Bismuthene for highly efficient carbon dioxide electroreduction reaction
Abstract
Bismuth (Bi) has been known as a highly efficient electrocatalyst for CO2 reduction reaction. Stable free-standing two-dimensional Bi monolayer (Bismuthene) structures have been predicted theoretically, but never realized experimentally. Here, we show the first simple large-scale synthesis of free-standing Bismuthene, to our knowledge, and demonstrate its high electrocatalytic efficiency for formate (HCOO-) formation from CO2 reduction reaction. The catalytic performance is evident by the high Faradaic efficiency (99% at -580 mV vs. Reversible Hydrogen Electrode (RHE)), small onset overpotential (<90 mV) and high durability (no performance decay after 75 h and annealing at 400 °C). Density functional theory calculations show the structure-sensitivity of the CO2 reduction reaction over Bismuthene and thicker nanosheets, suggesting that selective formation of HCOO- indeed can proceed easily on Bismuthene (111) facet due to the unique compressive strain. This work paves the way for the extensive experimental investigation of Bismuthene in many different fields.
- Authors:
-
- State Key Laboratory of Electroanalytical Chemistry, & Jilin Province Key Laboratory of Low Carbon Chemical Power, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun, People’s Republic of China; University of Science and Technology of China, Anhui, People’s Republic of China
- Univ. of Wisconsin, Madison, WI (United States). Dept. of Chemical and Biological Engineering
- State Key Laboratory of Electroanalytical Chemistry, & Jilin Province Key Laboratory of Low Carbon Chemical Power, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun, People’s Republic of China
- State Key Laboratory of Rare Earth, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun, People’s Republic of China
- University of Science and Technology of China, Anhui, People's Republic of China
- Publication Date:
- Research Org.:
- Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC); National Natural Science Foundation of China (NSFC); K.C. Wong Education Foundation and Science and Technology Innovation Foundation of Jilin Province for Talents Cultivation; Jilin Youth Foundation
- OSTI Identifier:
- 1624255
- Grant/Contract Number:
- AC02-05CH11231; 21925205; U1601211; 21633008; 2017YFE9127900; 21733004; 21721003; 2018YFB1502302; 21972133; 20160519005JH; 20170414019JH
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Nature Communications
- Additional Journal Information:
- Journal Volume: 11; Journal Issue: 1; Journal ID: ISSN 2041-1723
- Publisher:
- Nature Publishing Group
- Country of Publication:
- United States
- Language:
- English
- Subject:
- Science & Technology - Other Topics
Citation Formats
Yang, Fa, Elnabawy, Ahmed O., Schimmenti, Roberto, Song, Ping, Wang, Jiawei, Peng, Zhangquan, Yao, Shuang, Deng, Ruiping, Song, Shuyan, Lin, Yue, Mavrikakis, Manos, and Xu, Weilin. Bismuthene for highly efficient carbon dioxide electroreduction reaction. United States: N. p., 2020.
Web. doi:10.1038/s41467-020-14914-9.
Yang, Fa, Elnabawy, Ahmed O., Schimmenti, Roberto, Song, Ping, Wang, Jiawei, Peng, Zhangquan, Yao, Shuang, Deng, Ruiping, Song, Shuyan, Lin, Yue, Mavrikakis, Manos, & Xu, Weilin. Bismuthene for highly efficient carbon dioxide electroreduction reaction. United States. https://doi.org/10.1038/s41467-020-14914-9
Yang, Fa, Elnabawy, Ahmed O., Schimmenti, Roberto, Song, Ping, Wang, Jiawei, Peng, Zhangquan, Yao, Shuang, Deng, Ruiping, Song, Shuyan, Lin, Yue, Mavrikakis, Manos, and Xu, Weilin. Thu .
"Bismuthene for highly efficient carbon dioxide electroreduction reaction". United States. https://doi.org/10.1038/s41467-020-14914-9. https://www.osti.gov/servlets/purl/1624255.
