Specific ion effects at graphitic interfaces
Abstract
Improved understanding of aqueous solutions at graphitic interfaces is critical for energy storage and water desalination. However, many mechanistic details remain unclear, including how interfacial structure and response are dictated by intrinsic properties of solvated ions under applied voltage. In this work, we combine hybrid first-principles/continuum simulations with electrochemical measurements to investigate adsorption of several alkali-metal cations at the interface with graphene and within graphene slit-pores. We confirm that adsorption energy increases with ionic radius, while being highly dependent on the pore size. In addition, in contrast with conventional electrochemical models, we find that interfacial charge transfer contributes non-negligibly to this interaction and can be further enhanced by confinement. We conclude that the measured interfacial capacitance trends result from a complex interplay between voltage, confinement, and specific ion effects-including ion hydration and charge transfer.
- Authors:
-
- Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States)
- National Inst. of Advanced Industrial Science and Technology (AIST), Tsukuba (Japan)
- Publication Date:
- Research Org.:
- Lawrence Livermore National Laboratory (LLNL), Livermore, CA (United States)
- Sponsoring Org.:
- USDOE National Nuclear Security Administration (NNSA); USDOE Laboratory Directed Research and Development (LDRD) Program
- OSTI Identifier:
- 1633023
- Report Number(s):
- LLNL-JRNL-778780
Journal ID: ISSN 2041-1723; 968664
- Grant/Contract Number:
- AC52-07NA27344
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Nature Communications
- Additional Journal Information:
- Journal Volume: 10; Journal Issue: 1; Journal ID: ISSN 2041-1723
- Publisher:
- Nature Publishing Group
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 36 MATERIALS SCIENCE; Materials science; Energy storage; Electrochemistry; Graphene; Porous materials; Two-dimensional materials
Citation Formats
Zhan, Cheng, Cerón, Maira R., Hawks, Steven A., Otani, Minoru, Wood, Brandon C., Pham, Tuan Anh, Stadermann, Michael, and Campbell, Patrick G. Specific ion effects at graphitic interfaces. United States: N. p., 2019.
Web. doi:10.1038/s41467-019-12854-7.
Zhan, Cheng, Cerón, Maira R., Hawks, Steven A., Otani, Minoru, Wood, Brandon C., Pham, Tuan Anh, Stadermann, Michael, & Campbell, Patrick G. Specific ion effects at graphitic interfaces. United States. https://doi.org/10.1038/s41467-019-12854-7
Zhan, Cheng, Cerón, Maira R., Hawks, Steven A., Otani, Minoru, Wood, Brandon C., Pham, Tuan Anh, Stadermann, Michael, and Campbell, Patrick G. Thu .
"Specific ion effects at graphitic interfaces". United States. https://doi.org/10.1038/s41467-019-12854-7. https://www.osti.gov/servlets/purl/1633023.
@article{osti_1633023,
title = {Specific ion effects at graphitic interfaces},
author = {Zhan, Cheng and Cerón, Maira R. and Hawks, Steven A. and Otani, Minoru and Wood, Brandon C. and Pham, Tuan Anh and Stadermann, Michael and Campbell, Patrick G.},
abstractNote = {Improved understanding of aqueous solutions at graphitic interfaces is critical for energy storage and water desalination. However, many mechanistic details remain unclear, including how interfacial structure and response are dictated by intrinsic properties of solvated ions under applied voltage. In this work, we combine hybrid first-principles/continuum simulations with electrochemical measurements to investigate adsorption of several alkali-metal cations at the interface with graphene and within graphene slit-pores. We confirm that adsorption energy increases with ionic radius, while being highly dependent on the pore size. In addition, in contrast with conventional electrochemical models, we find that interfacial charge transfer contributes non-negligibly to this interaction and can be further enhanced by confinement. We conclude that the measured interfacial capacitance trends result from a complex interplay between voltage, confinement, and specific ion effects-including ion hydration and charge transfer.},
doi = {10.1038/s41467-019-12854-7},
journal = {Nature Communications},
number = 1,
volume = 10,
place = {United States},
year = {Thu Oct 24 00:00:00 EDT 2019},
month = {Thu Oct 24 00:00:00 EDT 2019}
}
Web of Science
Figures / Tables:
Works referenced in this record:
Molecular simulation study of temperature effect on ionic hydration in carbon nanotubes
journal, January 2008
- Shao, Qing; Huang, Liangliang; Zhou, Jian
- Physical Chemistry Chemical Physics, Vol. 10, Issue 14
Critical Knowledge Gaps in Mass Transport through Single-Digit Nanopores: A Review and Perspective
journal, May 2019
- Faucher, Samuel; Aluru, Narayana; Bazant, Martin Z.
