Exotic hysteresis of ferrimagnetic transition in Laves compound TbCo2

Huang, Dan; Gao, Jianrong; Lapidus, Saul H.; Brown, Dennis E.; Ren, Yang

doi:10.1080/21663831.2019.1704454

Title: Exotic hysteresis of ferrimagnetic transition in Laves compound TbCo₂

Abstract

We observed exotic hysteresis behavior in the ferrimagnetic transition of a Laves compound TbCo₂. While positive thermal hysteresis was observed in zero-field calorimetric measurements, inverse thermal hysteresis was observed in thermomagnetic measurements as a rare phenomenon. These observations confirmed a first order of the ferrimagnetic transition and revealed a lowering of this order by an external magnetic field. Elastic measurements and high-resolution synchrotron X-ray diffraction measurements suggested that the rare inverse thermal hysteresis can be related to microscopic lattice strains. Those strains are induced by a spontaneous magnetoelastic coupling and are modified by the external magnetic field.

Authors:

^[1];

^[2]; Lapidus, Saul H. ^[3]; Brown, Dennis E. ^[4]; Ren, Yang ^[5]

Northeastern Univ., Shenyang (People’s Republic of China); Univ. of Tennessee, Knoxville, TN (United States)
Northeastern Univ., Shenyang (People’s Republic of China)
Argonne National Lab. (ANL), Argonne, IL (United States). Advanced Photon Source (APS)
Northern Illinois Univ., DeKalb, IL (United States)
Advanced Photon Source, Argonne National Laboratory, Argonne, IL, USA

Publication Date:: Wed Dec 18 00:00:00 EST 2019

Research Org.:: Argonne National Lab. (ANL), Argonne, IL (United States). Advanced Photon Source (APS)

Sponsoring Org.:: National Natural Science Foundation of China (NSFC); Ministry of Science and Technology of the People’s Republic of China (MOST); China Scholarship Council (CSC)

OSTI Identifier:: 1615496

Grant/Contract Number:: AC02-06CH11357; 51831003; 2012CB619405; 201606080095

Resource Type:: Accepted Manuscript

Journal Name:: Materials Research Letters

Additional Journal Information:: Journal Volume: 8; Journal Issue: 3; Journal ID: ISSN 2166-3831

Publisher:: Taylor and Francis

Country of Publication:: United States

Language:: English

Subject:: 36 MATERIALS SCIENCE; Laves compound; inverse thermal hysteresis; magnetoelastic coupling

Citation Formats


                    Huang, Dan, Gao, Jianrong, Lapidus, Saul H., Brown, Dennis E., and Ren, Yang. Exotic hysteresis of ferrimagnetic transition in Laves compound TbCo2.  United States: N. p., 2019. 
Web.  doi:10.1080/21663831.2019.1704454.

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                    Huang, Dan, Gao, Jianrong, Lapidus, Saul H., Brown, Dennis E., & Ren, Yang. Exotic hysteresis of ferrimagnetic transition in Laves compound TbCo2.  United States.  https://doi.org/10.1080/21663831.2019.1704454

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                    Huang, Dan, Gao, Jianrong, Lapidus, Saul H., Brown, Dennis E., and Ren, Yang. Wed .  
"Exotic hysteresis of ferrimagnetic transition in Laves compound TbCo2".  United States.  https://doi.org/10.1080/21663831.2019.1704454.  https://www.osti.gov/servlets/purl/1615496.

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@article{osti_1615496,

  title        = {Exotic hysteresis of ferrimagnetic transition in Laves compound TbCo2},

  author       = {Huang, Dan and Gao, Jianrong and Lapidus, Saul H. and Brown, Dennis E. and Ren, Yang},

  abstractNote = {We observed exotic hysteresis behavior in the ferrimagnetic transition of a Laves compound TbCo2. While positive thermal hysteresis was observed in zero-field calorimetric measurements, inverse thermal hysteresis was observed in thermomagnetic measurements as a rare phenomenon. These observations confirmed a first order of the ferrimagnetic transition and revealed a lowering of this order by an external magnetic field. Elastic measurements and high-resolution synchrotron X-ray diffraction measurements suggested that the rare inverse thermal hysteresis can be related to microscopic lattice strains. Those strains are induced by a spontaneous magnetoelastic coupling and are modified by the external magnetic field.},

  doi          = {10.1080/21663831.2019.1704454},

  journal      = {Materials Research Letters},

  number       = 3,

  volume       = 8,

  place        = {United States},

  year         = {Wed Dec 18 00:00:00 EST 2019},

  month        = {Wed Dec 18 00:00:00 EST 2019}

}

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Title: Exotic hysteresis of ferrimagnetic transition in Laves compound TbCo2