@article{osti_1624255,
title = {Bismuthene for highly efficient carbon dioxide electroreduction reaction},
author = {Yang, Fa and Elnabawy, Ahmed O. and Schimmenti, Roberto and Song, Ping and Wang, Jiawei and Peng, Zhangquan and Yao, Shuang and Deng, Ruiping and Song, Shuyan and Lin, Yue and Mavrikakis, Manos and Xu, Weilin},
abstractNote = {Bismuth (Bi) has been known as a highly efficient electrocatalyst for CO2 reduction reaction. Stable free-standing two-dimensional Bi monolayer (Bismuthene) structures have been predicted theoretically, but never realized experimentally. Here, we show the first simple large-scale synthesis of free-standing Bismuthene, to our knowledge, and demonstrate its high electrocatalytic efficiency for formate (HCOO-) formation from CO2 reduction reaction. The catalytic performance is evident by the high Faradaic efficiency (99% at -580 mV vs. Reversible Hydrogen Electrode (RHE)), small onset overpotential (<90 mV) and high durability (no performance decay after 75 h and annealing at 400 °C). Density functional theory calculations show the structure-sensitivity of the CO2 reduction reaction over Bismuthene and thicker nanosheets, suggesting that selective formation of HCOO- indeed can proceed easily on Bismuthene (111) facet due to the unique compressive strain. This work paves the way for the extensive experimental investigation of Bismuthene in many different fields.},
doi = {10.1038/s41467-020-14914-9},
journal = {Nature Communications},
number = 1,
volume = 11,
place = {United States},
year = {Thu Feb 27 00:00:00 EST 2020},
month = {Thu Feb 27 00:00:00 EST 2020}
}
Works referenced in this record:
Bismuthene on a SiC substrate: A candidate for a high-temperature quantum spin Hall material
journal, June 2017
- Reis, F.; Li, G.; Dudy, L.
- Science, Vol. 357, Issue 6348
Generalized Gradient Approximation Made Simple
journal, October 1996
- Perdew, John P.; Burke, Kieron; Ernzerhof, Matthias
- Physical Review Letters, Vol. 77, Issue 18, p. 3865-3868
Liquid-phase exfoliated ultrathin Bi nanosheets: Uncovering the origins of enhanced electrocatalytic CO2 reduction on two-dimensional metal nanostructure
journal, November 2018
- Zhang, Wenjun; Hu, Yi; Ma, Lianbo
- Nano Energy, Vol. 53
Electroreduction of carbon monoxide to liquid fuel on oxide-derived nanocrystalline copper
journal, April 2014
- Li, Christina W.; Ciston, Jim; Kanan, Matthew W.
- Nature, Vol. 508, Issue 7497
PVA-assisted synthesis and characterization of core–shell Bi nanobelts
journal, December 2015
- Yu, Xing; Fautrelle, Yves; Ren, Zhongming
- Materials Letters, Vol. 161
Electrochemical Reduction of CO2 to Formate on Easily Prepared Carbon-Supported Bi Nanoparticles
journal, May 2019
- Ávila-Bolívar, Beatriz; García-Cruz, Leticia; Montiel, Vicente
- Molecules, Vol. 24, Issue 11
Bursting at the seams: Rippled monolayer bismuth on NbSe 2
journal, April 2018
- Fang, Alan; Adamo, Carolina; Jia, Shuang
- Science Advances, Vol. 4, Issue 4
Surface structure and temperature dependence of light-alkane skeletal rearrangement reactions catalyzed over platinum single-crystal surfaces
journal, December 1982
- Davis, S. Mark; Zaera, Francisco; Somorjai, Gabor A.
- Journal of the American Chemical Society, Vol. 104, Issue 26
Ultrastable atomic copper nanosheets for selective electrochemical reduction of carbon dioxide
journal, September 2017
- Dai, Lei; Qin, Qing; Wang, Pei
- Science Advances, Vol. 3, Issue 9
Atomic and Molecular Adsorption on the Bi(111) Surface: Insights into Catalytic CO 2 Reduction
journal, July 2018
- Oh, Wooseok; Rhee, Choong Kyun; Han, Jeong Woo
- The Journal of Physical Chemistry C, Vol. 122, Issue 40
The p‐Orbital Delocalization of Main‐Group Metals to Boost CO 2 Electroreduction
journal, October 2018
- He, Sisi; Ni, Fenglou; Ji, Yujin
- Angewandte Chemie, Vol. 130, Issue 49
Single-Layer MoS2 Phototransistors
journal, December 2011
- Yin, Zongyou; Li, Hai; Li, Hong
- ACS Nano, Vol. 6, Issue 1, p. 74-80
Kinetics of a rough crystal face: Temperature dependence of the growth rate
journal, October 1986
- Elwenspoek, M.
