Solid-state synthesis of ordered mesoporous carbon catalysts via a mechanochemical assembly through coordination cross-linking
Abstract
Ordered mesoporous carbons (OMCs) have demonstrated great potential in catalysis, and as supercapacitors and adsorbents. Since the introduction of the organic–organic self-assembly approach in 2004/2005 until now, the direct synthesis of OMCs is still limited to the wet processing of phenol-formaldehyde polycondensation, which involves soluble toxic precursors, and acid or alkali catalysts, and requires multiple synthesis steps, thus restricting the widespread application of OMCs. Herein, we report a simple, general, scalable and sustainable solid-state synthesis of OMCs and nickel OMCs with uniform and tunable mesopores (~4–10 nm), large pore volumes (up to 0.96 cm3 g–1) and high-surface areas exceeding 1,000m2g–1, based on a mechanochemical assembly between polyphenol-metal complexes and triblock co-polymers. Nickel nanoparticles (~5.40nm) confined in the cylindrical nanochannels show great thermal stability at 600 °C. Moreover, the nickel OMCs offer exceptional activity in the hydrogenation of bulky molecules (~2 nm).
- Authors:
-
- Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Chemical Sciences Division
- Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Chemical Sciences Division; East China Univ. of Science and Technology, Shanghai (China). Key Laboratory for Advanced Materials and Research Institute of Industrial Catalysis
- Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Materials Science and Technology Division
- Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Chemical Sciences Division; Univ. of Tennessee, Knoxville, TN (United States). Dept. of Chemistry
- East China Univ. of Science and Technology, Shanghai (China). Key Laboratory for Advanced Materials and Research Institute of Industrial Catalysis
- Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Neutron Science Directorate
- Vanderbilt Univ., Nashville, TN (United States). Dept. of Chemical and Biomolecular Engineering
- Univ. of Puerto Rico, San Juan, PR (United States). Dept. of Chemistry
- Publication Date:
- Research Org.:
- Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES). Chemical Sciences, Geosciences & Biosciences Division; National Basic Research Program of China; National High Technology Research and Development Program of China; USDOE Office of Science (SC), Basic Energy Sciences (BES). Materials Sciences & Engineering Division
- OSTI Identifier:
- 1623886
- Grant/Contract Number:
- AC05-00OR22725
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Nature Communications
- Additional Journal Information:
- Journal Volume: 8; Journal Issue: 1; Journal ID: ISSN 2041-1723
- Publisher:
- Nature Publishing Group
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND SUPERFLUIDITY; Coordination chemistry; Heterogeneous catalysis; Porous materials
Citation Formats
Zhang, Pengfei, Wang, Li, Yang, Shize, Schott, Jennifer A., Liu, Xiaofei, Mahurin, Shannon M., Huang, Caili, Zhang, Yu, Fulvio, Pasquale F., Chisholm, Matthew F., and Dai, Sheng. Solid-state synthesis of ordered mesoporous carbon catalysts via a mechanochemical assembly through coordination cross-linking. United States: N. p., 2017.
Web. doi:10.1038/ncomms15020.
Zhang, Pengfei, Wang, Li, Yang, Shize, Schott, Jennifer A., Liu, Xiaofei, Mahurin, Shannon M., Huang, Caili, Zhang, Yu, Fulvio, Pasquale F., Chisholm, Matthew F., & Dai, Sheng. Solid-state synthesis of ordered mesoporous carbon catalysts via a mechanochemical assembly through coordination cross-linking. United States. https://doi.org/10.1038/ncomms15020
Zhang, Pengfei, Wang, Li, Yang, Shize, Schott, Jennifer A., Liu, Xiaofei, Mahurin, Shannon M., Huang, Caili, Zhang, Yu, Fulvio, Pasquale F., Chisholm, Matthew F., and Dai, Sheng. Fri .
"Solid-state synthesis of ordered mesoporous carbon catalysts via a mechanochemical assembly through coordination cross-linking". United States. https://doi.org/10.1038/ncomms15020. https://www.osti.gov/servlets/purl/1623886.