- The Journal of Physical Chemistry C, Vol. 123, Issue 35
Electrolytic Transport in Modified Carbon Nanotubes
journal, October 2003
- Joseph, Sony; Mashl, R. Jay; Jakobsson, Eric
- Nano Letters, Vol. 3, Issue 10
Advanced carbon aerogels for energy applications
journal, January 2011
- Biener, Juergen; Stadermann, Michael; Suss, Matthew
- Energy & Environmental Science, Vol. 4, Issue 3, p. 656-667
QUANTUM ESPRESSO: a modular and open-source software project for quantum simulations of materials
journal, September 2009
- Giannozzi, Paolo; Baroni, Stefano; Bonini, Nicola
- Journal of Physics: Condensed Matter, Vol. 21, Issue 39, Article No. 395502
The Importance of Dehydration in Determining Ion Transport in Narrow Pores
journal, March 2012
- Richards, Laura A.; Schäfer, Andrea I.; Richards, Bryce S.
- Small, Vol. 8, Issue 11
Molecular dynamics simulations of the electric double layer capacitance of graphene electrodes in mono-valent aqueous electrolytes
journal, January 2016
- Jiang, Gengping; Cheng, Chi; Li, Dan
- Nano Research, Vol. 9, Issue 1
A grid-based Bader analysis algorithm without lattice bias
journal, January 2009
- Tang, W.; Sanville, E.; Henkelman, G.
- Journal of Physics: Condensed Matter, Vol. 21, Issue 8
Unraveling the potential and pore-size dependent capacitance of slit-shaped graphitic carbon pores in aqueous electrolytes
journal, January 2013
- Kalluri, R. K.; Biener, M. M.; Suss, M. E.
- Physical Chemistry Chemical Physics, Vol. 15, Issue 7
Water desalination via capacitive deionization: what is it and what can we expect from it?
journal, January 2015
- Suss, M. E.; Porada, S.; Sun, X.
- Energy & Environmental Science, Vol. 8, Issue 8
Materials for electrochemical capacitors
journal, November 2008
- Simon, Patrice; Gogotsi, Yury
- Nature Materials, Vol. 7, Issue 11
Two-Dimensional Transition Metal Carbides
journal, January 2012
- Naguib, Michael; Mashtalir, Olha; Carle, Joshua
- ACS Nano, Vol. 6, Issue 2
Faradaic reactions in capacitive deionization (CDI) - problems and possibilities: A review
journal, January 2018
- Zhang, Changyong; He, Di; Ma, Jinxing
- Water Research, Vol. 128
Carbons with narrow pore size distribution prepared by simultaneous carbonization and self-activation of tobacco stems and their application to supercapacitors
journal, January 2015
- Kleszyk, P.; Ratajczak, P.; Skowron, P.
- Carbon, Vol. 81
Negative dielectric constant of water confined in nanosheets
journal, February 2019
- Sugahara, Akira; Ando, Yasunobu; Kajiyama, Satoshi
- Nature Communications, Vol. 10, Issue 1
Using Ultramicroporous Carbon for the Selective Removal of Nitrate with Capacitive Deionization
journal, June 2019
- Hawks, Steven A.; Cerón, Maira R.; Oyarzun, Diego I.
- Environmental Science & Technology, Vol. 53, Issue 18
Translocation of Single-Stranded DNA Through Single-Walled Carbon Nanotubes
journal, December 2009
- Liu, H.; He, J.; Tang, J.
- Science, Vol. 327, Issue 5961
Origins and Implications of Interfacial Capacitance Enhancements in C 60 -Modified Graphene Supercapacitors
journal, October 2018
- Zhan, Cheng; Pham, Tuan Anh; Cerón, Maira R.
- ACS Applied Materials & Interfaces, Vol. 10, Issue 43
Capacitive desalination with flow-through electrodes
journal, January 2012
- Suss, Matthew E.; Baumann, Theodore F.; Bourcier, William L.
