Thiocyanate complexes of the lanthanides, Am and Cm

Wilson, Richard E.; Carter, Tyler J.; Autillo, Matthieu; Stegman, Samantha

doi:10.1039/c9cc07612c

Title: Thiocyanate complexes of the lanthanides, Am and Cm

Abstract

In this work, the synthesis and single crystal structures of Am(III) and Cm(III) thiocyanate complexes are reported along with an isostructural series of lanthanide thiocyanate complexes. Because the complexes are isostructural, a comparative study of the metal–thiocyanate bonds was conducted using Raman spectroscopy indicating very similar and electrostatic metal–ligand interactions.

Authors:

^[1]; Carter, Tyler J. ^[1]; Autillo, Matthieu ^[1]; Stegman, Samantha ^[1]

Argonne National Lab. (ANL), Lemont, IL (United States)

Publication Date:: Tue Feb 04 00:00:00 EST 2020

Research Org.:: Argonne National Laboratory (ANL), Argonne, IL (United States)

Sponsoring Org.:: USDOE Office of Science (SC), Basic Energy Sciences (BES). Chemical Sciences, Geosciences & Biosciences Division

OSTI Identifier:: 1633072

Alternate Identifier(s):: OSTI ID: 1597138

Grant/Contract Number:: AC02-06CH11357

Resource Type:: Accepted Manuscript

Journal Name:: ChemComm

Additional Journal Information:: Journal Volume: 56; Journal Issue: 17; Journal ID: ISSN 1359-7345

Publisher:: Royal Society of Chemistry

Country of Publication:: United States

Language:: English

Subject:: 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY

Citation Formats


                    Wilson, Richard E., Carter, Tyler J., Autillo, Matthieu, and Stegman, Samantha. Thiocyanate complexes of the lanthanides, Am and Cm.  United States: N. p., 2020. 
Web.  doi:10.1039/c9cc07612c.

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                    Wilson, Richard E., Carter, Tyler J., Autillo, Matthieu, & Stegman, Samantha. Thiocyanate complexes of the lanthanides, Am and Cm.  United States.  https://doi.org/10.1039/c9cc07612c

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                    Wilson, Richard E., Carter, Tyler J., Autillo, Matthieu, and Stegman, Samantha. Tue .  
"Thiocyanate complexes of the lanthanides, Am and Cm".  United States.  https://doi.org/10.1039/c9cc07612c.  https://www.osti.gov/servlets/purl/1633072.

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@article{osti_1633072,

  title        = {Thiocyanate complexes of the lanthanides, Am and Cm},

  author       = {Wilson, Richard E. and Carter, Tyler J. and Autillo, Matthieu and Stegman, Samantha},

  abstractNote = {In this work, the synthesis and single crystal structures of Am(III) and Cm(III) thiocyanate complexes are reported along with an isostructural series of lanthanide thiocyanate complexes. Because the complexes are isostructural, a comparative study of the metal–thiocyanate bonds was conducted using Raman spectroscopy indicating very similar and electrostatic metal–ligand interactions.},

  doi          = {10.1039/c9cc07612c},

  journal      = {ChemComm},

  number       = 17,

  volume       = 56,

  place        = {United States},

  year         = {Tue Feb 04 00:00:00 EST 2020},

  month        = {Tue Feb 04 00:00:00 EST 2020}

}

Copy to clipboard

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https://doi.org/10.1039/c9cc07612c

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Works referenced in this record:

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Ellis, Ross J.; Meridiano, Yannick; Muller, Julie
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Title: Thiocyanate complexes of the lanthanides, Am and Cm

Abstract

Citation Formats

Thiocyanate Complexes of Uranium in Multiple Oxidation States: A Combined Structural, Magnetic, Spectroscopic, Spectroelectrochemical, and Theoretical Study journal, July 2014

Comparing the 2,2′-Biphenylenedithiophosphinate Binding of Americium with Neodymium and Europium journal, September 2016

Azide interaction with 4f and 5f ions in aqueous solutions. 1. Trivalent ions journal, August 1983

The Curium Aqua Ion journal, April 2007

Ab Initio Study of Covalency in the Ground versus Core-Excited States and X-ray Absorption Spectra of Actinide Complexes journal, September 2018

