Uranyl dication mediated photoswitching of a calix[4]pyrrole-based metal coordination cage
Abstract
A set of self-assembled tri- and tetrapodal metal coordination cage structures (cage-1 and cage-2, respectively) constructed from the uranyl dication (UO22+) and a dibenzoic acid functionalised cis-calix[4]pyrrole (1) are described. The inherent photochemical reactivity of the uranyl dication mediates the transformation of cage-1 to cage-2 via the activation of molecular oxygen here.
- Authors:
-
[1];
[1];
[2];
[1];
[1];
[1]
- Univ. of Texas, Austin, TX (United States)
- Univ. of South Florida, Tampa, FL (United States)
- Publication Date:
- Research Org.:
- Univ. of Texas, Austin, TX (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- OSTI Identifier:
- 1615764
- Alternate Identifier(s):
- OSTI ID: 1463039
- Grant/Contract Number:
- FG02-01ER15186
- Resource Type:
- Accepted Manuscript
- Journal Name:
- ChemComm
- Additional Journal Information:
- Journal Volume: 54; Journal Issue: 68; Journal ID: ISSN 1359-7345
- Publisher:
- Royal Society of Chemistry
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
Citation Formats
Lee, Juhoon, Brewster, James T., Song, Bo, Lynch, Vincent M., Hwang, Inhong, Li, Xiaopeng, and Sessler, Jonathan L. Uranyl dication mediated photoswitching of a calix[4]pyrrole-based metal coordination cage. United States: N. p., 2018.
Web. doi:10.1039/C8CC05160G.
Lee, Juhoon, Brewster, James T., Song, Bo, Lynch, Vincent M., Hwang, Inhong, Li, Xiaopeng, & Sessler, Jonathan L. Uranyl dication mediated photoswitching of a calix[4]pyrrole-based metal coordination cage. United States. https://doi.org/10.1039/C8CC05160G
Lee, Juhoon, Brewster, James T., Song, Bo, Lynch, Vincent M., Hwang, Inhong, Li, Xiaopeng, and Sessler, Jonathan L. Tue .
"Uranyl dication mediated photoswitching of a calix[4]pyrrole-based metal coordination cage". United States. https://doi.org/10.1039/C8CC05160G. https://www.osti.gov/servlets/purl/1615764.
@article{osti_1615764,
title = {Uranyl dication mediated photoswitching of a calix[4]pyrrole-based metal coordination cage},
author = {Lee, Juhoon and Brewster, James T. and Song, Bo and Lynch, Vincent M. and Hwang, Inhong and Li, Xiaopeng and Sessler, Jonathan L.},
abstractNote = {A set of self-assembled tri- and tetrapodal metal coordination cage structures (cage-1 and cage-2, respectively) constructed from the uranyl dication (UO22+) and a dibenzoic acid functionalised cis-calix[4]pyrrole (1) are described. The inherent photochemical reactivity of the uranyl dication mediates the transformation of cage-1 to cage-2 via the activation of molecular oxygen here.},
doi = {10.1039/C8CC05160G},
journal = {ChemComm},
number = 68,
volume = 54,
place = {United States},
year = {Tue Jul 31 00:00:00 EDT 2018},
month = {Tue Jul 31 00:00:00 EDT 2018}
}
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