Optimization of Graphite–SiO blend electrodes for lithium-ion batteries: Stable cycling enabled by single-walled carbon nanotube conductive additive

Kirner, Joel; Qin, Yan; Zhang, Linghong; Jansen, Andrew; Lu, Wenquan

doi:10.1016/j.jpowsour.2020.227711

Title: Optimization of Graphite–SiO blend electrodes for lithium-ion batteries: Stable cycling enabled by single-walled carbon nanotube conductive additive

Abstract

Lithium-alloying materials are of great interest to improve the gravimetric and volumetric energy density of lithium-ion batteries, though their associated volume fluctuation with cycling often leads to poor cycling performance. Active-inactive alloys and blending alloys with carbon materials are common strategies to accommodate volume fluctuation. Herein we set out to optimize graphite-SiO blend electrode formulations to eliminate rapid capacity fade. Electrodes with highly stable cycling were prepared by simple planetary mixing procedures, enabled by the use of just a fraction of a weight percent of commercial SWCNTs as the only conductive additive, and by the appropriate choice of binder/stabilizing agent. In fact, the use of SWCNTs allowed for graphite-free SiO electrodes with approximately 74% higher volumetric energy density relative to traditional graphite electrodes, and superior capacity retention in coin-type full-cell testing versus NMC532 cathodes.

Authors:

^[1]; Qin, Yan ^[1];

^[1]; Jansen, Andrew ^[1];

^[1]

Argonne National Lab. (ANL), Argonne, IL (United States)

Publication Date:: Wed Jan 29 00:00:00 EST 2020

Research Org.:: Argonne National Lab. (ANL), Argonne, IL (United States)

Sponsoring Org.:: USDOE Office of Energy Efficiency and Renewable Energy (EERE), Transportation Office

OSTI Identifier:: 1632823

Grant/Contract Number:: AC02-06CH11357

Resource Type:: Accepted Manuscript

Journal Name:: Journal of Power Sources

Additional Journal Information:: Journal Volume: 450; Journal Issue: C; Journal ID: ISSN 0378-7753

Publisher:: Elsevier

Country of Publication:: United States

Language:: English

Subject:: 25 ENERGY STORAGE; Blend electrode; Carbon nanotube; Graphite; Lithium-ion battery; Silicon monoxide

Citation Formats


                    Kirner, Joel, Qin, Yan, Zhang, Linghong, Jansen, Andrew, and Lu, Wenquan. Optimization of Graphite–SiO blend electrodes for lithium-ion batteries: Stable cycling enabled by single-walled carbon nanotube conductive additive.  United States: N. p., 2020. 
Web.  doi:10.1016/j.jpowsour.2020.227711.

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                    Kirner, Joel, Qin, Yan, Zhang, Linghong, Jansen, Andrew, & Lu, Wenquan. Optimization of Graphite–SiO blend electrodes for lithium-ion batteries: Stable cycling enabled by single-walled carbon nanotube conductive additive.  United States.  https://doi.org/10.1016/j.jpowsour.2020.227711

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                    Kirner, Joel, Qin, Yan, Zhang, Linghong, Jansen, Andrew, and Lu, Wenquan. Wed .  
"Optimization of Graphite–SiO blend electrodes for lithium-ion batteries: Stable cycling enabled by single-walled carbon nanotube conductive additive".  United States.  https://doi.org/10.1016/j.jpowsour.2020.227711.  https://www.osti.gov/servlets/purl/1632823.

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@article{osti_1632823,

  title        = {Optimization of Graphite–SiO blend electrodes for lithium-ion batteries: Stable cycling enabled by single-walled carbon nanotube conductive additive},

  author       = {Kirner, Joel and Qin, Yan and Zhang, Linghong and Jansen, Andrew and Lu, Wenquan},

  abstractNote = {Lithium-alloying materials are of great interest to improve the gravimetric and volumetric energy density of lithium-ion batteries, though their associated volume fluctuation with cycling often leads to poor cycling performance. Active-inactive alloys and blending alloys with carbon materials are common strategies to accommodate volume fluctuation. Herein we set out to optimize graphite-SiO blend electrode formulations to eliminate rapid capacity fade. Electrodes with highly stable cycling were prepared by simple planetary mixing procedures, enabled by the use of just a fraction of a weight percent of commercial SWCNTs as the only conductive additive, and by the appropriate choice of binder/stabilizing agent. In fact, the use of SWCNTs allowed for graphite-free SiO electrodes with approximately 74% higher volumetric energy density relative to traditional graphite electrodes, and superior capacity retention in coin-type full-cell testing versus NMC532 cathodes.},

  doi          = {10.1016/j.jpowsour.2020.227711},

  journal      = {Journal of Power Sources},

  number       = C,

  volume       = 450,

  place        = {United States},

  year         = {Wed Jan 29 00:00:00 EST 2020},

  month        = {Wed Jan 29 00:00:00 EST 2020}

}

Copy to clipboard

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Works referenced in this record:

Alloy Design for Lithium-Ion Battery Anodes
journal, January 2007

Obrovac, M. N.; Christensen, Leif; Le, Dinh Ba
Journal of The Electrochemical Society, Vol. 154, Issue 9, p. A849-A855
DOI: 10.1149/1.2752985

Alloy Negative Electrodes for Li-Ion Batteries
journal, October 2014

Obrovac, M. N.; Chevrier, V. L.
Chemical Reviews, Vol. 114, Issue 23
DOI: 10.1021/cr500207g

Designing nanostructured Si anodes for high energy lithium ion batteries
journal, October 2012

Wu, Hui; Cui, Yi
Nano Today, Vol. 7, Issue 5
DOI: 10.1016/j.nantod.2012.08.004

Recent advancement of SiOx based anodes for lithium-ion batteries
journal, September 2017

Chen, Tao; Wu, Ji; Zhang, Qinglin
Journal of Power Sources, Vol. 363
DOI: 10.1016/j.jpowsour.2017.07.073

Analysis of SiO Anodes for Lithium-Ion Batteries
journal, January 2005

Miyachi, Mariko; Yamamoto, Hironori; Kawai, Hidemasa
Journal of The Electrochemical Society, Vol. 152, Issue 10
DOI: 10.1149/1.2013210

Electrochemical behavior of SiO anode for Li secondary batteries
journal, October 2011

Kim, Jae-Hun; Park, Cheol-Min; Kim, Hansu
Journal of Electroanalytical Chemistry, Vol. 661, Issue 1
DOI: 10.1016/j.jelechem.2011.08.010

Improved Performances of Nanosilicon Electrodes Using the Salt LiFSI: A Photoelectron Spectroscopy Study
journal, June 2013

Philippe, Bertrand; Dedryvère, Rémi; Gorgoi, Mihaela
Journal of the American Chemical Society, Vol. 135, Issue 26
DOI: 10.1021/ja403082s

Atomic-Level Understanding toward a High-Capacity and High-Power Silicon Oxide (SiO) Material
journal, December 2015

Jung, Sung Chul; Kim, Hyung-Jin; Kim, Jae-Hun
The Journal of Physical Chemistry C, Vol. 120, Issue 2
DOI: 10.1021/acs.jpcc.5b10589

RETRACTED ARTICLE: Theoretical Limits of Energy Density in Silicon-Carbon Composite Anode Based Lithium Ion Batteries
journal, June 2016

Dash, Ranjan; Pannala, Sreekanth
Scientific Reports, Vol. 6, Issue 1
DOI: 10.1038/srep27449

Evaluating Si-Based Materials for Li-Ion Batteries in Commercially Relevant Negative Electrodes
journal, January 2014

Chevrier, Vincent L.; Liu, Li; Le, Dinh Ba
Journal of The Electrochemical Society, Vol. 161, Issue 5
DOI: 10.1149/2.066405jes

High Energy Density Calendered Si Alloy/Graphite Anodes
journal, January 2014

Du, Zhijia; Dunlap, R. A.; Obrovac, M. N.
Journal of The Electrochemical Society, Vol. 161, Issue 10
DOI: 10.1149/2.0941410jes

Towards Improving the Practical Energy Density of Li-Ion Batteries: Optimization and Evaluation of Silicon:Graphite Composites in Full Cells
journal, December 2016

Yim, Chae-Ho; Niketic, Svetlana; Salem, Nuha
Journal of The Electrochemical Society, Vol. 164, Issue 1
DOI: 10.1149/2.0481701jes

A Guide to Li-Ion Coin-Cell Electrode Making for Academic Researchers
journal, January 2011

Marks, Thomas; Trussler, Simon; Smith, A. J.
Journal of The Electrochemical Society, Vol. 158, Issue 1
DOI: 10.1149/1.3515072

Performance of high-power lithium-ion cells under pulse discharge and charge conditions
journal, December 2009

Abraham, D. P.; Dees, D. W.; Christophersen, J.
International Journal of Energy Research, Vol. 34, Issue 2
DOI: 10.1002/er.1665

Polyacrylate Modifier for Graphite Anode of Lithium-Ion Batteries
journal, January 2009

