A-site compositional effects in Ga-doped hollandite materials of the form BaxCsyGa2x+yTi8-2x-yO16: implications for Cs immobilization in crystalline ceramic waste forms

Xu, Yun; Wen, Yi; Grote, Rob; Amoroso, Jake; Shuller Nickles, Lindsay; Brinkman, Kyle S.

doi:10.1038/srep27412

Title: A-site compositional effects in Ga-doped hollandite materials of the form Ba_xCs_yGa_2x+yTi_8-2x-yO₁₆: implications for Cs immobilization in crystalline ceramic waste forms

Abstract

Not provided.

Authors:

Xu, Yun ^[1]; Wen, Yi ^[2]; Grote, Rob ^[1]; Amoroso, Jake ^[3]; Shuller Nickles, Lindsay ^[1]; Brinkman, Kyle S. ^[1]

Clemson Univ., SC (United States), Dept, of Materials Science and Engineering
Clemson Univ., SC (United States), Dept, of Environmental Engineering and Earth Science
Savannah River Site (SRS), Aiken, SC (United States). Savannah River National Lab. (SRNL)

Publication Date:: Wed Jun 01 00:00:00 EDT 2016

Research Org.:: Clemson Univ., SC (United States)

Sponsoring Org.:: USDOE Office of Science (SC)

OSTI Identifier:: 1624839

Grant/Contract Number:: SC0012530

Resource Type:: Accepted Manuscript

Journal Name:: Scientific Reports

Additional Journal Information:: Journal Volume: 6; Journal Issue: 1; Journal ID: ISSN 2045-2322

Publisher:: Nature Publishing Group

Country of Publication:: United States

Language:: English

Subject:: Science & Technology - Other Topics

Citation Formats


                    Xu, Yun, Wen, Yi, Grote, Rob, Amoroso, Jake, Shuller Nickles, Lindsay, and Brinkman, Kyle S. A-site compositional effects in Ga-doped hollandite materials of the form BaxCsyGa2x+yTi8-2x-yO16: implications for Cs immobilization in crystalline ceramic waste forms.  United States: N. p., 2016. 
Web.  doi:10.1038/srep27412.

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                    Xu, Yun, Wen, Yi, Grote, Rob, Amoroso, Jake, Shuller Nickles, Lindsay, & Brinkman, Kyle S. A-site compositional effects in Ga-doped hollandite materials of the form BaxCsyGa2x+yTi8-2x-yO16: implications for Cs immobilization in crystalline ceramic waste forms.  United States.  https://doi.org/10.1038/srep27412

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                    Xu, Yun, Wen, Yi, Grote, Rob, Amoroso, Jake, Shuller Nickles, Lindsay, and Brinkman, Kyle S. Wed .  
"A-site compositional effects in Ga-doped hollandite materials of the form BaxCsyGa2x+yTi8-2x-yO16: implications for Cs immobilization in crystalline ceramic waste forms".  United States.  https://doi.org/10.1038/srep27412.  https://www.osti.gov/servlets/purl/1624839.

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@article{osti_1624839,

  title        = {A-site compositional effects in Ga-doped hollandite materials of the form BaxCsyGa2x+yTi8-2x-yO16: implications for Cs immobilization in crystalline ceramic waste forms},

  author       = {Xu, Yun and Wen, Yi and Grote, Rob and Amoroso, Jake and Shuller Nickles, Lindsay and Brinkman, Kyle S.},

  abstractNote = {Not provided.},

  doi          = {10.1038/srep27412},

  journal      = {Scientific Reports},

  number       = 1,

  volume       = 6,

  place        = {United States},

  year         = {Wed Jun 01 00:00:00 EDT 2016},

  month        = {Wed Jun 01 00:00:00 EDT 2016}

}

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Yang, Yushan; Xie, Xiaodong; Yang, Xiaoyong
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Atomistic scale investigation of cation ordering and phase stability in Cs-substituted Ba1.33Zn1.33Ti6.67O16, Ba1.33Ga2.66Ti5.67O16 and Ba1.33Al2.66Ti5.33O16 hollandite
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Wen, Yi; Xu, Yun; Brinkman, Kyle S.
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Structural Evolution in Hollandite Solid Solutions Across the A‐Site Compositional Range from Ba _1.33 Ga _2.66 Ti _5.34 O ₁₆ to Cs _1.33 Ga _1.33 Ti _6.67 O ₁₆
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Title: A-site compositional effects in Ga-doped hollandite materials of the form BaxCsyGa2x+yTi8-2x-yO16: implications for Cs immobilization in crystalline ceramic waste forms

Abstract

Citation Formats

Low-Temperature Phase of Sodium Priderite, NaxCrxTi8–xO16, with a Monoclinic Hollandite Structure journal, June 1999