- Energy & Environmental Science, Vol. 5, Issue 11
Relation between the Ion Size and Pore Size for an Electric Double-Layer Capacitor
journal, March 2008
- Largeot, Celine; Portet, Cristelle; Chmiola, John
- Journal of the American Chemical Society, Vol. 130, Issue 9
Hybrid solvation models for bulk, interface, and membrane: Reference interaction site methods coupled with density functional theory
journal, September 2017
- Nishihara, S.; Otani, M.
- Physical Review B, Vol. 96, Issue 11
Salt concentration and charging velocity determine ion charge storage mechanism in nanoporous supercapacitors
journal, October 2018
- Prehal, C.; Koczwara, C.; Amenitsch, H.
- Nature Communications, Vol. 9, Issue 1
Improved modeling of electrified interfaces using the effective screening medium method
journal, October 2013
- Hamada, Ikutaro; Sugino, Osamu; Bonnet, Nicéphore
- Physical Review B, Vol. 88, Issue 15
First-principles calculations of charged surfaces and interfaces: A plane-wave nonrepeated slab approach
journal, March 2006
- Otani, M.; Sugino, O.
- Physical Review B, Vol. 73, Issue 11
Origin of Giant Ionic Currents in Carbon Nanotube Channels
journal, August 2011
- Pang, Pei; He, Jin; Park, Jae Hyun
- ACS Nano, Vol. 5, Issue 9
Development and Testing of the OPLS All-Atom Force Field on Conformational Energetics and Properties of Organic Liquids
journal, January 1996
- Jorgensen, William L.; Maxwell, David S.; Tirado-Rives, Julian
- Journal of the American Chemical Society, Vol. 118, Issue 45
Anomalous Increase in Carbon Capacitance at Pore Sizes Less Than 1 Nanometer
journal, September 2006
- Chmiola, J.
- Science, Vol. 313, Issue 5794
First-Principles Molecular Dynamics at a Constant Electrode Potential
journal, December 2012
- Bonnet, Nicéphore; Morishita, Tetsuya; Sugino, Osamu
- Physical Review Letters, Vol. 109, Issue 26
Capacitive Energy Storage in Nanostructured Carbon–Electrolyte Systems
journal, June 2012
- Simon, P.; Gogotsi, Y.
- Accounts of Chemical Research, Vol. 46, Issue 5
Aqueous NaCl Solutions within Charged Carbon-Slit Pores: Partition Coefficients and Density Distributions from Molecular Dynamics Simulations
journal, June 2011
- Kalluri, Raja Kirthi; Konatham, Deepthi; Striolo, Alberto
- The Journal of Physical Chemistry C, Vol. 115, Issue 28
Analysis of Lithium Insertion/Desorption Reaction at Interfaces between Graphite Electrodes and Electrolyte Solution Using Density Functional + Implicit Solvation Theory
journal, April 2018
- Haruyama, Jun; Ikeshoji, Tamio; Otani, Minoru
- The Journal of Physical Chemistry C, Vol. 122, Issue 18
Ion separation using a Y-junction carbon nanotube
journal, January 2006
- Park, Jae Hyun; Sinnott, Susan B.; Aluru, N. R.
- Nanotechnology, Vol. 17, Issue 3
Capacitance of Basal Plane and Edge-Oriented Highly Ordered Pyrolytic Graphite: Specific Ion Effects
journal, January 2019
- Iamprasertkun, Pawin; Hirunpinyopas, Wisit; Keerthi, Ashok
- The Journal of Physical Chemistry Letters, Vol. 10, Issue 3
Mechanism of ion adsorption to aqueous interfaces: Graphene/water vs. air/water
journal, August 2017
- McCaffrey, Debra L.; Nguyen, Son C.; Cox, Stephen J.
- Proceedings of the National Academy of Sciences, Vol. 114, Issue 51
Influences of ions and temperature on performance of carbon nano-particulates in supercapacitors with neutral aqueous electrolytes
journal, August 2014
- Chae, Jung Hoon; Chen, George Zheng
- Particuology, Vol. 15
Self-consistent description of a metal–water interface by the Kohn–Sham density functional theory and the three-dimensional reference interaction site model
journal, May 1999
- Kovalenko, Andriy; Hirata, Fumio
- The Journal of Chemical Physics, Vol. 110, Issue 20
Electrolytic transport through a synthetic nanometer-diameter pore
journal, July 2005
- Ho, C.; Qiao, R.; Heng, J. B.
