Controlling Structure Beyond the Initial Coordination Sphere: Complexation-Induced Reversed Micelle Formation in Calix[4]pyrrole-Containing Diblock Copolymers
Abstract
A diblock copolymer containing a strapped calix[4]pyrrole-based ion pair recognition subunit has been synthesized via RAFT polymerization. As prepared, the polymer is hydrophobic and devoid of any particular morphological form. Yet, upon ion pair complexation, the copolymer self-assembles to generate reverse micelles in organic media. The reverse micelle formed in this way may be used to extract alkali cation and cesium halide anion salts from an aqueous source into an organic receiving phase. The polymer confirmed more effective as an extractant than the corresponding free ion pair receptor.
- Authors:
-
[1];
[1];
[1];
[1];
[2]
- Univ. of Texas, Austin, TX (United States)
- Univ. of Texas, Austin, TX (United States); Shanghai Univ. (China)
- Publication Date:
- Research Org.:
- Univ. of Texas, Austin, TX (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES); R. A. Welch Foundation
- OSTI Identifier:
- 1615751
- Grant/Contract Number:
- FG02-01ER15186
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Journal of the American Chemical Society
- Additional Journal Information:
- Journal Volume: 140; Journal Issue: 41; Journal ID: ISSN 0002-7863
- Publisher:
- American Chemical Society (ACS)
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; anions; central nervous system; receptors; ions; copolymers
Citation Formats
Chi, Xiaodong, Peters, Gretchen M., Brockman, Chandler, Lynch, Vincent M., and Sessler, Jonathan L. Controlling Structure Beyond the Initial Coordination Sphere: Complexation-Induced Reversed Micelle Formation in Calix[4]pyrrole-Containing Diblock Copolymers. United States: N. p., 2018.
Web. doi:10.1021/jacs.8b09620.
Chi, Xiaodong, Peters, Gretchen M., Brockman, Chandler, Lynch, Vincent M., & Sessler, Jonathan L. Controlling Structure Beyond the Initial Coordination Sphere: Complexation-Induced Reversed Micelle Formation in Calix[4]pyrrole-Containing Diblock Copolymers. United States. https://doi.org/10.1021/jacs.8b09620
Chi, Xiaodong, Peters, Gretchen M., Brockman, Chandler, Lynch, Vincent M., and Sessler, Jonathan L. Mon .
"Controlling Structure Beyond the Initial Coordination Sphere: Complexation-Induced Reversed Micelle Formation in Calix[4]pyrrole-Containing Diblock Copolymers". United States. https://doi.org/10.1021/jacs.8b09620. https://www.osti.gov/servlets/purl/1615751.
@article{osti_1615751,
title = {Controlling Structure Beyond the Initial Coordination Sphere: Complexation-Induced Reversed Micelle Formation in Calix[4]pyrrole-Containing Diblock Copolymers},
author = {Chi, Xiaodong and Peters, Gretchen M. and Brockman, Chandler and Lynch, Vincent M. and Sessler, Jonathan L.},
abstractNote = {A diblock copolymer containing a strapped calix[4]pyrrole-based ion pair recognition subunit has been synthesized via RAFT polymerization. As prepared, the polymer is hydrophobic and devoid of any particular morphological form. Yet, upon ion pair complexation, the copolymer self-assembles to generate reverse micelles in organic media. The reverse micelle formed in this way may be used to extract alkali cation and cesium halide anion salts from an aqueous source into an organic receiving phase. The polymer confirmed more effective as an extractant than the corresponding free ion pair receptor.},
doi = {10.1021/jacs.8b09620},
journal = {Journal of the American Chemical Society},
number = 41,
volume = 140,
place = {United States},
year = {Mon Oct 08 00:00:00 EDT 2018},
month = {Mon Oct 08 00:00:00 EDT 2018}
}
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