- Applied Physics A Solids and Surfaces, Vol. 41, Issue 2
Partially oxidized atomic cobalt layers for carbon dioxide electroreduction to liquid fuel
journal, January 2016
- Gao, Shan; Lin, Yue; Jiao, Xingchen
- Nature, Vol. 529, Issue 7584
Formation of lattice-dislocated bismuth nanowires on copper foam for enhanced electrocatalytic CO 2 reduction at low overpotential
journal, January 2019
- Zhang, Xiaolong; Sun, Xinghuan; Guo, Si-Xuan
- Energy & Environmental Science, Vol. 12, Issue 4
Spin–Orbit Coupling-Dominated Catalytic Activity of Two-Dimensional Bismuth toward CO 2 Electroreduction: Not the Thinner the Better
journal, July 2019
- Wang, Yu; Zhu, Xiaorong; Li, Yafei
- The Journal of Physical Chemistry Letters, Vol. 10, Issue 16
In situ micro-Raman studies of laser-induced bismuth oxidation reveals metastability of β-Bi_2O_3 microislands
journal, January 2014
- Steele, J. A.; Lewis, R. A.
- Optical Materials Express, Vol. 4, Issue 10
Effect of Strain on the Reactivity of Metal Surfaces
journal, September 1998
- Mavrikakis, M.; Hammer, B.; Nørskov, J. K.
- Physical Review Letters, Vol. 81, Issue 13
Semiconducting Group 15 Monolayers: A Broad Range of Band Gaps and High Carrier Mobilities
journal, December 2015
- Zhang, Shengli; Xie, Meiqiu; Li, Fengyu
- Angewandte Chemie International Edition, Vol. 55, Issue 5
Flexible Ultrafast Aqueous Rechargeable Ni//Bi Battery Based on Highly Durable Single-Crystalline Bismuth Nanostructured Anode
journal, August 2016
- Zeng, Yinxiang; Lin, Ziqi; Meng, Yue
- Advanced Materials, Vol. 28, Issue 41
Implicit solvation model for density-functional study of nanocrystal surfaces and reaction pathways
journal, February 2014
- Mathew, Kiran; Sundararaman, Ravishankar; Letchworth-Weaver, Kendra
- The Journal of Chemical Physics, Vol. 140, Issue 8
Ultrathin Bi Nanosheets with Superior Photoluminescence
journal, July 2017
- Hussain, Naveed; Liang, Tongxiang; Zhang, Qingyun
- Small, Vol. 13, Issue 36
Towards a better Sn: Efficient electrocatalytic reduction of CO 2 to formate by Sn/SnS 2 derived from SnS 2 nanosheets
journal, January 2017
- Li, Fengwang; Chen, Lu; Xue, Mianqi
- Nano Energy, Vol. 31
Rational Design of a Hierarchical Tin Dendrite Electrode for Efficient Electrochemical Reduction of CO 2
journal, July 2015
- Won, Da Hye; Choi, Chang Hyuck; Chung, Jaehoon
- ChemSusChem, Vol. 8, Issue 18
Bi 2 O 3 Nanosheets Grown on Multi‐Channel Carbon Matrix to Catalyze Efficient CO 2 Electroreduction to HCOOH
journal, September 2019
- Liu, Subiao; Lu, Xue Feng; Xiao, Jing
- Angewandte Chemie International Edition, Vol. 58, Issue 39
Efficiency of ab-initio total energy calculations for metals and semiconductors using a plane-wave basis set
journal, July 1996
- Kresse, G.; Furthmüller, J.
