Revealing 3D Morphological and Chemical Evolution Mechanisms of Metals in Molten Salt by Multimodal Microscopy
Abstract
Growing interest in molten salts as effective high-temperature heat-transfer fluids for sustainable energy systems drives a critical need to fundamentally understand the interactions between metals and molten salts. This work utilizes the multimodal microscopy methods of synchrotron X-ray nanotomography and electron microscopy to investigate the 3D morphological and chemical evolution of two-model systems, pure nickel metal and Ni-20Cr binary alloy, in a representative molten salt (KCl-MgCl2 50–50 mol %, 800 °C). In both systems, unexpected shell-like structures formed because of the presence of more noble tungsten, suggesting a potential route of using Ni–W alloys for enhanced molten-salt corrosion resistance. The binary alloy Ni-20Cr developed a bicontinuous porous structure, reassembling functional porous metals manufactured by dealloying. This work elucidates better mechanistic understanding of corrosion in molten salts, which can contribute to the design of more reliable alloys for molten salt applications including next-generation nuclear and solar power plants and opens the possibility of using molten salts to fabricate functional porous materials.
- Authors:
-
[1];
[3];
[2];
[3];
[3];
[5];
[3];
[3];
[6]
- Stony Brook Univ., NY (United States)
- Idaho National Lab. (INL), Idaho Falls, ID (United States)
- Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
- Brookhaven National Lab. (BNL), Upton, NY (United States). National Synchrotron Light Source II (NSLS-II)
- Brookhaven National Lab. (BNL), Upton, NY (United States)
- Stony Brook Univ., NY (United States); Brookhaven National Lab. (BNL), Upton, NY (United States). National Synchrotron Light Source II (NSLS-II)
- Publication Date:
- Research Org.:
- Energy Frontier Research Centers (EFRC) (United States). Molten Salts in Extreme Environments (MSEE); Brookhaven National Laboratory (BNL), Upton, NY (United States); Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- OSTI Identifier:
- 1631921
- Alternate Identifier(s):
- OSTI ID: 1619027
- Report Number(s):
- BNL-215956-2020-JAAM
Journal ID: ISSN 1944-8244
- Grant/Contract Number:
- SC0012704; AC07-05ID14517; AC05-00OR22725
- Resource Type:
- Accepted Manuscript
- Journal Name:
- ACS Applied Materials and Interfaces
- Additional Journal Information:
- Journal Volume: 12; Journal Issue: 15; Journal ID: ISSN 1944-8244
- Publisher:
- American Chemical Society (ACS)
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 36 MATERIALS SCIENCE; 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; chloride molten salt; high-temperature corrosion; Ni-based alloys; X-ray CT; TXM; molten salt corrosion dealloying; multiscale imaging
Citation Formats
Ronne, Arthur, He, Lingfeng, Dolzhnikov, Dmitriy, Xie, Yi, Ge, Mingyuan, Halstenberg, Phillip, Wang, Yachun, Manard, Benjamin T., Xiao, Xianghui, Lee, Wah-Keat, Sasaki, Kotaro, Dai, Sheng, Mahurin, Shannon M., and Chen-Wiegart, Yu-chen Karen. Revealing 3D Morphological and Chemical Evolution Mechanisms of Metals in Molten Salt by Multimodal Microscopy. United States: N. p., 2020.
Web. doi:10.1021/acsami.9b19099.
Ronne, Arthur, He, Lingfeng, Dolzhnikov, Dmitriy, Xie, Yi, Ge, Mingyuan, Halstenberg, Phillip, Wang, Yachun, Manard, Benjamin T., Xiao, Xianghui, Lee, Wah-Keat, Sasaki, Kotaro, Dai, Sheng, Mahurin, Shannon M., & Chen-Wiegart, Yu-chen Karen. Revealing 3D Morphological and Chemical Evolution Mechanisms of Metals in Molten Salt by Multimodal Microscopy. United States. https://doi.org/10.1021/acsami.9b19099
Ronne, Arthur, He, Lingfeng, Dolzhnikov, Dmitriy, Xie, Yi, Ge, Mingyuan, Halstenberg, Phillip, Wang, Yachun, Manard, Benjamin T., Xiao, Xianghui, Lee, Wah-Keat, Sasaki, Kotaro, Dai, Sheng, Mahurin, Shannon M., and Chen-Wiegart, Yu-chen Karen. Thu .