@article{osti_1623886,
title = {Solid-state synthesis of ordered mesoporous carbon catalysts via a mechanochemical assembly through coordination cross-linking},
author = {Zhang, Pengfei and Wang, Li and Yang, Shize and Schott, Jennifer A. and Liu, Xiaofei and Mahurin, Shannon M. and Huang, Caili and Zhang, Yu and Fulvio, Pasquale F. and Chisholm, Matthew F. and Dai, Sheng},
abstractNote = {Ordered mesoporous carbons (OMCs) have demonstrated great potential in catalysis, and as supercapacitors and adsorbents. Since the introduction of the organic–organic self-assembly approach in 2004/2005 until now, the direct synthesis of OMCs is still limited to the wet processing of phenol-formaldehyde polycondensation, which involves soluble toxic precursors, and acid or alkali catalysts, and requires multiple synthesis steps, thus restricting the widespread application of OMCs. Herein, we report a simple, general, scalable and sustainable solid-state synthesis of OMCs and nickel OMCs with uniform and tunable mesopores (~4–10 nm), large pore volumes (up to 0.96 cm3 g–1) and high-surface areas exceeding 1,000m2g–1, based on a mechanochemical assembly between polyphenol-metal complexes and triblock co-polymers. Nickel nanoparticles (~5.40nm) confined in the cylindrical nanochannels show great thermal stability at 600 °C. Moreover, the nickel OMCs offer exceptional activity in the hydrogenation of bulky molecules (~2 nm).},
doi = {10.1038/ncomms15020},
journal = {Nature Communications},
number = 1,
volume = 8,
place = {United States},
year = {Fri Apr 28 00:00:00 EDT 2017},
month = {Fri Apr 28 00:00:00 EDT 2017}
}
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Ordered Mesoporous Carbons for Adsorption of Paracetamol and Non-Steroidal Anti-Inflammatory Drugs: Ibuprofen and Naproxen from Aqueous Solutions
journal, May 2019
- Jedynak, Katarzyna; Szczepanik, Beata; Rędzia, Nina
- Water, Vol. 11, Issue 5
Mechanochemical Synthesis of Ruthenium Cluster@Ordered Mesoporous Carbon Catalysts by Synergetic Dual Templates
journal, May 2019
- Wang, Li; Zhao, Jiahua; Zhang, Pengfei
- Chemistry – A European Journal, Vol. 25, Issue 36
Synthesis of Ag nanoparticles/ordered mesoporous carbon as a highly efficient catalyst for the electroreduction of benzyl bromide
journal, January 2020
- Zhang, Zhi-Xia; Wang, Shuo; Li, Shi-Ming
- RSC Advances, Vol. 10, Issue 2
Synthesis of carbon nanotubes@mesoporous carbon core–shell structured electrocatalysts via a molecule-mediated interfacial co-assembly strategy
journal, January 2019
- Zhu, Xiaohang; Xia, Yuan; Zhang, Xingmiao
- Journal of Materials Chemistry A, Vol. 7, Issue 15
Potassium-incorporated mesoporous carbons: strong solid bases with enhanced catalytic activity and stability
journal, January 2018
- Li, Tian-Tian; Gao, Xia-Jun; Qi, Shi-Chao
- Catalysis Science & Technology, Vol. 8, Issue 11
Naturally occurring gallic acid derived multifunctional porous polymers for highly efficient CO 2 conversion and I 2 capture
journal, January 2018
- Xie, Chao; Song, Jinliang; Wu, Haoran
- Green Chemistry, Vol. 20, Issue 20
Solvent-free and rapid synthesis of mesoporous Pt–iron oxide catalysts via mechanochemical assembly
journal, January 2019
- Zhou, Min; Zhao, Jiahua; Zhang, Pengfei
- Catalysis Science & Technology, Vol. 9, Issue 15
Biomass-derived ordered mesoporous carbon nano-ellipsoid encapsulated metal nanoparticles inside: ideal nanoreactors for shape-selective catalysis
journal, January 2020
- Liu, Jinrong; Xie, Lei; Wang, Zhe
- Chemical Communications, Vol. 56, Issue 2
Electrostatic-Assisted Liquefaction of Porous Carbons
journal, October 2017
- Li, Peipei; Schott, Jennifer A.; Zhang, Jinshui
- Angewandte Chemie International Edition, Vol. 56, Issue 47
Tuning the Adsorption Energy of Methanol Molecules Along Ni-N-Doped Carbon Phase Boundaries by the Mott-Schottky Effect for Gas-Phase Methanol Dehydrogenation
journal, February 2018
- Xue, Zhong-Hua; Han, Jing-Tan; Feng, Wei-Jie
- Angewandte Chemie, Vol. 130, Issue 10
High-level nitrogen-doped, micro/mesoporous carbon as an efficient metal-free electrocatalyst for the oxygen reduction reaction: optimizing the reaction surface area by a solvent-free mechanochemical method
journal, January 2019
- Zhang, Wendu; Qi, Jiawei; Bai, Peiyao
- New Journal of Chemistry, Vol. 43, Issue 27
Electrocatalytic Upgrading of Lignin‐Derived Bio‐Oil Based on Surface‐Engineered PtNiB Nanostructure
journal, March 2019
- Zhou, Yulin; Gao, Yijing; Zhong, Xing
- Advanced Functional Materials, Vol. 29, Issue 10
Ultrathin WS 2 nanosheets vertically embedded in a hollow mesoporous carbon framework – a triple-shell structure with enhanced lithium storage and electrocatalytic properties
journal, January 2018
- Zhang, Xiue; Zhao, Rongfang; Wu, Qianhui
- Journal of Materials Chemistry A, Vol. 6, Issue 39
Facile Synthesis of Porous Carbon for the Removal of Diclofenac Sodium from Water
journal, September 2019
- Mao, Naqing; Huang, Lijin; Shuai, Qin
- ACS Omega, Vol. 4, Issue 12
N-Doped Mesoporous Carbons: From Synthesis to Applications as Metal-Free Reduction Catalysts and Energy Storage Materials
journal, November 2019
- Yang, Ying; Gu, Lin; Guo, Shangwei
- Frontiers in Chemistry, Vol. 7