- Computational Materials Science, Vol. 6, Issue 1, p. 15-50
Recent Advances in Ultrathin Two-Dimensional Nanomaterials
journal, March 2017
- Tan, Chaoliang; Cao, Xiehong; Wu, Xue-Jun
- Chemical Reviews, Vol. 117, Issue 9
Selective conversion of CO 2 to formate on a size tunable nano-Bi electrocatalyst
journal, July 2017
- Qiu, Yue; Du, Jun; Dong, Wen
- Journal of CO2 Utilization, Vol. 20
Special points for Brillouin-zone integrations
journal, June 1976
- Monkhorst, Hendrik J.; Pack, James D.
- Physical Review B, Vol. 13, Issue 12, p. 5188-5192
Large-Area Dry Transfer of Single-Crystalline Epitaxial Bismuth Thin Films
journal, October 2016
- Walker, Emily S.; Na, Seung Ryul; Jung, Daehwan
- Nano Letters, Vol. 16, Issue 11
Efficient iterative schemes for ab initio total-energy calculations using a plane-wave basis set
journal, October 1996
- Kresse, G.; Furthmüller, J.
- Physical Review B, Vol. 54, Issue 16, p. 11169-11186
Single Unit Cell Bismuth Tungstate Layers Realizing Robust Solar CO 2 Reduction to Methanol
journal, September 2015
- Liang, Liang; Lei, Fengcai; Gao, Shan
- Angewandte Chemie International Edition, Vol. 54, Issue 47
The Nature of the Interlayer Interaction in Bulk and Few-Layer Phosphorus
journal, November 2015
- Shulenburger, L.; Baczewski, A. D.; Zhu, Z.
- Nano Letters, Vol. 15, Issue 12
Correlations in coverage-dependent atomic adsorption energies on Pd(111)
journal, May 2009
- Kitchin, John R.
- Physical Review B, Vol. 79, Issue 20
Precision Measurements of the Lattice Constants of Twelve Common Metals
journal, June 1925
- Davey, Wheeler P.
- Physical Review, Vol. 25, Issue 6
Shape-controlled bismuth nanoflakes as highly selective catalysts for electrochemical carbon dioxide reduction to formate
journal, September 2017
- Kim, Sungjoo; Dong, Wan Jae; Gim, Seungo
- Nano Energy, Vol. 39
A Molecular Surface Functionalization Approach to Tuning Nanoparticle Electrocatalysts for Carbon Dioxide Reduction
journal, June 2016
- Cao, Zhi; Kim, Dohyung; Hong, Dachao
- Journal of the American Chemical Society, Vol. 138, Issue 26
Origin of the Overpotential for Oxygen Reduction at a Fuel-Cell Cathode
journal, November 2004
- Nørskov, J. K.; Rossmeisl, J.; Logadottir, A.
- The Journal of Physical Chemistry B, Vol. 108, Issue 46
Controllable Synthesis of Few-Layer Bismuth Subcarbonate by Electrochemical Exfoliation for Enhanced CO 2 Reduction Performance
journal, September 2018
- Zhang, Ying; Zhang, Xiaolong; Ling, Yunzhi
- Angewandte Chemie International Edition, Vol. 57, Issue 40
Bismuth Single Atoms Resulting from Transformation of Metal–Organic Frameworks and Their Use as Electrocatalysts for CO 2 Reduction
journal, September 2019
- Zhang, Erhuan; Wang, Tao; Yu, Ke
- Journal of the American Chemical Society, Vol. 141, Issue 42
The Electrochemical Reduction of Carbon Dioxide to Formate/Formic Acid: Engineering and Economic Feasibility
journal, September 2011
- Agarwal, Arun S.; Zhai, Yumei; Hill, Davion
- ChemSusChem, Vol. 4, Issue 9
Rational Design of Bi Nanoparticles for Efficient Electrochemical CO 2 Reduction: The Elucidation of Size and Surface Condition Effects
journal, August 2016
- Zhang, Zhiyong; Chi, Miaofang; Veith, Gabriel M.
- ACS Catalysis, Vol. 6, Issue 9
Aqueous CO 2 Reduction at Very Low Overpotential on Oxide-Derived Au Nanoparticles
journal, November 2012
- Chen, Yihong; Li, Christina W.; Kanan, Matthew W.