The Synthesis, and the Crystal and Molecular Structures of Tetraethylammonium [Aquaheptakis(thiocyanato)lanthanoidate(III)], [(C 2 H 5 ) 4 N] 4 [M(SCN) 7 (H 2 O)], (M=La, Ce, Pr; Nd, Dy, Er): The Complexes in a Cubic Octa-Coordination Geometry journal, August 1988

New Approach to Separation of Trivalent Actinide Elements from Lanthanide Elements. Selective Liquid-Liquid Extraction with Tricaprylmethylammonium Thiocyanate. journal, October 1964

Revised effective ionic radii and systematic studies of interatomic distances in halides and chalcogenides journal, September 1976

The role of the 5f valence orbitals of early actinides in chemical bonding journal, July 2017

Determining Relative f and d Orbital Contributions to M–Cl Covalency in MCl 6 2– (M = Ti, Zr, Hf, U) and UOCl 5 – Using Cl K-Edge X-ray Absorption Spectroscopy and Time-Dependent Density Functional Theory journal, March 2012

The Raman spectrum of [U(NCS)8]4? and configuration of the ion in solution journal, January 1986

Extraction Selectivity of a Quaternary Alkylammonium Salt for Trivalent Actinides over Trivalent Lanthanides: Does Extractant Aggregation Play a Role? journal, May 2017

Complexation and Extraction of Trivalent Actinides and Lanthanides by Triazinylpyridine N -Donor Ligands journal, October 2012

Phase Transitions in Tetramethylammonium Hexachlorometalate Compounds (TMA) 2 MCl 6 (M = U, Np, Pt, Sn, Hf, Zr): Phase Transitions in Tetramethylammonium Hexachlorometalate Compounds (TMA) 2 MCl 6 (M = U, Np, Pt, Sn, Hf, Zr) journal, November 2017

Complexation-Induced Supramolecular Assembly Drives Metal-Ion Extraction journal, August 2014

Complexing of trivalent actinide ions by thiocyanate journal, May 1974

Structural Variability of 4f and 5f Thiocyanate Complexes and Dissociation of Uranium(III)–Thiocyanate Bonds with Increased Ionicity journal, November 2017

Infrared spectra of complexes of the thiocyanate and related ions journal, August 1971

Covalency in f-element complexes journal, January 2013

Liquid anion exchange of thiocyanate-nitrate actinide and lanthanide complexes journal, October 1973

Quantification of f-element covalency through analysis of the electron density: insights from simulation journal, January 2017

Covalency in Americium(III) Hexachloride journal, June 2017

The Structures and Optical Spectra of Hydrated Transplutonium Ions in the Solid State and in Solution journal, January 2007

An Ion-exchange Study of Possible Hybridized 5f Bonding in the Actinides 1 journal, March 1954

Isolation of Transplutonium Elements by Tertiary Amine Extraction journal, November 1963

Coordination Chemistry of Homoleptic Actinide(IV)-Thiocyanate Complexes journal, September 2015

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Thiocyanate complexes of some trivalent lanthanide and actinide elements journal, June 1965

Comparison of Covalency in the Complexes of Trivalent Actinide and Lanthanide Cations journal, August 2002

Comparing the 2,2′-Biphenylenedithiophosphinate Binding of Americium with Neodymium and Europium journal, September 2016

Complexation-Induced Supramolecular Assembly Drives Metal-Ion Extraction journal, August 2014

The Structures and Optical Spectra of Hydrated Transplutonium Ions in the Solid State and in Solution. journal, April 2007

The role of the 5f valence orbitals of early actinides in chemical bonding text, January 2017

The Structures and Optical Spectra of Hydrated Transplutonium Ions in the Solid State and in Solution journal, January 2007

Thiocyanate Complexes of Uranium in Multiple Oxidation States: A Combined Structural, Magnetic, Spectroscopic, Spectroelectrochemical, and Theoretical Study
journal, July 2014

Comparing the 2,2′-Biphenylenedithiophosphinate Binding of Americium with Neodymium and Europium
journal, September 2016

Azide interaction with 4f and 5f ions in aqueous solutions. 1. Trivalent ions
journal, August 1983

The Curium Aqua Ion
journal, April 2007

Ab Initio Study of Covalency in the Ground versus Core-Excited States and X-ray Absorption Spectra of Actinide Complexes
journal, September 2018

