Tin-graphene tubes as anodes for lithium-ion batteries with high volumetric and gravimetric energy densities
Abstract
Limited by the size of microelectronics, as well as the space of electrical vehicles, there are tremendous demands for lithium-ion batteries with high volumetric energy densities. Current lithium-ion batteries, however, adopt graphite-based anodes with low tap density and gravimetric capacity, resulting in poor volumetric performance metric. Here, by encapsulating nanoparticles of metallic tin in mechanically robust graphene tubes, we show tin anodes with high volumetric and gravimetric capacities, high rate performance, and long cycling life. Pairing with a commercial cathode material LiNi0.6Mn0.2Co0.2O2, full cells exhibit a gravimetric and volumetric energy density of 590 W h Kg-1 and 1,252 W h L-1 , respectively, the latter of which doubles that of the cell based on graphite anodes. This work provides an effective route towards lithium-ion batteries with high energy density for a broad range of applications.
- Authors:
-
- Univ. of California, Los Angeles, CA (United States). Chemical and Biomolecular Engineering
- Jilin Univ., Changchun (China). State Key Lab. of Supramolecular Strucure and Materials
- Pacific Northwest National Lab. (PNNL), Richland, WA (United States). Environmental Molecular Sciences Lab.
- ENN Group, Langfang (China)
- Shanghai Univ. of Electric Power (China). Shanghai Key Lab. of Materials Protection and Advanced Materials in Electric Power
- Publication Date:
- Research Org.:
- Pacific Northwest National Laboratory (PNNL), Richland, WA (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES). Chemical Sciences, Geosciences & Biosciences Division
- OSTI Identifier:
- 1629184
- Grant/Contract Number:
- AC05-76RL01830
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Nature Communications
- Additional Journal Information:
- Journal Volume: 11; Journal Issue: 1; Journal ID: ISSN 2041-1723
- Publisher:
- Nature Publishing Group
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 25 ENERGY STORAGE
Citation Formats
Mo, Runwei, Tan, Xinyi, Li, Fan, Tao, Ran, Xu, Jinhui, Kong, Dejia, Wang, Zhiyong, Xu, Bin, Wang, Xiang, Wang, Chongmin, Li, Jinlai, Peng, Yiting, and Lu, Yunfeng. Tin-graphene tubes as anodes for lithium-ion batteries with high volumetric and gravimetric energy densities. United States: N. p., 2020.
Web. doi:10.1038/s41467-020-14859-z.
Mo, Runwei, Tan, Xinyi, Li, Fan, Tao, Ran, Xu, Jinhui, Kong, Dejia, Wang, Zhiyong, Xu, Bin, Wang, Xiang, Wang, Chongmin, Li, Jinlai, Peng, Yiting, & Lu, Yunfeng. Tin-graphene tubes as anodes for lithium-ion batteries with high volumetric and gravimetric energy densities. United States. https://doi.org/10.1038/s41467-020-14859-z
Mo, Runwei, Tan, Xinyi, Li, Fan, Tao, Ran, Xu, Jinhui, Kong, Dejia, Wang, Zhiyong, Xu, Bin, Wang, Xiang, Wang, Chongmin, Li, Jinlai, Peng, Yiting, and Lu, Yunfeng. Fri .
"Tin-graphene tubes as anodes for lithium-ion batteries with high volumetric and gravimetric energy densities". United States. https://doi.org/10.1038/s41467-020-14859-z. https://www.osti.gov/servlets/purl/1629184.
@article{osti_1629184,
title = {Tin-graphene tubes as anodes for lithium-ion batteries with high volumetric and gravimetric energy densities},
author = {Mo, Runwei and Tan, Xinyi and Li, Fan and Tao, Ran and Xu, Jinhui and Kong, Dejia and Wang, Zhiyong and Xu, Bin and Wang, Xiang and Wang, Chongmin and Li, Jinlai and Peng, Yiting and Lu, Yunfeng},
abstractNote = {Limited by the size of microelectronics, as well as the space of electrical vehicles, there are tremendous demands for lithium-ion batteries with high volumetric energy densities. Current lithium-ion batteries, however, adopt graphite-based anodes with low tap density and gravimetric capacity, resulting in poor volumetric performance metric. Here, by encapsulating nanoparticles of metallic tin in mechanically robust graphene tubes, we show tin anodes with high volumetric and gravimetric capacities, high rate performance, and long cycling life. Pairing with a commercial cathode material LiNi0.6Mn0.2Co0.2O2, full cells exhibit a gravimetric and volumetric energy density of 590 W h Kg-1 and 1,252 W h L-1 , respectively, the latter of which doubles that of the cell based on graphite anodes. This work provides an effective route towards lithium-ion batteries with high energy density for a broad range of applications.},
doi = {10.1038/s41467-020-14859-z},
journal = {Nature Communications},
number = 1,
volume = 11,
place = {United States},
year = {Fri Mar 13 00:00:00 EDT 2020},
month = {Fri Mar 13 00:00:00 EDT 2020}
}
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Alloy Negative Electrodes for Li-Ion Batteries
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Monodisperse and Inorganically Capped Sn and Sn/SnO 2 Nanocrystals for High-Performance Li-Ion Battery Anodes
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High Capacity Li Ion Battery Anodes Using Ge Nanowires
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Facile Synthesis of Free-Standing Silicon Membranes with Three-Dimensional Nanoarchitecture for Anodes of Lithium Ion Batteries
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Ultrasmall Sn Nanoparticles Embedded in Nitrogen-Doped Porous Carbon As High-Performance Anode for Lithium-Ion Batteries
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Facile Synthesis of Highly Porous Ni–Sn Intermetallic Microcages with Excellent Electrochemical Performance for Lithium and Sodium Storage
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Sn@CNT Nanostructures Rooted in Graphene with High and Fast Li-Storage Capacities
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Phase Evolution of Tin Nanocrystals in Lithium Ion Batteries
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- Im, Hyung Soon; Cho, Yong Jae; Lim, Young Rok
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Anodes for Sodium Ion Batteries Based on Tin–Germanium–Antimony Alloys
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- Farbod, Behdokht; Cui, Kai; Kalisvaart, W. Peter
- ACS Nano, Vol. 8, Issue 5
Issues and challenges facing rechargeable lithium batteries
journal, November 2001
- Tarascon, J.-M.; Armand, M.
- Nature, Vol. 414, Issue 6861, p. 359-367
3D nitrogen-doped graphene foam with encapsulated germanium/nitrogen-doped graphene yolk-shell nanoarchitecture for high-performance flexible Li-ion battery
journal, January 2017
- Mo, Runwei; Rooney, David; Sun, Kening
- Nature Communications, Vol. 8, Issue 1
Stable Li-ion battery anodes by in-situ polymerization of conducting hydrogel to conformally coat silicon nanoparticles
journal, June 2013
- Wu, Hui; Yu, Guihua; Pan, Lijia
- Nature Communications, Vol. 4, Issue 1
Scalable synthesis of silicon-nanolayer-embedded graphite for high-energy lithium-ion batteries
journal, August 2016
- Ko, Minseong; Chae, Sujong; Ma, Jiyoung
- Nature Energy, Vol. 1, Issue 9
Nanostructured materials for advanced energy conversion and storage devices
journal, May 2005
- Aricò, Antonino Salvatore; Bruce, Peter; Scrosati, Bruno
- Nature Materials, Vol. 4, Issue 5, p. 366-377
Materials for electrochemical capacitors
journal, November 2008
- Simon, Patrice; Gogotsi, Yury
- Nature Materials, Vol. 7, Issue 11
High-performance lithium-ion anodes using a hierarchical bottom-up approach
journal, March 2010
- Magasinski, A.; Dixon, P.; Hertzberg, B.
- Nature Materials, Vol. 9, Issue 4, p. 353-358
Fast-charging high-energy lithium-ion batteries via implantation of amorphous silicon nanolayer in edge-plane activated graphite anodes
journal, October 2017
- Kim, Namhyung; Chae, Sujong; Ma, Jiyoung
- Nature Communications, Vol. 8, Issue 1
Graphene balls for lithium rechargeable batteries with fast charging and high volumetric energy densities
journal, November 2017
- Son, In Hyuk; Park, Jong Hwan; Park, Seongyong
- Nature Communications, Vol. 8, Issue 1
Caging tin oxide in three-dimensional graphene networks for superior volumetric lithium storage
journal, January 2018
- Han, Junwei; Kong, Debin; Lv, Wei
- Nature Communications, Vol. 9, Issue 1
Improvement of natural graphite as a lithium-ion battery anode material, from raw flake to carbon-coated sphereElectronic supplementary information (ESI) available: colour versions of Figs. 6, 8 and 9. See http://www.rsc.org/suppdata/jm/b3/b316702j/
journal, January 2004
- Yoshio, Masaki; Wang, Hongyu; Fukuda, Kenji
- Journal of Materials Chemistry, Vol. 14, Issue 11
Multilayer nanoassembly of Sn-nanopillar arrays sandwiched between graphene layers for high-capacity lithium storage
journal, January 2011
- Ji, Liwen; Tan, Zhongkui; Kuykendall, Tevye
- Energy & Environmental Science, Vol. 4, Issue 9
Carbon-coated nano-sized Li4Ti5O12 nanoporous micro-sphere as anode material for high-rate lithium-ion batteries
journal, January 2011
- Zhu, Guan-Nan; Liu, Hai-Jing; Zhuang, Ji-Hua
- Energy & Environmental Science, Vol. 4, Issue 10
SnS2@reduced graphene oxide nanocomposites as anode materials with high capacity for rechargeable lithium ion batteries
journal, January 2012
- Yin, Jiefu; Cao, Huaqiang; Zhou, Zhongfu
- Journal of Materials Chemistry, Vol. 22, Issue 45
True Performance Metrics in Electrochemical Energy Storage
journal, November 2011
- Gogotsi, Y.; Simon, P.
- Science, Vol. 334, Issue 6058
Determination of the Lithium Ion Diffusion Coefficient in Graphite
journal, January 1999
- Yu, Ping
- Journal of The Electrochemical Society, Vol. 146, Issue 1
Anomalous, High-Voltage Irreversible Capacity in Tin Electrodes for Lithium Batteries
journal, January 2003
- Beattie, S. D.; Hatchard, T.; Bonakdarpour, A.
- Journal of The Electrochemical Society, Vol. 150, Issue 6
Reversible Insertion of Sodium in Tin
journal, January 2012
- Ellis, L. D.; Hatchard, T. D.; Obrovac, M. N.
- Journal of The Electrochemical Society, Vol. 159, Issue 11
Investigation of the Influence of Nanostructured LiNi 0.33 Co 0.33 Mn 0.33 O 2 Lithium-Ion Battery Electrodes on Performance and Aging
journal, January 2018
- Dreizler, Andreas M.; Bohn, Nicole; Geßwein, Holger
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