- Journal of the American Chemical Society, Vol. 134, Issue 49
Freestanding Tin Disulfide Single-Layers Realizing Efficient Visible-Light Water Splitting
journal, July 2012
- Sun, Yongfu; Cheng, Hao; Gao, Shan
- Angewandte Chemie International Edition, Vol. 51, Issue 35
Ultrathin Co 3 O 4 Layers Realizing Optimized CO 2 Electroreduction to Formate
journal, November 2015
- Gao, Shan; Jiao, Xingchen; Sun, Zhongti
- Angewandte Chemie International Edition, Vol. 55, Issue 2
Selective CO 2 Reduction on 2D Mesoporous Bi Nanosheets
journal, October 2018
- Yang, Hui; Han, Na; Deng, Jun
- Advanced Energy Materials, Vol. 8, Issue 35
Thermoelectric Properties of a Monolayer Bismuth
journal, December 2013
- Cheng, Long; Liu, Huijun; Tan, Xiaojian
- The Journal of Physical Chemistry C, Vol. 118, Issue 2
Flexible Ultrafast Aqueous Rechargeable Ni//Bi Battery Based on Highly Durable Single-Crystalline Bismuth Nanostructured Anode
journal, August 2016
- Zeng, Yinxiang; Lin, Ziqi; Meng, Yue
- Advanced Materials, Vol. 28, Issue 41
Selective CO 2 Reduction on 2D Mesoporous Bi Nanosheets
journal, October 2018
- Yang, Hui; Han, Na; Deng, Jun
- Advanced Energy Materials, Vol. 8, Issue 35
Semiconducting Group 15 Monolayers: A Broad Range of Band Gaps and High Carrier Mobilities
journal, December 2015
- Zhang, Shengli; Xie, Meiqiu; Li, Fengyu
- Angewandte Chemie, Vol. 128, Issue 5
Ultrathin Co 3 O 4 Layers Realizing Optimized CO 2 Electroreduction to Formate
journal, November 2015
- Gao, Shan; Jiao, Xingchen; Sun, Zhongti
- Angewandte Chemie, Vol. 128, Issue 2
Controllable Synthesis of Few‐Layer Bismuth Subcarbonate by Electrochemical Exfoliation for Enhanced CO 2 Reduction Performance
journal, September 2018
- Zhang, Ying; Zhang, Xiaolong; Ling, Yunzhi
- Angewandte Chemie, Vol. 130, Issue 40
The p‐Orbital Delocalization of Main‐Group Metals to Boost CO 2 Electroreduction
journal, October 2018
- He, Sisi; Ni, Fenglou; Ji, Yujin
- Angewandte Chemie, Vol. 130, Issue 49
Bi 2 O 3 Nanosheets Grown on Multi‐Channel Carbon Matrix to Catalyze Efficient CO 2 Electroreduction to HCOOH
journal, July 2019
- Liu, Subiao; Lu, Xue Feng; Xiao, Jing
- Angewandte Chemie, Vol. 131, Issue 39
Freestanding Tin Disulfide Single-Layers Realizing Efficient Visible-Light Water Splitting
journal, July 2012
- Sun, Yongfu; Cheng, Hao; Gao, Shan
- Angewandte Chemie International Edition, Vol. 51, Issue 35
Ultrathin Bi Nanosheets with Superior Photoluminescence
journal, July 2017
- Hussain, Naveed; Liang, Tongxiang; Zhang, Qingyun
- Small, Vol. 13, Issue 36
PVA-assisted synthesis and characterization of core–shell Bi nanobelts
journal, December 2015
- Yu, Xing; Fautrelle, Yves; Ren, Zhongming
- Materials Letters, Vol. 161
Towards a better Sn: Efficient electrocatalytic reduction of CO 2 to formate by Sn/SnS 2 derived from SnS 2 nanosheets
journal, January 2017
- Li, Fengwang; Chen, Lu; Xue, Mianqi
- Nano Energy, Vol. 31
Shape-controlled bismuth nanoflakes as highly selective catalysts for electrochemical carbon dioxide reduction to formate
journal, September 2017
- Kim, Sungjoo; Dong, Wan Jae; Gim, Seungo
- Nano Energy, Vol. 39
Liquid-phase exfoliated ultrathin Bi nanosheets: Uncovering the origins of enhanced electrocatalytic CO2 reduction on two-dimensional metal nanostructure