The Synthesis, and the Crystal and Molecular Structures of Tetraethylammonium [Aquaheptakis(thiocyanato)lanthanoidate(III)], [(C ₂ H ₅ ) ₄ N] ₄ [M(SCN) ₇ (H ₂ O)], (M=La, Ce, Pr; Nd, Dy, Er): The Complexes in a Cubic Octa-Coordination Geometry
journal, August 1988

New Approach to Separation of Trivalent Actinide Elements from Lanthanide Elements. Selective Liquid-Liquid Extraction with Tricaprylmethylammonium Thiocyanate.
journal, October 1964

Revised effective ionic radii and systematic studies of interatomic distances in halides and chalcogenides
journal, September 1976

The role of the 5f valence orbitals of early actinides in chemical bonding
journal, July 2017

Determining Relative f and d Orbital Contributions to M–Cl Covalency in MCl ₆ ^2– (M = Ti, Zr, Hf, U) and UOCl ₅ ^– Using Cl K-Edge X-ray Absorption Spectroscopy and Time-Dependent Density Functional Theory
journal, March 2012

The Raman spectrum of [U(NCS)8]4? and configuration of the ion in solution
journal, January 1986

Extraction Selectivity of a Quaternary Alkylammonium Salt for Trivalent Actinides over Trivalent Lanthanides: Does Extractant Aggregation Play a Role?
journal, May 2017

Complexation and Extraction of Trivalent Actinides and Lanthanides by Triazinylpyridine N -Donor Ligands
journal, October 2012

Phase Transitions in Tetramethylammonium Hexachlorometalate Compounds (TMA) ₂ MCl ₆ (M = U, Np, Pt, Sn, Hf, Zr): Phase Transitions in Tetramethylammonium Hexachlorometalate Compounds (TMA) ₂ MCl ₆ (M = U, Np, Pt, Sn, Hf, Zr)
journal, November 2017

Complexation-Induced Supramolecular Assembly Drives Metal-Ion Extraction
journal, August 2014

Complexing of trivalent actinide ions by thiocyanate
journal, May 1974

Structural Variability of 4f and 5f Thiocyanate Complexes and Dissociation of Uranium(III)–Thiocyanate Bonds with Increased Ionicity
journal, November 2017

Infrared spectra of complexes of the thiocyanate and related ions
journal, August 1971

Covalency in f-element complexes
journal, January 2013

Liquid anion exchange of thiocyanate-nitrate actinide and lanthanide complexes
journal, October 1973

Quantification of f-element covalency through analysis of the electron density: insights from simulation
journal, January 2017

Covalency in Americium(III) Hexachloride
journal, June 2017

The Structures and Optical Spectra of Hydrated Transplutonium Ions in the Solid State and in Solution
journal, January 2007

An Ion-exchange Study of Possible Hybridized 5f Bonding in the Actinides ¹
journal, March 1954

Isolation of Transplutonium Elements by Tertiary Amine Extraction
journal, November 1963

Coordination Chemistry of Homoleptic Actinide(IV)-Thiocyanate Complexes
journal, September 2015

Ab Initio Ligand-Field Theory Analysis and Covalency Trends in Actinide and Lanthanide Free Ions and Octahedral Complexes
journal, July 2017

Am(III) AND Eu(III) EXTRACTION BY ALIQUAT-336 AND BENZYL SUBSTITUTED QUATERNARY AMMONIUM SALTS FROM NITRATE AND THIOCYANATE SOLUTIONS*
journal, July 1995

Thiocyanate complexes of some trivalent lanthanide and actinide elements
journal, June 1965

Comparison of Covalency in the Complexes of Trivalent Actinide and Lanthanide Cations
journal, August 2002

Comparing the 2,2′-Biphenylenedithiophosphinate Binding of Americium with Neodymium and Europium
journal, September 2016

Complexation-Induced Supramolecular Assembly Drives Metal-Ion Extraction
journal, August 2014

The Structures and Optical Spectra of Hydrated Transplutonium Ions in the Solid State and in Solution.
journal, April 2007

The role of the 5f valence orbitals of early actinides in chemical bonding
text, January 2017

The Structures and Optical Spectra of Hydrated Transplutonium Ions in the Solid State and in Solution
journal, January 2007