The role of temperature and solid load on secondary char formation and hydrochar energy properties
journal, March 2017

Rapid estimation of the manufacturing cost of extracts obtained by supercritical fluid extraction
journal, March 2005

Supercritical fluid extraction of vegetable matrices: Applications, trends and future perspectives of a convincing green technology
journal, August 2014

Economic Assessment of Supercritical CO2 Extraction of Waxes as Part of a Maize Stover Biorefinery
journal, July 2015

Toward an integrated straw-based biorefinery
journal, January 2007

Valorization of spruce needle waste via supercritical extraction of waxes and facile isolation of nonacosan-10-ol
journal, January 2018

Antimicrobial and Antioxidant Compounds in the Nonvolatile Fraction of Expressed Orange Essential Oil
journal, August 1999

Isopimaric acid fromPinus nigra shows activity against multidrug-resistant and EMRSA strains ofStaphylococcus aureus
journal, January 2005

Anti-inflammatory activity of abietic acid, a diterpene isolated from Pimenta racemosa var. grissea
journal, February 2010

Study of diabietic acid as matrix forming material
journal, June 1996

Study of the biodegradation and in vivo biocompatibility of novel biomaterials
journal, September 2003

Phytosterols as anticancer compounds
journal, February 2007

Charcoal as an Alternative Reductant in Ferroalloy Production: A Review
journal, November 2020