"Revealing 3D Morphological and Chemical Evolution Mechanisms of Metals in Molten Salt by Multimodal Microscopy". United States. https://doi.org/10.1021/acsami.9b19099. https://www.osti.gov/servlets/purl/1631921.
@article{osti_1631921,
title = {Revealing 3D Morphological and Chemical Evolution Mechanisms of Metals in Molten Salt by Multimodal Microscopy},
author = {Ronne, Arthur and He, Lingfeng and Dolzhnikov, Dmitriy and Xie, Yi and Ge, Mingyuan and Halstenberg, Phillip and Wang, Yachun and Manard, Benjamin T. and Xiao, Xianghui and Lee, Wah-Keat and Sasaki, Kotaro and Dai, Sheng and Mahurin, Shannon M. and Chen-Wiegart, Yu-chen Karen},
abstractNote = {Growing interest in molten salts as effective high-temperature heat-transfer fluids for sustainable energy systems drives a critical need to fundamentally understand the interactions between metals and molten salts. This work utilizes the multimodal microscopy methods of synchrotron X-ray nanotomography and electron microscopy to investigate the 3D morphological and chemical evolution of two-model systems, pure nickel metal and Ni-20Cr binary alloy, in a representative molten salt (KCl-MgCl2 50–50 mol %, 800 °C). In both systems, unexpected shell-like structures formed because of the presence of more noble tungsten, suggesting a potential route of using Ni–W alloys for enhanced molten-salt corrosion resistance. The binary alloy Ni-20Cr developed a bicontinuous porous structure, reassembling functional porous metals manufactured by dealloying. This work elucidates better mechanistic understanding of corrosion in molten salts, which can contribute to the design of more reliable alloys for molten salt applications including next-generation nuclear and solar power plants and opens the possibility of using molten salts to fabricate functional porous materials.},
doi = {10.1021/acsami.9b19099},
journal = {ACS Applied Materials and Interfaces},
number = 15,
volume = 12,
place = {United States},
year = {Thu Mar 26 00:00:00 EDT 2020},
month = {Thu Mar 26 00:00:00 EDT 2020}
}
Free Publicly Available Full Text
Publisher's Version of Record
Other availability
Search WorldCat to find libraries that may hold this journal
Cited by: 18 works
Citation information provided by
Web of Science
Web of Science
Save to My Library
You must Sign In or Create an Account in order to save documents to your library.
Works referenced in this record:
Ultra-high temperature ceramics: Materials for extreme environments
journal, March 2017
- Fahrenholtz, William G.; Hilmas, Greg E.
- Scripta Materialia, Vol. 129
Hot corrosion behaviour of HVOF-sprayed NiCrBSi coatings on Ni- and Fe-based superalloys in Na2SO4–60% V2O5 environment at 900°C
journal, February 2006
- Sidhu, T. S.; Prakash, S.; Agrawal, R. D.
- Acta Materialia, Vol. 54, Issue 3
Assessment of Candidate Molten Salt Coolants for the NGNP/NHI Heat-Transfer Loop
report, June 2006
- Williams, D. F.
Thermal Properties of LiCl-KCl Molten Salt for Nuclear Waste Separation
report, November 2012
- Sridharan, Kumar; Allen, Todd; Anderson, Mark
Development of Pyroprocessing and its Future Direction
journal, April 2008
- Inoue, Tadashi; Koch, Lothar
- Nuclear Engineering and Technology, Vol. 40, Issue 3
Presence of Li Clusters in Molten LiCl-Li
journal, May 2016
- Merwin, Augustus; Phillips, William C.; Williamson, Mark A.
