Architectural Stabilization of a Gold(III) Catalyst in Metal-Organic Frameworks
Abstract
Unimolecular decomposition pathways are challenging to address in transition-metal catalysis and have previously not been suppressed via incorporation into a solid support. Two robust metal-organic frameworks (IRMOF-10 and bio-MOF-100) are used for the architectural stabilization of a structurally well-defined gold(III) catalyst. The inherent rigidity of these materials is utilized to preclude a unimolecular decomposition pathway—reductive elimination. Through this architectural stabilization strategy, decomposition of the incorporated gold(III) catalyst in the metal-organic frameworks is not observed; in contrast, the homogeneous analog is prone to decomposition in solution. Finally, stabilization of the catalyst in these metal-organic frameworks precludes leaching and enables recyclability, which is crucial for productive heterogeneous catalysis.
- Authors:
-
- Univ. of California, Berkeley, CA (United States)
- Univ. of California, Berkeley, CA (United States); Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States); Kavli Energy NanoSciences Institute at Berkeley, Berkeley, CA (United States)
- Univ. of California, Berkeley, CA (United States); Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)
- Publication Date:
- Research Org.:
- Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC); National Institutes of Health (NIH); National Science Foundation (NSF); Ministry of Economic Affairs and Digital Transformation of Spain (MINECO); King Abdulaziz City for Science and Technology
- OSTI Identifier:
- 1633252
- Grant/Contract Number:
- AC02-05CH11231
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Chem
- Additional Journal Information:
- Journal Volume: 6; Journal Issue: 1; Journal ID: ISSN 2451-9294
- Publisher:
- Cell Press, Elsevier
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
Citation Formats
Lee, John S., Kapustin, Eugene A., Pei, Xiaokun, Llopis, Sebastián, Yaghi, Omar M., and Toste, F. Dean. Architectural Stabilization of a Gold(III) Catalyst in Metal-Organic Frameworks. United States: N. p., 2019.
Web. doi:10.1016/j.chempr.2019.10.022.
Lee, John S., Kapustin, Eugene A., Pei, Xiaokun, Llopis, Sebastián, Yaghi, Omar M., & Toste, F. Dean. Architectural Stabilization of a Gold(III) Catalyst in Metal-Organic Frameworks. United States. https://doi.org/10.1016/j.chempr.2019.10.022
Lee, John S., Kapustin, Eugene A., Pei, Xiaokun, Llopis, Sebastián, Yaghi, Omar M., and Toste, F. Dean. Mon .
"Architectural Stabilization of a Gold(III) Catalyst in Metal-Organic Frameworks". United States. https://doi.org/10.1016/j.chempr.2019.10.022. https://www.osti.gov/servlets/purl/1633252.
@article{osti_1633252,
title = {Architectural Stabilization of a Gold(III) Catalyst in Metal-Organic Frameworks},
author = {Lee, John S. and Kapustin, Eugene A. and Pei, Xiaokun and Llopis, Sebastián and Yaghi, Omar M. and Toste, F. Dean},
abstractNote = {Unimolecular decomposition pathways are challenging to address in transition-metal catalysis and have previously not been suppressed via incorporation into a solid support. Two robust metal-organic frameworks (IRMOF-10 and bio-MOF-100) are used for the architectural stabilization of a structurally well-defined gold(III) catalyst. The inherent rigidity of these materials is utilized to preclude a unimolecular decomposition pathway—reductive elimination. Through this architectural stabilization strategy, decomposition of the incorporated gold(III) catalyst in the metal-organic frameworks is not observed; in contrast, the homogeneous analog is prone to decomposition in solution. Finally, stabilization of the catalyst in these metal-organic frameworks precludes leaching and enables recyclability, which is crucial for productive heterogeneous catalysis.},
doi = {10.1016/j.chempr.2019.10.022},
journal = {Chem},
number = 1,
volume = 6,
place = {United States},
year = {Mon Nov 25 00:00:00 EST 2019},
month = {Mon Nov 25 00:00:00 EST 2019}
}
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