journal, November 2018
- Zhang, Wenjun; Hu, Yi; Ma, Lianbo
- Nano Energy, Vol. 53
Recent Advances in Ultrathin Two-Dimensional Nanomaterials
journal, March 2017
- Tan, Chaoliang; Cao, Xiehong; Wu, Xue-Jun
- Chemical Reviews, Vol. 117, Issue 9
Atomic and Molecular Adsorption on the Bi(111) Surface: Insights into Catalytic CO 2 Reduction
journal, July 2018
- Oh, Wooseok; Rhee, Choong Kyun; Han, Jeong Woo
- The Journal of Physical Chemistry C, Vol. 122, Issue 40
Spin–Orbit Coupling-Dominated Catalytic Activity of Two-Dimensional Bismuth toward CO 2 Electroreduction: Not the Thinner the Better
journal, July 2019
- Wang, Yu; Zhu, Xiaorong; Li, Yafei
- The Journal of Physical Chemistry Letters, Vol. 10, Issue 16
Large-Area Dry Transfer of Single-Crystalline Epitaxial Bismuth Thin Films
journal, October 2016
- Walker, Emily S.; Na, Seung Ryul; Jung, Daehwan
- Nano Letters, Vol. 16, Issue 11
Aqueous CO 2 Reduction at Very Low Overpotential on Oxide-Derived Au Nanoparticles
journal, November 2012
- Chen, Yihong; Li, Christina W.; Kanan, Matthew W.
- Journal of the American Chemical Society, Vol. 134, Issue 49
A Molecular Surface Functionalization Approach to Tuning Nanoparticle Electrocatalysts for Carbon Dioxide Reduction
journal, June 2016
- Cao, Zhi; Kim, Dohyung; Hong, Dachao
- Journal of the American Chemical Society, Vol. 138, Issue 26
Partially oxidized atomic cobalt layers for carbon dioxide electroreduction to liquid fuel
journal, January 2016
- Gao, Shan; Lin, Yue; Jiao, Xingchen
- Nature, Vol. 529, Issue 7584
Ultrathin bismuth nanosheets from in situ topotactic transformation for selective electrocatalytic CO2 reduction to formate
journal, April 2018
- Han, Na; Wang, Yu; Yang, Hui
- Nature Communications, Vol. 9, Issue 1
Structural defects on converted bismuth oxide nanotubes enable highly active electrocatalysis of carbon dioxide reduction
journal, June 2019
- Gong, Qiufang; Ding, Pan; Xu, Mingquan
- Nature Communications, Vol. 10, Issue 1
Construction of Pd-Zn dual sites to enhance the performance for ethanol electro-oxidation reaction
journal, September 2021
- Qiu, Yajun; Zhang, Jian; Jin, Jing
- Nature Communications, Vol. 12, Issue 1
Few-layer bismuthene for ultrashort pulse generation in a dissipative system based on an evanescent field
journal, January 2018
- Chai, Tong; Li, Xiaohui; Feng, Tianci
- Nanoscale, Vol. 10, Issue 37
Simple model explaining and predicting coverage-dependent atomic adsorption energies on transition metal surfaces
journal, July 2010
- İnoğlu, Nilay; Kitchin, John R.
- Physical Review B, Vol. 82, Issue 4
Single and bilayer bismuthene: Stability at high temperature and mechanical and electronic properties
journal, July 2016
- Aktürk, E.; Aktürk, O. Üzengi; Ciraci, S.
- Physical Review B, Vol. 94, Issue 1
Bursting at the seams: Rippled monolayer bismuth on NbSe 2
journal, April 2018
- Fang, Alan; Adamo, Carolina; Jia, Shuang
- Science Advances, Vol. 4, Issue 4
Implicit solvation model for density-functional study of nanocrystal surfaces and reaction pathways
text, January 2013
- Mathew, Kiran; Sundararaman, Ravishankar; Letchworth-Weaver, Kendra
- arXiv