- Scientific Reports, Vol. 6, Issue 1
A Conceptual Study of Pyroprocessing for Recovering Actinides from Spent Oxide Fuels
journal, December 2008
- Yoo, Jae-Hyung; Seo, Chung-Seok; Kim, Eung-Ho
- Nuclear Engineering and Technology, Vol. 40, Issue 7
Comparison of sodium and KCl-MgCl2 as heat transfer fluids in CSP solar tower with sCO2 power cycles
journal, March 2018
- Polimeni, Simone; Binotti, Marco; Moretti, Luca
- Solar Energy, Vol. 162
Thermodynamic and kinetic consideration on the corrosion of Fe, Ni and Cr beneath a molten KCl–ZnCl2 mixture
journal, March 2006
- Ruh, Andreas; Spiegel, Michael
- Corrosion Science, Vol. 48, Issue 3
Materials corrosion in molten LiF–NaF–KF salt
journal, January 2009
- Olson, Luke C.; Ambrosek, James W.; Sridharan, Kumar
- Journal of Fluorine Chemistry, Vol. 130, Issue 1
Investigation on corrosion behavior of Ni-based alloys in molten fluoride salt using synchrotron radiation techniques
journal, September 2013
- Liu, Min; Zheng, Junyi; Lu, Yanling
- Journal of Nuclear Materials, Vol. 440, Issue 1-3, p. 124-128
Thermodynamics of corrosion in fused chlorides
journal, October 1960
- Edeleanu, C.; Littlewood, R.
- Electrochimica Acta, Vol. 3, Issue 3
Corrosion Resistance of Some Nickel-Base Alloys to Molten Fluoride Salts Containing UF4 and Tellurium *
journal, January 1976
- Keiser, J. R.
- ECS Proceedings Volumes, Vol. 1976-6, Issue 1
High Performance Corrosion Resistance of Nickel-Based Alloys in Molten Salt Flibe
journal, July 2009
- Kondo, Masatoshi; Nagasaka, Takuya; Muroga, Takeo
- Fusion Science and Technology, Vol. 56, Issue 1
Corrosion in the molten fluoride and chloride salts and materials development for nuclear applications
journal, August 2018
- Guo, Shaoqiang; Zhang, Jinsuo; Wu, Wei
- Progress in Materials Science, Vol. 97
Redox potential control in molten salt systems for corrosion mitigation
journal, November 2018
- Zhang, Jinsuo; Forsberg, Charles W.; Simpson, Michael F.
- Corrosion Science, Vol. 144
High temperature electrochemistry of molten fluoride salt for measurement of dissolved chromium
journal, June 2011
- Ludwig, D.; Olson, L.; Sridharan, K.
- Corrosion Engineering, Science and Technology, Vol. 46, Issue 4
Glassy carbon rotating ring-disc electrode for molten salt studies
journal, July 1976
- Phillips, J.; Gale, R. J.; Wier, R. G.
- Analytical Chemistry, Vol. 48, Issue 8
High temperature corrosion studies in molten salt-FLiNaK
journal, December 2013
- Sona, C. S.; Gajbhiye, B. D.; Hule, P. V.
- Corrosion Engineering, Science and Technology, Vol. 49, Issue 4
Corrosion behaviour of Ni-based superalloys in molten FLiNaK salts
journal, September 2018
- Patel, Niketan S.; Pavlík, Viliam; Kubíková, Blanka
- Corrosion Engineering, Science and Technology, Vol. 54, Issue 1
Intergranular corrosion of high temperature alloys in molten fluoride salts
journal, June 2010
- Olson, Luke; Sridharan, Kumar; Anderson, Mark
- Materials at High Temperatures, Vol. 27, Issue 2
Corrosion behavior of Hastelloy-N alloys in molten salt fluoride in Ar gas or in air
journal, May 2015
- Fukumoto, Ken-ichi; Fujimura, Ryota; Yamawaki, Michio
- Journal of Nuclear Science and Technology, Vol. 52, Issue 10
Aggregation and data analysis of corrosion studies in molten chloride and fluoride salts
journal, December 2018
- Raiman, Stephen S.; Lee, Sangkeun
- Journal of Nuclear Materials, Vol. 511
Re‐establishing the paradigm for evaluating halide salt compatibility to study commercial chloride salts at 600°C–800°C
journal, April 2019
- Pint, Bruce A.; McMurray, Jake W.; Willoughby, Adam W.