Komaba, S.; Okushi, K.; Ozeki, T.
Electrochemical and Solid-State Letters, Vol. 12, Issue 5
DOI: 10.1149/1.3086262

Polyacrylate as Functional Binder for Silicon and Graphite Composite Electrode in Lithium-Ion Batteries
journal, January 2011

Komaba, Shinichi; Ozeki, Tomoaki; Yabuuchi, Naoaki
Electrochemistry, Vol. 79, Issue 1
DOI: 10.5796/electrochemistry.79.6

Study on Polymer Binders for High-Capacity SiO Negative Electrode of Li-Ion Batteries
journal, June 2011

Komaba, Shinichi; Shimomura, Keiji; Yabuuchi, Naoaki
The Journal of Physical Chemistry C, Vol. 115, Issue 27
DOI: 10.1021/jp201691g

Capacity Fading Mechanism and Improvement of Cycling Stability of the SiO Anode for Lithium-Ion Batteries
journal, January 2018

Zhang, Linghong; Qin, Yan; Liu, Yuzi
Journal of The Electrochemical Society, Vol. 165, Issue 10
DOI: 10.1149/2.0431810jes

Specific surface area of carbon nanotubes and bundles of carbon nanotubes
journal, April 2001

Peigney, A.; Laurent, Ch.; Flahaut, E.
Carbon, Vol. 39, Issue 4, p. 507-514
DOI: 10.1016/S0008-6223(00)00155-X

Layered Oxide, Graphite and Silicon-Graphite Electrodes for Lithium-Ion Cells: Effect of Electrolyte Composition and Cycling Windows
journal, October 2016

Klett, Matilda; Gilbert, James A.; Pupek, Krzysztof Z.
Journal of The Electrochemical Society, Vol. 164, Issue 1
DOI: 10.1149/2.0131701jes

A high performance silicon/carbon composite anode with carbon nanofiber for lithium-ion batteries
journal, March 2010

Si, Q.; Hanai, K.; Ichikawa, T.
Journal of Power Sources, Vol. 195, Issue 6
DOI: 10.1016/j.jpowsour.2009.09.073

Improvement of cyclic behavior of a ball-milled SiO and carbon nanofiber composite anode for lithium-ion batteries
journal, November 2011

Si, Q.; Hanai, K.; Ichikawa, T.
Journal of Power Sources, Vol. 196, Issue 22
DOI: 10.1016/j.jpowsour.2011.08.005

Preparation and characterization of silicon monoxide/graphite/carbon nanotubes composite as anode for lithium-ion batteries
journal, September 2011

Ren, Yurong; Ding, Jianning; Yuan, Ningyi
Journal of Solid State Electrochemistry, Vol. 16, Issue 4
DOI: 10.1007/s10008-011-1525-2

Facile Synthesis and High Anode Performance of Carbon Fiber-Interwoven Amorphous Nano-SiO _x /Graphene for Rechargeable Lithium Batteries
journal, October 2013

Nguyen, Dan Thien; Nguyen, Cao Cuong; Kim, Jong-Seon
ACS Applied Materials & Interfaces, Vol. 5, Issue 21
DOI: 10.1021/am4034763

Facile spray-drying/pyrolysis synthesis of intertwined SiO@CNFs&G composites as superior anode materials for Li-ion batteries
journal, January 2014

Hou, Xianhua; Wang, Jiyun; Zhang, Miao
RSC Adv., Vol. 4, Issue 65
DOI: 10.1039/C4RA03475A

Catalyst Ni-assisted synthesis of interweaved SiO/G/CNTs&CNFs composite as anode material for lithium-ion batteries
journal, June 2015

Li, Yana; Hou, Xianhua; Wang, Jiyun
Journal of Materials Science: Materials in Electronics, Vol. 26, Issue 10
DOI: 10.1007/s10854-015-3386-4

Highly stable SiOx/multiwall carbon nanotube/N-doped carbon composite as anodes for lithium-ion batteries
journal, July 2016

Ren, Yurong; Wu, Ximin; Li, Mingqi
Electrochimica Acta, Vol. 206
DOI: 10.1016/j.electacta.2016.04.161

High-performance ball-milled SiOx anodes for lithium ion batteries
journal, January 2017

Zhang, Junying; Zhang, Chunqian; Liu, Zhi
Journal of Power Sources, Vol. 339
DOI: 10.1016/j.jpowsour.2016.11.044

Differentiating the Degradation Phenomena in Silicon-Graphite Electrodes for Lithium-Ion Batteries
journal, January 2017

Wetjen, Morten; Pritzl, Daniel; Jung, Roland
Journal of The Electrochemical Society, Vol. 164, Issue 12
DOI: 10.1149/2.1921712jes