Abstract

Citation Formats

The order of the magnetic phase transitions in RCo 2 (R = rare earth) intermetallic compounds journal, October 2000

Large Magnetostriction from Morphotropic Phase Boundary in Ferromagnets journal, May 2010

The transport properties of RCo 2 compounds journal, August 1995

Tuning the magnetic and structural transitions in TbC o 2 M n x compounds journal, August 2017

Physical properties of RCo 2 Laves phases journal, May 2001

Elastic properties of polycrystalline rare earth-cobalt laves compounds journal, January 1978

Nature and entropy content of the ordering transitions in R Co 2 journal, April 2006

Exchange interactions in heavy rare-earths RCo 2 compounds journal, May 2017

Temperature dependent neutron powder diffraction study of the Laves phase compound TbCo2 journal, March 2005

Magnetic Structure of Rare‐Earth‐Cobalt (RCo 2 ) Intermetallic Compounds journal, March 1965

Implementation of a modern resonant ultrasound spectroscopy system for the measurement of the elastic moduli of small solid specimens journal, December 2005

Multiferroic (ferroelastic/ferromagnetic/ferrimagnetic) aspects of phase transitions in RCo 2 Laves phases journal, January 2014

Changeover in the order of the magnetic phase transition in the intermetallic compounds (Er1−xTbx)Co2 journal, October 1998

Identifying the critical point of the weakly first-order itinerant magnet DyCo 2 with complementary magnetization and calorimetric measurements journal, April 2013

Magnetocaloric effect and critical behavior near the paramagnetic to ferrimagnetic phase transition temperature in TbCo 2 − x Fe x journal, May 2010

Field induced volume magnetostriction in some rare earth-Co2 compounds journal, September 1978

A powder neutron diffraction study of some rare-earth–Co2 compounds journal, November 1978

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Magnetic properties and spontaneous distortion in TbCo 2 journal, May 1979

Memory effect and inverse thermal hysteresis in La0.87Mn0.98Fe0.02Ox journal, May 2007

On the nature of the magnetocaloric effect of the first-order magnetostructural transition journal, September 2012

Metamagnetism, giant magnetoresistance and magnetocaloric effects in RCo2-based compounds in the vicinity of the Curie temperature journal, July 2002

Temperature Dependent Neutron Powder Diffraction Study of the Laves Phase Compound TbCo2. journal, May 2005

Title: Exotic hysteresis of ferrimagnetic transition in Laves compound TbCo₂

The order of the magnetic phase transitions in RCo ₂ (R = rare earth) intermetallic compounds
journal, October 2000

Large Magnetostriction from Morphotropic Phase Boundary in Ferromagnets
journal, May 2010

The transport properties of RCo ₂ compounds
journal, August 1995

Tuning the magnetic and structural transitions in $TbC o_{2} M n_{x}$ compounds
journal, August 2017

Physical properties of RCo ₂ Laves phases
journal, May 2001

Elastic properties of polycrystalline rare earth-cobalt laves compounds
journal, January 1978

Nature and entropy content of the ordering transitions in $R {Co}_{2}$
journal, April 2006

Exchange interactions in heavy rare-earths RCo ₂ compounds
journal, May 2017

Temperature dependent neutron powder diffraction study of the Laves phase compound TbCo2
journal, March 2005

Magnetic Structure of Rare‐Earth‐Cobalt (RCo ₂ ) Intermetallic Compounds
journal, March 1965

Implementation of a modern resonant ultrasound spectroscopy system for the measurement of the elastic moduli of small solid specimens
journal, December 2005

Multiferroic (ferroelastic/ferromagnetic/ferrimagnetic) aspects of phase transitions in RCo ₂ Laves phases
journal, January 2014

Changeover in the order of the magnetic phase transition in the intermetallic compounds (Er1−xTbx)Co2
journal, October 1998

Identifying the critical point of the weakly first-order itinerant magnet DyCo $_{2}$ with complementary magnetization and calorimetric measurements
journal, April 2013

Magnetocaloric effect and critical behavior near the paramagnetic to ferrimagnetic phase transition temperature in ${TbCo}_{2 - x} {Fe}_{x}$
journal, May 2010

Field induced volume magnetostriction in some rare earth-Co2 compounds
journal, September 1978

A powder neutron diffraction study of some rare-earth–Co2 compounds
journal, November 1978

Polarised neutron study of TbCo ₂
journal, July 1979

Magnetic properties and spontaneous distortion in TbCo ₂
journal, May 1979

Memory effect and inverse thermal hysteresis in La0.87Mn0.98Fe0.02Ox
journal, May 2007

On the nature of the magnetocaloric effect of the first-order magnetostructural transition
journal, September 2012

Metamagnetism, giant magnetoresistance and magnetocaloric effects in RCo2-based compounds in the vicinity of the Curie temperature
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