- Materials and Corrosion, Vol. 70, Issue 8
Effect of moisture on corrosion of Ni-based alloys in molten alkali fluoride FLiNaK salt environments
journal, June 2013
- Ouyang, Fan-Yi; Chang, Chi-Hung; You, Bo-Chien
- Journal of Nuclear Materials, Vol. 437, Issue 1-3
Corrosion performance of ferrous and refractory metals in molten salts under reducing conditions
journal, May 1999
- Indacochea, J. E.; Smith, J. L.; Litko, K. R.
- Journal of Materials Research, Vol. 14, Issue 5
High-Temperature Oxidation and Corrosion of Structural Materials in Molten Chlorides
journal, January 2001
- Indacochea, J. E.; Smith, J. L.; Litko, K. R.
- Oxidation of Metals, Vol. 55, Issue 1/2, p. 1-16
The high-temperature corrosion of Hastelloy N alloy (UNS N10003) in molten fluoride salts analysed by STXM, XAS, XRD, SEM, EPMA, TEM/EDS
journal, May 2016
- Ye, Xiang-Xi; Ai, Hua; Guo, Zhi
- Corrosion Science, Vol. 106
A comparative study on the high temperature corrosion of TP347H stainless steel, C22 alloy and laser-cladding C22 coating in molten chloride salts
journal, June 2014
- Liu, Shunv; Liu, Zongde; Wang, Yongtian
- Corrosion Science, Vol. 83
Generation IV International Forum: A decade of progress through international cooperation
journal, November 2014
- Kelly, John E.
- Progress in Nuclear Energy, Vol. 77
Comparison of SOFC cathode microstructure quantified using X-ray nanotomography and focused ion beam–scanning electron microscopy
journal, June 2011
- Nelson, George J.; Harris, William M.; Lombardo, Jeffrey J.
- Electrochemistry Communications, Vol. 13, Issue 6
Speciation of Molybdenum and Tungsten in Molten Chlorides: A Spectroelectrochemical Study
journal, October 2006
- Volkovich, Vladimir A.; Danilov, Danil A. A.; Polovov, Ilya B.
- ECS Transactions, Vol. 3, Issue 35
Effects of alloying elements on the corrosion behavior of Ni-based alloys in molten NaCl-KCl-MgCl2 salt at different temperatures
journal, October 2018
- Sun, Hua; Zhang, Peng; Wang, Jianqiang
- Corrosion Science, Vol. 143
Molten chloride salts for next generation concentrated solar power plants: Mitigation strategies against corrosion of structural materials
journal, May 2019
- Ding, Wenjin; Shi, Hao; Jianu, Adrian
- Solar Energy Materials and Solar Cells, Vol. 193
Imaging of 3D morphological evolution of nanoporous silicon anode in lithium ion battery by X-ray nano-tomography
journal, October 2018
- Zhao, Chonghang; Wada, Takeshi; De Andrade, Vincent
- Nano Energy, Vol. 52
Nanoporous Gold Catalysts for Selective Gas-Phase Oxidative Coupling of Methanol at Low Temperature
journal, January 2010
- Wittstock, A.; Zielasek, V.; Biener, J.
- Science, Vol. 327, Issue 5963
Oxygen reduction in nanoporous metal–ionic liquid composite electrocatalysts
journal, October 2010
- Snyder, J.; Fujita, T.; Chen, M. W.