- Proceedings of the National Academy of Sciences, Vol. 102, Issue 30
Molecular Friction-Induced Electroosmotic Phenomena in Thin Neutral Nanotubes
journal, June 2014
- Vuković, Lela; Vokac, Elizabeth; Král, Petr
- The Journal of Physical Chemistry Letters, Vol. 5, Issue 12
Kinetic-Dominated Charging Mechanism within Representative Aqueous Electrolyte-based Electric Double-Layer Capacitors
journal, July 2017
- Yang, Huachao; Yang, Jinyuan; Bo, Zheng
- The Journal of Physical Chemistry Letters, Vol. 8, Issue 15
Consistency of carbon nanopore characteristics derived from adsorption of simple gases and 2D-NLDFT models. Advantages of using adsorption isotherms of oxygen (O2) at 77 K
journal, April 2019
- Jagiello, Jacek; Kenvin, Jeffrey
- Journal of Colloid and Interface Science, Vol. 542
The OPLS [optimized potentials for liquid simulations] potential functions for proteins, energy minimizations for crystals of cyclic peptides and crambin
journal, March 1988
- Jorgensen, William L.; Tirado-Rives, Julian
- Journal of the American Chemical Society, Vol. 110, Issue 6
Effective Polarization in Pairwise Potentials at the Graphene–Electrolyte Interface
journal, January 2017
- Williams, Christopher D.; Dix, James; Troisi, Alessandro
- The Journal of Physical Chemistry Letters, Vol. 8, Issue 3
Van der Waals Density Functional for General Geometries
journal, June 2004
- Dion, M.; Rydberg, H.; Schröder, E.
- Physical Review Letters, Vol. 92, Issue 24
High surface area carbon aerogel monoliths with hierarchical porosity
journal, July 2008
- Baumann, Theodore F.; Worsley, Marcus A.; Han, T. Yong-Jin
- Journal of Non-Crystalline Solids, Vol. 354, Issue 29, p. 3513-3515
Dual gas analysis of microporous carbons using 2D-NLDFT heterogeneous surface model and combined adsorption data of N2 and CO2
journal, September 2015
- Jagiello, Jacek; Ania, Conchi; Parra, Jose B.
- Carbon, Vol. 91
Soft self-consistent pseudopotentials in a generalized eigenvalue formalism
journal, April 1990
- Vanderbilt, David
- Physical Review B, Vol. 41, Issue 11, p. 7892-7895
Connections Matter: On the Importance of Pore Percolation for Nanoporous Supercapacitors
journal, July 2019
- Vasilyev, Oleg A.; Kornyshev, Alexei A.; Kondrat, Svyatoslav
- ACS Applied Energy Materials, Vol. 2, Issue 8
Effect of Ions on the Structure of Water: Structure Making and Breaking
journal, March 2009
- Marcus, Yizhak
- Chemical Reviews, Vol. 109, Issue 3
Anomalous Hydration Shell Order of Na + and K + inside Carbon Nanotubes
journal, March 2009
- Shao, Qing; Zhou, Jian; Lu, Linghong
- Nano Letters, Vol. 9, Issue 3
Review on the science and technology of water desalination by capacitive deionization
journal, October 2013
- Porada, S.; Zhao, R.; van der Wal, A.
- Progress in Materials Science, Vol. 58, Issue 8
Metallic 1T phase MoS2 nanosheets as supercapacitor electrode materials
journal, March 2015
- Acerce, Muharrem; Voiry, Damien; Chhowalla, Manish
- Nature Nanotechnology, Vol. 10, Issue 4
Water desalination via capacitive deionization: what is it and what can we expect from it?
null, January 2015
- Suss, M. E.; Porada, S.; Sun, X.
- Cambridge : Royal Society of Chemistry
Salt concentration and charging velocity determine ion charge storage mechanism in nanoporous supercapacitors
collection, January 2018
- Prehal, Christian; Koczwara, Christian; Amenitsch, Heinz
- Universität des Saarlandes
Review on the science and technology of water desalination by capacitive deionization
other, January 2013
- Presser, Volker; Porada, S.; Zhao, R.
- Amsterdam : Elsevier
The Importance of Dehydration in Determining Ion Transport in Narrow Pores
journal, March 2012
- Richards, Laura A.; Schäfer, Andrea I.; Richards, Bryce S.
- Small, Vol. 8, Issue 11
Molecular dynamics simulations of the electric double layer capacitance of graphene electrodes in mono-valent aqueous electrolytes
journal, January 2016
- Jiang, Gengping; Cheng, Chi; Li, Dan
- Nano Research, Vol. 9, Issue 1
Carbons with narrow pore size distribution prepared by simultaneous carbonization and self-activation of tobacco stems and their application to supercapacitors
journal, January 2015
- Kleszyk, P.; Ratajczak, P.; Skowron, P.