Very Stable Lithium Metal Stripping–Plating at a High Rate and High Areal Capacity in Fluoroethylene Carbonate-Based Organic Electrolyte Solution
journal, May 2017

Markevich, Elena; Salitra, Gregory; Chesneau, Frederick
ACS Energy Letters, Vol. 2, Issue 6
DOI: 10.1021/acsenergylett.7b00300

Fluoroethylene Carbonate Additives to Render Uniform Li Deposits in Lithium Metal Batteries
journal, January 2017

Zhang, Xue-Qiang; Cheng, Xin-Bing; Chen, Xiang
Advanced Functional Materials, Vol. 27, Issue 10
DOI: 10.1002/adfm.201605989

Pre-Lithiation Strategies for Rechargeable Energy Storage Technologies: Concepts, Promises and Challenges
journal, January 2018

Holtstiege, Florian; Bärmann, Peer; Nölle, Roman
Batteries, Vol. 4, Issue 1
DOI: 10.3390/batteries4010004

Li-ion battery materials: present and future
journal, June 2015

Nitta, Naoki; Wu, Feixiang; Lee, Jung Tae
Materials Today, Vol. 18, Issue 5
DOI: 10.1016/j.mattod.2014.10.040

Lithium Insertion in Carbon-Silicon Composite Materials Produced by Mechanical Milling
journal, January 1998

Wang, C. S.; Wu, G. T.; Zhang, X. B.
Journal of The Electrochemical Society, Vol. 145, Issue 8, p. 2751-2758
DOI: 10.1149/1.1838709

Improvement of Usable Capacity and Cyclability of Silicon-Based Anode Materials for Lithium Batteries by Sol-Gel Graphite Matrix
journal, January 2002

Niu, Jianjun; Lee, Jim Yang
Electrochemical and Solid-State Letters, Vol. 5, Issue 6
DOI: 10.1149/1.1472256

Studies of the Capacity Fade Mechanisms of LiCoO ₂ /Si-Alloy: Graphite Cells
journal, January 2016

Petibon, R.; Chevrier, V. L.; Aiken, C. P.
Journal of The Electrochemical Society, Vol. 163, Issue 7
DOI: 10.1149/2.0191607jes

Consumption of Fluoroethylene Carbonate (FEC) on Si-C Composite Electrodes for Li-Ion Batteries
journal, January 2016

Jung, Roland; Metzger, Michael; Haering, Dominik
Journal of The Electrochemical Society, Vol. 163, Issue 8
DOI: 10.1149/2.0951608jes

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Title: Optimization of Graphite–SiO blend electrodes for lithium-ion batteries: Stable cycling enabled by single-walled carbon nanotube conductive additive

Abstract

Citation Formats

Alloy Design for Lithium-Ion Battery Anodes journal, January 2007

Alloy Negative Electrodes for Li-Ion Batteries journal, October 2014

Designing nanostructured Si anodes for high energy lithium ion batteries journal, October 2012

Recent advancement of SiOx based anodes for lithium-ion batteries journal, September 2017

Analysis of SiO Anodes for Lithium-Ion Batteries journal, January 2005

Electrochemical behavior of SiO anode for Li secondary batteries journal, October 2011

Improved Performances of Nanosilicon Electrodes Using the Salt LiFSI: A Photoelectron Spectroscopy Study journal, June 2013

Atomic-Level Understanding toward a High-Capacity and High-Power Silicon Oxide (SiO) Material journal, December 2015

RETRACTED ARTICLE: Theoretical Limits of Energy Density in Silicon-Carbon Composite Anode Based Lithium Ion Batteries journal, June 2016

Evaluating Si-Based Materials for Li-Ion Batteries in Commercially Relevant Negative Electrodes journal, January 2014

High Energy Density Calendered Si Alloy/Graphite Anodes journal, January 2014

Towards Improving the Practical Energy Density of Li-Ion Batteries: Optimization and Evaluation of Silicon:Graphite Composites in Full Cells journal, December 2016

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Performance of high-power lithium-ion cells under pulse discharge and charge conditions journal, December 2009

Polyacrylate Modifier for Graphite Anode of Lithium-Ion Batteries journal, January 2009

Polyacrylate as Functional Binder for Silicon and Graphite Composite Electrode in Lithium-Ion Batteries journal, January 2011

Study on Polymer Binders for High-Capacity SiO Negative Electrode of Li-Ion Batteries journal, June 2011

Capacity Fading Mechanism and Improvement of Cycling Stability of the SiO Anode for Lithium-Ion Batteries journal, January 2018