Generalized Gradient Approximation Made Simple journal, October 1996

Dielectric relaxation in hollandites and rutile journal, December 1991

Long-term storage of spent nuclear fuel journal, February 2015

Structural Behavior of Ba 1.24 Al 2.48 Ti 5.52 O 16 Hollandite at High Temperature: An In Situ Neutron Diffraction Study journal, September 2014

Ionic conduction in one dimension: A structural study of the hollandite K 1.54 Mg 0.77 Ti 7.23 O 1 6 over the range 133≤ T ≤919 K journal, July 1986

An X-ray structural analysis of cesium substitution in the barium hollandite phase of synroc journal, July 1984

Synthesis and dielectric properties of MXTi7O16 (M = Ba and Sr; X = Mg and Zn) hollandite ceramics journal, April 2004

Relative importance of grain boundaries and size effects in thermal conductivity of nanocrystalline materials journal, November 2014

Structural Defects of Silver Hollandite, Ag x Mn 8 O y , Nanorods: Dramatic Impact on Electrochemistry journal, July 2015

Hollandites as a new class of multiferroics journal, August 2014

Preparation and characterization of (Ba,Cs)(M,Ti)8O16 (M=Al3+, Fe3+, Ga3+, Cr3+, Sc3+, Mg2+) hollandite ceramics developed for radioactive cesium immobilization journal, June 2007

Melt processed multiphase ceramic waste forms for nuclear waste immobilization journal, November 2014

New Crystalline Silicotitanate (CST) Waste Forms: Hydrothermal Synthesis and Characterization of CS-SI-TI-O Phases journal, January 1999

Microstructural characterization of single-crystalline potassium hollandite nanowires journal, December 2008

The permittivity and the conductivity of Ba-hollandite Ba1.16M2.32Ti5.68O16 (M=Al, Ga) observed by dielectric spectroscopy journal, July 2007

Synthesis and characterization of hollandite-type material intended for the specific containment of radioactive cesium journal, October 2006

Synthesis and magnetic properties of single-crystalline Na2-xMn8O16 nanorods journal, January 2011

Single Crystal Growth of Birnessite- and Hollandite-Type Manganese Oxides by a Flux Method journal, May 2003

Inside Back Cover: The Active Sites of a Rod-Shaped Hollandite DeNO x Catalyst (Chem. Eur. J. 27/2015) journal, June 2015

Iterative minimization techniques for ab initio total-energy calculations: molecular dynamics and conjugate gradients journal, October 1992

Barium borosilicate glass – a potential matrix for immobilization of sulfate bearing high-level radioactive liquid waste journal, November 2006

Ionic conductivities of hollandites journal, April 1978

ac ionic conductivity of hollandite type compounds from 100 Hz to 37.0 GHz journal, December 1982

Disposal of high-level nuclear wastes: a geological perspective journal, April 1985

Melt processed single phase hollandite waste forms for nuclear waste immobilization: Ba1.0Cs0.3A2.3Ti5.7O16; A=Cr, Fe, Al journal, January 2014

Thermochemistry of Barium Hollandites journal, March 2013

Development of Crystal-Tolerant High-Level Waste Glasses report, December 2010

Materials Science of High-Level Nuclear Waste Immobilization journal, January 2009

Ceramics for high level radioactive waste solidification journal, September 2012

Hollandite cathodes for lithium ion batteries. 2. Thermodynamic and kinetics studies of lithium insertion into BaMMn7O16 (M=Mg, Mn, Fe, Ni) journal, May 2001

Apatitic Waste Forms: Process Overview journal, January 1997

ChemInform Abstract: IONIC CONDUCTIVITIES OF HOLLANDITES journal, August 1978

Ceramics for high level radioactive waste solidification journal, September 2012

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Immobilization of radionuclides in single-phase crystalline waste forms: A review on their intrinsic properties and long term behaviour journal, July 2000

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Title: A-site compositional effects in Ga-doped hollandite materials of the form Ba_xCs_yGa_2x+yTi_8-2x-yO₁₆: implications for Cs immobilization in crystalline ceramic waste forms

Low-Temperature Phase of Sodium Priderite, NaxCrxTi8–xO16, with a Monoclinic Hollandite Structure
journal, June 1999

Generalized Gradient Approximation Made Simple
journal, October 1996

Dielectric relaxation in hollandites and rutile
journal, December 1991

Long-term storage of spent nuclear fuel
journal, February 2015

Structural Behavior of Ba _1.24 Al _2.48 Ti _5.52 O ₁₆ Hollandite at High Temperature: An In Situ Neutron Diffraction Study
journal, September 2014

Ionic conduction in one dimension: A structural study of the hollandite K _1.54 Mg _0.77 Ti _7.23 O ₁ ₆ over the range 133≤ T ≤919 K
journal, July 1986

An X-ray structural analysis of cesium substitution in the barium hollandite phase of synroc
journal, July 1984

Synthesis and dielectric properties of MXTi7O16 (M = Ba and Sr; X = Mg and Zn) hollandite ceramics
journal, April 2004

Relative importance of grain boundaries and size effects in thermal conductivity of nanocrystalline materials
journal, November 2014

Structural Defects of Silver Hollandite, Ag _x Mn ₈ O _{y ,} Nanorods: Dramatic Impact on Electrochemistry
journal, July 2015

Hollandites as a new class of multiferroics
journal, August 2014

Preparation and characterization of (Ba,Cs)(M,Ti)8O16 (M=Al3+, Fe3+, Ga3+, Cr3+, Sc3+, Mg2+) hollandite ceramics developed for radioactive cesium immobilization
journal, June 2007

Melt processed multiphase ceramic waste forms for nuclear waste immobilization
journal, November 2014

New Crystalline Silicotitanate (CST) Waste Forms: Hydrothermal Synthesis and Characterization of CS-SI-TI-O Phases
journal, January 1999

Microstructural characterization of single-crystalline potassium hollandite nanowires
journal, December 2008

The permittivity and the conductivity of Ba-hollandite Ba1.16M2.32Ti5.68O16 (M=Al, Ga) observed by dielectric spectroscopy
journal, July 2007

Synthesis and characterization of hollandite-type material intended for the specific containment of radioactive cesium
journal, October 2006

Synthesis and magnetic properties of single-crystalline Na2-xMn8O16 nanorods
journal, January 2011

Single Crystal Growth of Birnessite- and Hollandite-Type Manganese Oxides by a Flux Method
journal, May 2003

Inside Back Cover: The Active Sites of a Rod-Shaped Hollandite DeNO _x Catalyst (Chem. Eur. J. 27/2015)
journal, June 2015

Iterative minimization techniques for ab initio total-energy calculations: molecular dynamics and conjugate gradients
journal, October 1992

Barium borosilicate glass – a potential matrix for immobilization of sulfate bearing high-level radioactive liquid waste
journal, November 2006

Ionic conductivities of hollandites
journal, April 1978

ac ionic conductivity of hollandite type compounds from 100 Hz to 37.0 GHz
journal, December 1982

Disposal of high-level nuclear wastes: a geological perspective
journal, April 1985

Melt processed single phase hollandite waste forms for nuclear waste immobilization: Ba1.0Cs0.3A2.3Ti5.7O16; A=Cr, Fe, Al
journal, January 2014

Thermochemistry of Barium Hollandites
journal, March 2013

Development of Crystal-Tolerant High-Level Waste Glasses
report, December 2010

Materials Science of High-Level Nuclear Waste Immobilization
journal, January 2009

Ceramics for high level radioactive waste solidification
journal, September 2012

Hollandite cathodes for lithium ion batteries. 2. Thermodynamic and kinetics studies of lithium insertion into BaMMn7O16 (M=Mg, Mn, Fe, Ni)
journal, May 2001

Apatitic Waste Forms: Process Overview
journal, January 1997

ChemInform Abstract: IONIC CONDUCTIVITIES OF HOLLANDITES
journal, August 1978

Ceramics for high level radioactive waste solidification
journal, September 2012

Synthesis and characterization of hollandite-type material intended for the specific containment of radioactive cesium
journal, October 2006

Immobilization of radionuclides in single-phase crystalline waste forms: A review on their intrinsic properties and long term behaviour
journal, July 2000

Structural Defects of Silver Hollandite, Ag _x Mn ₈ O _{y ,} Nanorods: Dramatic Impact on Electrochemistry
journal, July 2015

Relative importance of grain boundaries and size effects in thermal conductivity of nanocrystalline materials
journal, November 2014

Critical path-driven property and performance transitions in heterogeneous microstructures
journal, February 2017

Compositional control of tunnel features in hollandite-based ceramics: structure and stability of (Ba,Cs)1.33(Zn,Ti)8O16
journal, September 2018

Synthesis and phase structure of (Cs0.8−xBa0.4+x)(Al3+1.6+ xTi4+6.4− x)O16 ceramics using sol-spray pyrolysis route for immobilizing radioactive cesium
journal, May 2019

Atomistic scale investigation of cation ordering and phase stability in Cs-substituted Ba1.33Zn1.33Ti6.67O16, Ba1.33Ga2.66Ti5.67O16 and Ba1.33Al2.66Ti5.33O16 hollandite
journal, March 2018

Structural Evolution in Hollandite Solid Solutions Across the A‐Site Compositional Range from Ba _1.33 Ga _2.66 Ti _5.34 O ₁₆ to Cs _1.33 Ga _1.33 Ti _6.67 O ₁₆
journal, August 2016

Compositional control of radionuclide retention in hollandite‐based ceramic waste forms for Cs‐immobilization
journal, December 2018

Temperature‐dependent electrical transport behavior and structural evolution in hollandite‐type titanium‐based oxide
journal, May 2019

An Interdisciplinary View of Interfaces: Perspectives Regarding Emergent Phase Formation
journal, October 2017