- Carbon, Vol. 81
Dual gas analysis of microporous carbons using 2D-NLDFT heterogeneous surface model and combined adsorption data of N2 and CO2
journal, September 2015
- Jagiello, Jacek; Ania, Conchi; Parra, Jose B.
- Carbon, Vol. 91
High surface area carbon aerogel monoliths with hierarchical porosity
journal, July 2008
- Baumann, Theodore F.; Worsley, Marcus A.; Han, T. Yong-Jin
- Journal of Non-Crystalline Solids, Vol. 354, Issue 29, p. 3513-3515
Faradaic reactions in capacitive deionization (CDI) - problems and possibilities: A review
journal, January 2018
- Zhang, Changyong; He, Di; Ma, Jinxing
- Water Research, Vol. 128
Using Ultramicroporous Carbon for the Selective Removal of Nitrate with Capacitive Deionization
journal, June 2019
- Hawks, Steven A.; Cerón, Maira R.; Oyarzun, Diego I.
- Environmental Science & Technology, Vol. 53, Issue 18
Analysis of Lithium Insertion/Desorption Reaction at Interfaces between Graphite Electrodes and Electrolyte Solution Using Density Functional + Implicit Solvation Theory
journal, April 2018
- Haruyama, Jun; Ikeshoji, Tamio; Otani, Minoru
- The Journal of Physical Chemistry C, Vol. 122, Issue 18
Critical Knowledge Gaps in Mass Transport through Single-Digit Nanopores: A Review and Perspective
journal, May 2019
- Faucher, Samuel; Aluru, Narayana; Bazant, Martin Z.
- The Journal of Physical Chemistry C, Vol. 123, Issue 35
Effective Polarization in Pairwise Potentials at the Graphene–Electrolyte Interface
journal, January 2017
- Williams, Christopher D.; Dix, James; Troisi, Alessandro
- The Journal of Physical Chemistry Letters, Vol. 8, Issue 3
Kinetic-Dominated Charging Mechanism within Representative Aqueous Electrolyte-based Electric Double-Layer Capacitors
journal, July 2017
- Yang, Huachao; Yang, Jinyuan; Bo, Zheng
- The Journal of Physical Chemistry Letters, Vol. 8, Issue 15
Capacitance of Basal Plane and Edge-Oriented Highly Ordered Pyrolytic Graphite: Specific Ion Effects
journal, January 2019
- Iamprasertkun, Pawin; Hirunpinyopas, Wisit; Keerthi, Ashok
- The Journal of Physical Chemistry Letters, Vol. 10, Issue 3
Capacitive Energy Storage in Nanostructured Carbon–Electrolyte Systems
journal, June 2012
- Simon, P.; Gogotsi, Y.
- Accounts of Chemical Research, Vol. 46, Issue 5
Effect of Ions on the Structure of Water: Structure Making and Breaking
journal, March 2009
- Marcus, Yizhak
- Chemical Reviews, Vol. 109, Issue 3
The OPLS [optimized potentials for liquid simulations] potential functions for proteins, energy minimizations for crystals of cyclic peptides and crambin
journal, March 1988
- Jorgensen, William L.; Tirado-Rives, Julian
- Journal of the American Chemical Society, Vol. 110, Issue 6
Relation between the Ion Size and Pore Size for an Electric Double-Layer Capacitor
journal, March 2008
- Largeot, Celine; Portet, Cristelle; Chmiola, John
- Journal of the American Chemical Society, Vol. 130, Issue 9
Development and Testing of the OPLS All-Atom Force Field on Conformational Energetics and Properties of Organic Liquids
journal, January 1996
- Jorgensen, William L.; Maxwell, David S.; Tirado-Rives, Julian
- Journal of the American Chemical Society, Vol. 118, Issue 45
Aqueous NaCl Solutions within Charged Carbon-Slit Pores: Partition Coefficients and Density Distributions from Molecular Dynamics Simulations
journal, June 2011
- Kalluri, Raja Kirthi; Konatham, Deepthi; Striolo, Alberto
- The Journal of Physical Chemistry C, Vol. 115, Issue 28
Molecular Friction-Induced Electroosmotic Phenomena in Thin Neutral Nanotubes
journal, June 2014
- Vuković, Lela; Vokac, Elizabeth; Král, Petr
- The Journal of Physical Chemistry Letters, Vol. 5, Issue 12
Electrolytic Transport in Modified Carbon Nanotubes
journal, October 2003
- Joseph, Sony; Mashl, R. Jay; Jakobsson, Eric
- Nano Letters, Vol. 3, Issue 10
Anomalous Hydration Shell Order of Na + and K + inside Carbon Nanotubes
journal, March 2009
- Shao, Qing; Zhou, Jian; Lu, Linghong
- Nano Letters, Vol. 9, Issue 3
Origin of Giant Ionic Currents in Carbon Nanotube Channels
journal, August 2011
- Pang, Pei; He, Jin; Park, Jae Hyun
- ACS Nano, Vol. 5, Issue 9
Two-Dimensional Transition Metal Carbides
journal, January 2012
- Naguib, Michael; Mashtalir, Olha; Carle, Joshua
- ACS Nano, Vol. 6, Issue 2
Salt concentration and charging velocity determine ion charge storage mechanism in nanoporous supercapacitors
journal, October 2018
- Prehal, C.; Koczwara, C.; Amenitsch, H.
