Luminescent Properties of DOBDC Containing MOFs: The Role of Free Hydroxyls
Abstract
A novel metal–organic framework (MOF), Mn-DOBDC, has been synthesized in an effort to investigate the role of both the metal center and presence of free linker hydroxyls on the luminescent properties of DOBDC (2,5-dihydroxyterephthalic acid) containing MOFs. Co-MOF-74, RE-DOBDC (RE–Eu and Tb), and Mn-DOBDC have been synthesized and analyzed by powder X-ray diffraction (PXRD) and the fluorescent properties probed by UV–Vis spectroscopy and density functional theory (DFT). Mn-DOBDC has been synthesized by a new method involving a concurrent facile reflux synthesis and slow crystallization, resulting in yellow single crystals in monoclinic space group C2/c. Mn-DOBDC was further analyzed by single-crystal X-ray diffraction (SCXRD), scanning electron microscopy–energy-dispersive spectroscopy (SEM-EDS), and photoluminescent emission. Results indicate that the luminescent properties of the DOBDC linker are transferred to the three-dimensional structures of both the RE-DOBDC and Mn-DOBDC, which contain free hydroxyls on the linker. In Co-MOF-74 however, luminescence is quenched in the solid state due to binding of the phenolic hydroxyls within the MOF structure. Finally, Mn-DOBDC exhibits a ligand-based tunable emission that can be controlled in solution by the use of different solvents.
- Publication Date:
- Research Org.:
- Sandia National Lab. (SNL-NM), Albuquerque, NM (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- OSTI Identifier:
- 1619220
- Report Number(s):
- SAND-2020-1609J
Journal ID: ISSN 1944-8244; 683701
- Grant/Contract Number:
- AC04-94AL85000; SC0012577; NA0003525
- Resource Type:
- Accepted Manuscript
- Journal Name:
- ACS Applied Materials and Interfaces
- Additional Journal Information:
- Journal Volume: 12; Journal Issue: 20; Journal ID: ISSN 1944-8244
- Publisher:
- American Chemical Society (ACS)
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 36 MATERIALS SCIENCE; metal-organic framework; MOF; luminescence
Citation Formats
Henkelis, Susan E., Rademacher, David, Vogel, Dayton J., Valdez, Nichole R., Rodriguez, Mark A., Rohwer, Lauren E. S., and Nenoff, Tina M. Luminescent Properties of DOBDC Containing MOFs: The Role of Free Hydroxyls. United States: N. p., 2020.
Web. doi:10.1021/acsami.0c02829.
Henkelis, Susan E., Rademacher, David, Vogel, Dayton J., Valdez, Nichole R., Rodriguez, Mark A., Rohwer, Lauren E. S., & Nenoff, Tina M. Luminescent Properties of DOBDC Containing MOFs: The Role of Free Hydroxyls. United States. https://doi.org/10.1021/acsami.0c02829
Henkelis, Susan E., Rademacher, David, Vogel, Dayton J., Valdez, Nichole R., Rodriguez, Mark A., Rohwer, Lauren E. S., and Nenoff, Tina M. Mon .
"Luminescent Properties of DOBDC Containing MOFs: The Role of Free Hydroxyls". United States. https://doi.org/10.1021/acsami.0c02829. https://www.osti.gov/servlets/purl/1619220.
@article{osti_1619220,
title = {Luminescent Properties of DOBDC Containing MOFs: The Role of Free Hydroxyls},
author = {Henkelis, Susan E. and Rademacher, David and Vogel, Dayton J. and Valdez, Nichole R. and Rodriguez, Mark A. and Rohwer, Lauren E. S. and Nenoff, Tina M.},
abstractNote = {A novel metal–organic framework (MOF), Mn-DOBDC, has been synthesized in an effort to investigate the role of both the metal center and presence of free linker hydroxyls on the luminescent properties of DOBDC (2,5-dihydroxyterephthalic acid) containing MOFs. Co-MOF-74, RE-DOBDC (RE–Eu and Tb), and Mn-DOBDC have been synthesized and analyzed by powder X-ray diffraction (PXRD) and the fluorescent properties probed by UV–Vis spectroscopy and density functional theory (DFT). Mn-DOBDC has been synthesized by a new method involving a concurrent facile reflux synthesis and slow crystallization, resulting in yellow single crystals in monoclinic space group C2/c. Mn-DOBDC was further analyzed by single-crystal X-ray diffraction (SCXRD), scanning electron microscopy–energy-dispersive spectroscopy (SEM-EDS), and photoluminescent emission. Results indicate that the luminescent properties of the DOBDC linker are transferred to the three-dimensional structures of both the RE-DOBDC and Mn-DOBDC, which contain free hydroxyls on the linker. In Co-MOF-74 however, luminescence is quenched in the solid state due to binding of the phenolic hydroxyls within the MOF structure. Finally, Mn-DOBDC exhibits a ligand-based tunable emission that can be controlled in solution by the use of different solvents.},
doi = {10.1021/acsami.0c02829},
journal = {ACS Applied Materials and Interfaces},
number = 20,
volume = 12,
place = {United States},
year = {Mon Apr 27 00:00:00 EDT 2020},
month = {Mon Apr 27 00:00:00 EDT 2020}
}
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