- Nature Materials, Vol. 9, Issue 11
Evolution of nanoporosity in dealloying
journal, March 2001
- Erlebacher, Jonah; Aziz, Michael J.; Karma, Alain
- Nature, Vol. 410, Issue 6827, p. 450-453
Spontaneous evolution of bicontinuous nanostructures in dealloyed Li-based systems
journal, August 2013
- Chen, Qing; Sieradzki, Karl
- Nature Materials, Vol. 12, Issue 12
In situ imaging of dealloying during nanoporous gold formation by transmission X-ray microscopy
journal, February 2013
- Chen-Wiegart, Yu-chen Karen; Wang, Steve; Lee, Wah-Keat
- Acta Materialia, Vol. 61, Issue 4
Dealloying by metallic melt
journal, April 2011
- Wada, Takeshi; Yubuta, Kunio; Inoue, Akihisa
- Materials Letters, Vol. 65, Issue 7
Kinetics and morphological evolution of liquid metal dealloying
journal, August 2016
- McCue, Ian; Gaskey, Bernard; Geslin, Pierre-Antoine
- Acta Materialia, Vol. 115
Topology-generating interfacial pattern formation during liquid metal dealloying
journal, November 2015
- Geslin, Pierre-Antoine; McCue, Ian; Gaskey, Bernard
- Nature Communications, Vol. 6, Issue 1
Evolution of a bicontinuous nanostructure via a solid-state interfacial dealloying reaction
journal, June 2016
- Wada, Takeshi; Yubuta, Kunio; Kato, Hidemi
- Scripta Materialia, Vol. 118
Percolation thresholds and universal formulas
journal, February 1997
- van der Marck, S. C.
- Physical Review E, Vol. 55, Issue 2
Dealloying at High Homologous Temperature: Morphology Diagrams
journal, January 2017
- Geng, Ke; Sieradzki, Karl
- Journal of The Electrochemical Society, Vol. 164, Issue 6
Effect of tungsten content on the microstructure and tensile properties of Ni–xW–6Cr alloys
journal, February 2016
- Liu, Shulin; Ye, Xiang-Xi; Jiang, Li
- Materials Science and Engineering: A, Vol. 655
On the possibility of severe corrosion of a Ni-W-Cr alloy in fluoride molten salts at high temperature
journal, April 2019
- Ai, Hua; Ye, Xiang-Xi; Jiang, Li
- Corrosion Science, Vol. 149
One-minute nano-tomography using hard X-ray full-field transmission microscope
journal, August 2018
- Ge, Mingyuan; Coburn, David Scott; Nazaretski, Evgeny
- Applied Physics Letters, Vol. 113, Issue 8
Microstructural evolution and deformation behavior of Al-Cu alloys: A Transmission X-ray Microscopy (TXM) and micropillar compression study
journal, February 2018
- Kaira, C. Shashank; Kantzos, Christopher; Williams, Jason J.
- Acta Materialia, Vol. 144
Real-Time Visualization of Diffusion-Controlled Nanowire Growth in Solution
journal, July 2014
- Ye, Shengrong; Chen, Zuofeng; Ha, Yoon-Cheol
- Nano Letters, Vol. 14, Issue 8
Visualization of electrochemically driven solid-state phase transformations using operando hard X-ray spectro-imaging
journal, April 2015
- Li, Linsen; Chen-Wiegart, Yu-chen Karen; Wang, Jiajun
- Nature Communications, Vol. 6, Issue 1
Rapid quenching by the Taylor wire technique
journal, April 1978
- Pardoe, G. W. F.; Butler, E.; Gelder, D.
- Journal of Materials Science, Vol. 13, Issue 4
Vapor Pressure of Pure Substances. Organic and Inorganic Compounds
journal, April 1947
- Stull, Daniel R.
- Industrial & Engineering Chemistry, Vol. 39, Issue 4
Experimental Test of Properties of KCl–MgCl2 Eutectic Molten Salt for Heat Transfer and Thermal Storage Fluid in Concentrated Solar Power Systems
journal, May 2018
- Xu, Xiankun; Wang, Xiaoxin; Li, Peiwen
- Journal of Solar Energy Engineering, Vol. 140, Issue 5
Extending the methodology of X-ray crystallography to allow imaging of micrometre-sized non-crystalline specimens
journal, July 1999
- Miao, Jianwei; Charalambous, Pambos; Kirz, Janos
- Nature, Vol. 400, Issue 6742
Fiji: an open-source platform for biological-image analysis
journal, June 2012
- Schindelin, Johannes; Arganda-Carreras, Ignacio; Frise, Erwin
- Nature Methods, Vol. 9, Issue 7