- Nature Communications, Vol. 9, Issue 1
Molecular simulation study of temperature effect on ionic hydration in carbon nanotubes
journal, January 2008
- Shao, Qing; Huang, Liangliang; Zhou, Jian
- Physical Chemistry Chemical Physics, Vol. 10, Issue 14
Advanced carbon aerogels for energy applications
journal, January 2011
- Biener, Juergen; Stadermann, Michael; Suss, Matthew
- Energy & Environmental Science, Vol. 4, Issue 3, p. 656-667
Novel insight into neutral medium as electrolyte for high-voltage supercapacitors
journal, January 2012
- Fic, Krzysztof; Lota, Grzegorz; Meller, Mikolaj
- Energy Environ. Sci., Vol. 5, Issue 2
Self-consistent description of a metal–water interface by the Kohn–Sham density functional theory and the three-dimensional reference interaction site model
journal, May 1999
- Kovalenko, Andriy; Hirata, Fumio
- The Journal of Chemical Physics, Vol. 110, Issue 20
Electrolytic transport through a synthetic nanometer-diameter pore
journal, July 2005
- Ho, C.; Qiao, R.; Heng, J. B.
- Proceedings of the National Academy of Sciences, Vol. 102, Issue 30
Mechanism of ion adsorption to aqueous interfaces: Graphene/water vs. air/water
journal, August 2017
- McCaffrey, Debra L.; Nguyen, Son C.; Cox, Stephen J.
- Proceedings of the National Academy of Sciences, Vol. 114, Issue 51
QUANTUM ESPRESSO: a modular and open-source software project for quantum simulations of materials
journal, September 2009
- Giannozzi, Paolo; Baroni, Stefano; Bonini, Nicola
- Journal of Physics: Condensed Matter, Vol. 21, Issue 39, Article No. 395502
A grid-based Bader analysis algorithm without lattice bias
journal, January 2009
- Tang, W.; Sanville, E.; Henkelman, G.
- Journal of Physics: Condensed Matter, Vol. 21, Issue 8
Ion separation using a Y-junction carbon nanotube
journal, January 2006
- Park, Jae Hyun; Sinnott, Susan B.; Aluru, N. R.
- Nanotechnology, Vol. 17, Issue 3
Charge Inversion and Flow Reversal in a Nanochannel Electro-osmotic Flow
journal, May 2004
- Qiao, R.; Aluru, N. R.
- Physical Review Letters, Vol. 92, Issue 19
Anomalous Increase in Carbon Capacitance at Pore Sizes Less Than 1 Nanometer
journal, September 2006
- Chmiola, J.
- Science, Vol. 313, Issue 5794
Translocation of Single-Stranded DNA Through Single-Walled Carbon Nanotubes
journal, December 2009
- Liu, H.; He, J.; Tang, J.
- Science, Vol. 327, Issue 5961
Water desalination via capacitive deionization: what is it and what can we expect from it?
text, January 2015
- Suss, M. E.; Porada, S.; Sun, X.
- Cambridge : RSC Publ.
Van der Waals Density Functional for General Geometries
text, January 2004
- Dion, M.; Rydberg, H.; Schroder, E.
- arXiv
Figures / Tables found in this record: