Rheological behavior of neat and carbon fiber-reinforced poly(ether ketone ketone) for extrusion deposition additive manufacturing
Abstract
To develop new materials for extrusion additive manufacturing (AM) systems, a fundamental understanding of rheological properties is essential to correlate the effect of processing on material structure and its properties. In this work, the rheological properties of five different grades of neat and carbon fiber (CF)-reinforced poly(ether ketone ketone) are reported. Rheological properties are essential to understand the effect of reinforcing fibers and AM process parameters such as time, temperature, environment, and shear rate on flow behavior during processing. Small-amplitude oscillatory shear tests and steady shear tests indicated neat grades to exhibit less increase in viscosity over time when processed in air than the CF-filled grades. The filled grades showed greater shear thinning and lower sensitivity to temperature. Altogether, this rheological analysis provides a broad framework for determining appropriate processing conditions for extrusion deposition AM of such high-temperature polymer systems.
- Authors:
-
[1];
[2];
[2];
[3];
- Oak Ridge National Lab. (ORNL), Knoxville, TN (United States); Univ. of Tennessee, Knoxville, TN (United States)
- Oak Ridge National Lab. (ORNL), Knoxville, TN (United States)
- Oak Ridge National Lab. (ORNL), Knoxville, TN (United States); Univ. of Tennessee, Knoxville, TN (United States); Purdue Univ., West Lafayette, IN (United States)
- Publication Date:
- Research Org.:
- Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
- Sponsoring Org.:
- USDOE Office of Energy Efficiency and Renewable Energy (EERE)
- OSTI Identifier:
- 1633176
- Grant/Contract Number:
- AC05-00OR22725
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Polymer Engineering and Science
- Additional Journal Information:
- Journal Volume: 60; Journal Issue: 5; Journal ID: ISSN 0032-3888
- Publisher:
- Wiley
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 36 MATERIALS SCIENCE
Citation Formats
Kishore, Vidya, Ajinjeru, Christine, Hassen, Ahmed A., Lindahl, John, Kunc, Vlastimil, and Duty, Chad. Rheological behavior of neat and carbon fiber-reinforced poly(ether ketone ketone) for extrusion deposition additive manufacturing. United States: N. p., 2020.
Web. doi:10.1002/pen.25362.
Kishore, Vidya, Ajinjeru, Christine, Hassen, Ahmed A., Lindahl, John, Kunc, Vlastimil, & Duty, Chad. Rheological behavior of neat and carbon fiber-reinforced poly(ether ketone ketone) for extrusion deposition additive manufacturing. United States. https://doi.org/10.1002/pen.25362
Kishore, Vidya, Ajinjeru, Christine, Hassen, Ahmed A., Lindahl, John, Kunc, Vlastimil, and Duty, Chad. Fri .
"Rheological behavior of neat and carbon fiber-reinforced poly(ether ketone ketone) for extrusion deposition additive manufacturing". United States. https://doi.org/10.1002/pen.25362. https://www.osti.gov/servlets/purl/1633176.
@article{osti_1633176,
title = {Rheological behavior of neat and carbon fiber-reinforced poly(ether ketone ketone) for extrusion deposition additive manufacturing},
author = {Kishore, Vidya and Ajinjeru, Christine and Hassen, Ahmed A. and Lindahl, John and Kunc, Vlastimil and Duty, Chad},
abstractNote = {To develop new materials for extrusion additive manufacturing (AM) systems, a fundamental understanding of rheological properties is essential to correlate the effect of processing on material structure and its properties. In this work, the rheological properties of five different grades of neat and carbon fiber (CF)-reinforced poly(ether ketone ketone) are reported. Rheological properties are essential to understand the effect of reinforcing fibers and AM process parameters such as time, temperature, environment, and shear rate on flow behavior during processing. Small-amplitude oscillatory shear tests and steady shear tests indicated neat grades to exhibit less increase in viscosity over time when processed in air than the CF-filled grades. The filled grades showed greater shear thinning and lower sensitivity to temperature. Altogether, this rheological analysis provides a broad framework for determining appropriate processing conditions for extrusion deposition AM of such high-temperature polymer systems.},
doi = {10.1002/pen.25362},
journal = {Polymer Engineering and Science},
number = 5,
volume = 60,
place = {United States},
year = {Fri Mar 13 00:00:00 EDT 2020},
month = {Fri Mar 13 00:00:00 EDT 2020}
}
Free Publicly Available Full Text
Publisher's Version of Record
Other availability
Search WorldCat to find libraries that may hold this journal
Cited by: 6 works
Citation information provided by
Web of Science
Web of Science
Save to My Library
You must Sign In or Create an Account in order to save documents to your library.
Works referenced in this record:
Thermoplastic composites reinforced with long fiber thermotropic liquid crystalline polymers for fused deposition modeling: Thermoplastic Composites Reinforced With Long Fiber TLCPs
journal, August 1998
- Gray, R. W.; Baird, D. G.; Bøhn, J. H.
- Polymer Composites, Vol. 19, Issue 4
Rheological behavior of multiwalled carbon nanotube/polycarbonate composites
journal, May 2002
- Pötschke, Petra; Fornes, T. D.; Paul, D. R.
- Polymer, Vol. 43, Issue 11
Fused deposition modeling with polypropylene
journal, October 2015
- Carneiro, O. S.; Silva, A. F.; Gomes, R.
- Materials & Design, Vol. 83
Isothermal crystallization kinetics of poly(ether ketone ketone) and its carbon-fibre-reinforced composites
journal, January 1991
- Hsiao, Benjamin S.; Chang, Ike Y.; Sauer, Bryan B.
- Polymer, Vol. 32, Issue 15
Glass transition characteristics of poly(aryl ether ketone ketone) and its copolymers
journal, May 1996
- Krishnaswamy, R. K.; Kalika, D. S.
- Polymer, Vol. 37, Issue 10
Expanding the applicability of FDM-type technologies through materials development
journal, March 2015
- Roberson, David; Shemelya, Corey M.; MacDonald, Eric
- Rapid Prototyping Journal, Vol. 21, Issue 2
Determination of melt processing conditions for high performance amorphous thermoplastics for large format additive manufacturing
journal, May 2018
- Ajinjeru, Christine; Kishore, Vidya; Liu, Peng
- Additive Manufacturing, Vol. 21
Structure and mechanical behavior of Big Area Additive Manufacturing (BAAM) materials
journal, January 2017
- Duty, Chad E.; Kunc, Vlastimil; Compton, Brett
- Rapid Prototyping Journal, Vol. 23, Issue 1
Structure, crystallization and morphology of poly (aryl ether ketone ketone)
journal, January 1992
- Gardner, KennCorwin H.; Hsiao, Benjamin S.; Matheson, Robert R.
- Polymer, Vol. 33, Issue 12
Rheological and thermal behaviors of commercial poly(aryletherketone)s
journal, September 2012
- White, Kevin L.; Jin, Lin; Ferrer, Nangelie
- Polymer Engineering & Science, Vol. 53, Issue 3
Infrared preheating to improve interlayer strength of big area additive manufacturing (BAAM) components
journal, March 2017
- Kishore, Vidya; Ajinjeru, Christine; Nycz, Andrzej
- Additive Manufacturing, Vol. 14
Highly oriented carbon fiber–polymer composites via additive manufacturing
journal, December 2014
- Tekinalp, Halil L.; Kunc, Vlastimil; Velez-Garcia, Gregorio M.
- Composites Science and Technology, Vol. 105
Polyetheretherketone (PEEK): Processing-structure and properties studies for a matrix in high performance composites
journal, June 1986
- Seferis, James C.
- Polymer Composites, Vol. 7, Issue 3
Rheological analysis of vapor-grown carbon nanofiber-reinforced polyethylene composites
journal, January 2004
- Lozano, Karen; Yang, Shuying; Zeng, Qiang
- Journal of Applied Polymer Science, Vol. 93, Issue 1
Thermal degradation of poly(aryl-ether-ether-ketone): Experimental evaluation of crosslinking reactions
journal, November 1990
- Day, M.; Sally, D.; Wiles, D. M.
- Journal of Applied Polymer Science, Vol. 40, Issue 910
The influence of dynamic rheological properties on carbon fiber-reinforced polyetherimide for large-scale extrusion-based additive manufacturing
journal, August 2018
- Ajinjeru, Christine; Kishore, Vidya; Lindahl, John
- The International Journal of Advanced Manufacturing Technology, Vol. 99, Issue 1-4
Recent Development in Thermoplastic Composites: A Review of Matrix Systems and Processing Methods
journal, July 1988
- Chang, I. Y.; Lees, J. K.
- Journal of Thermoplastic Composite Materials, Vol. 1, Issue 3
Thermal stability and crystallization of poly(aryl ether ether ketone)
journal, January 1991
- Jonas, A.; Legras, R.
- Polymer, Vol. 32, Issue 15
Rheology of fiber filled polymer melts: Role of fiber-fiber interactions and polymer-fiber coupling
journal, January 2005
- Guo, Rong; Azaiez, Jalel; Bellehumeur, Celine
- Polymer Engineering & Science, Vol. 45, Issue 3
Investigation on the dynamic melt rheological properties of polypropylene/wood flour composites
journal, April 2009
- Azizi, H.; Ghasemi, I.
- Polymer Composites, Vol. 30, Issue 4
A study on nanofiber-reinforced thermoplastic composites (II): Investigation of the mixing rheology and conduction properties
journal, January 2001
- Lozano, K.; Bonilla-Rios, J.; Barrera, E. V.
- Journal of Applied Polymer Science, Vol. 80, Issue 8