Specific surface area of carbon nanotubes and bundles of carbon nanotubes journal, April 2001

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A high performance silicon/carbon composite anode with carbon nanofiber for lithium-ion batteries journal, March 2010

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Facile Synthesis and High Anode Performance of Carbon Fiber-Interwoven Amorphous Nano-SiO x /Graphene for Rechargeable Lithium Batteries journal, October 2013

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Very Stable Lithium Metal Stripping–Plating at a High Rate and High Areal Capacity in Fluoroethylene Carbonate-Based Organic Electrolyte Solution journal, May 2017

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Pre-Lithiation Strategies for Rechargeable Energy Storage Technologies: Concepts, Promises and Challenges journal, January 2018

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Lithium Insertion in Carbon-Silicon Composite Materials Produced by Mechanical Milling journal, January 1998

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Studies of the Capacity Fade Mechanisms of LiCoO 2 /Si-Alloy: Graphite Cells journal, January 2016

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Alloy Design for Lithium-Ion Battery Anodes
journal, January 2007

Alloy Negative Electrodes for Li-Ion Batteries
journal, October 2014

Designing nanostructured Si anodes for high energy lithium ion batteries
journal, October 2012

Recent advancement of SiOx based anodes for lithium-ion batteries
journal, September 2017

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journal, January 2005

Electrochemical behavior of SiO anode for Li secondary batteries
journal, October 2011

Improved Performances of Nanosilicon Electrodes Using the Salt LiFSI: A Photoelectron Spectroscopy Study
journal, June 2013

Atomic-Level Understanding toward a High-Capacity and High-Power Silicon Oxide (SiO) Material
journal, December 2015

RETRACTED ARTICLE: Theoretical Limits of Energy Density in Silicon-Carbon Composite Anode Based Lithium Ion Batteries
journal, June 2016

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journal, January 2014

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Polyacrylate Modifier for Graphite Anode of Lithium-Ion Batteries
journal, January 2009

Polyacrylate as Functional Binder for Silicon and Graphite Composite Electrode in Lithium-Ion Batteries
journal, January 2011

Study on Polymer Binders for High-Capacity SiO Negative Electrode of Li-Ion Batteries
journal, June 2011

Capacity Fading Mechanism and Improvement of Cycling Stability of the SiO Anode for Lithium-Ion Batteries
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Specific surface area of carbon nanotubes and bundles of carbon nanotubes
journal, April 2001

Layered Oxide, Graphite and Silicon-Graphite Electrodes for Lithium-Ion Cells: Effect of Electrolyte Composition and Cycling Windows
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journal, November 2011

Preparation and characterization of silicon monoxide/graphite/carbon nanotubes composite as anode for lithium-ion batteries
journal, September 2011

Facile Synthesis and High Anode Performance of Carbon Fiber-Interwoven Amorphous Nano-SiO _x /Graphene for Rechargeable Lithium Batteries
journal, October 2013

Facile spray-drying/pyrolysis synthesis of intertwined SiO@CNFs&G composites as superior anode materials for Li-ion batteries
journal, January 2014

Catalyst Ni-assisted synthesis of interweaved SiO/G/CNTs&CNFs composite as anode material for lithium-ion batteries
journal, June 2015

Highly stable SiOx/multiwall carbon nanotube/N-doped carbon composite as anodes for lithium-ion batteries
journal, July 2016

High-performance ball-milled SiOx anodes for lithium ion batteries
journal, January 2017

Differentiating the Degradation Phenomena in Silicon-Graphite Electrodes for Lithium-Ion Batteries
journal, January 2017

Very Stable Lithium Metal Stripping–Plating at a High Rate and High Areal Capacity in Fluoroethylene Carbonate-Based Organic Electrolyte Solution
journal, May 2017

Fluoroethylene Carbonate Additives to Render Uniform Li Deposits in Lithium Metal Batteries
journal, January 2017

Pre-Lithiation Strategies for Rechargeable Energy Storage Technologies: Concepts, Promises and Challenges
journal, January 2018

Li-ion battery materials: present and future
journal, June 2015

Lithium Insertion in Carbon-Silicon Composite Materials Produced by Mechanical Milling
journal, January 1998

Improvement of Usable Capacity and Cyclability of Silicon-Based Anode Materials for Lithium Batteries by Sol-Gel Graphite Matrix
journal, January 2002

Studies of the Capacity Fade Mechanisms of LiCoO ₂ /Si-Alloy: Graphite Cells
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Consumption of Fluoroethylene Carbonate (FEC) on Si-C Composite Electrodes for Li-Ion Batteries
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